File name: Pandora147s1_SWDetroitMI_20221201_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20260322T235648.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20221201_L1_smca1c1d20210609p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20221201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221201T140912.2Z 8370.589725 97 1 48.03 2 77.99 135.09 138.77 39.75 0.00 1 0.00 1 0 25 2.798e-01 1.035e-02 2.906e-01 1.144e-02 5.641344e-01 6.100265e-03 6.667129e-03 -6.000000e+00 1.605440e-01 222.65 -2.00 3.54 -2.00 320.98 0.00e+00 3.430887e-03 2.531425e-03 8.419808e-04 -6.000000e+00 7.070783e-03 276.59 -2.00 20.00 -2.00 320.47 0.00e+00 4.661 0.002 302.00 328.00 3 3.0044e+00 1.9290e-02 5.4177e-02 -6.0000e+00 3.9799e-01 6.4668e-02 2.5134e-02 3.0248e-02 -6.0000e+00 4.3456e-01 -6.2927e-02 2.5150e-02 1.6472e-02 -6.0000e+00 2.5360e-01 2.7126e-02 1.2504e-02 5.8416e-03 -6.0000e+00 1.0879e-01 1.4930e-04 -1.7494e-03 3.3699e-04 6.9613e-05 -6.0000e+00 7.6754e-03 -1.2604e-02 -1.0864e-04 12 8 8 10 0 0 99.99 16.18 0.27 -0.01260 -0.02575 61 14 1 5 0 787.260 22.29 15.00 16.18 5.07 23.1 851.62 900000 -40638 -123780 -153182 -106393 -118312 900000 900000 900000 900000 -40161 -86329 22111 -87774 24586 35303 65318 -7086 -34362 -20836 -2561 -46506 -44585 36683 -25669 -21815 332 15622 -17846 8837 -44562 -334 -2954 -21966 -4209 -1320 -7560 19315 -12647 -5801 -8792 -5756 9556 1120 -856 16321 5167 9109 6617 16276 -1166 2787 4664 4762 13386 1272 4633 -4758 2216 -4277 -1647 -784 4040 1265 5864 2419 2136 3497 3683 573 1096 404 -869 703 -289 3485 2246 -2217 457 -78 2142 1910 -2589 -1911 -1899 -1729 44 842 135 -187 612 -833 2234 1154 374 -2059 1162 -126 -79 -668 -186 -2219 -1332 -1057 -835 -2025 279 -1181 -1012 -7 -332 17 242 324 238 77 350 1216 736 -266 -247 228 691 270 1080 567 -251 972 370 -488 810 564 166 -456 1 -357 136 -128 89 -182 -309 -82 -244 900000 -453 -2036 -3496 -1412 -1632 900000 900000 900000 900000 -448 -1443 246 -2143 274 413 728 -154 -1076 -608 -65 -1851 -1751 715 -967 -845 11 431 -663 253 -2325 -14 -149 -1447 -235 -71 -445 994 -1038 -544 -989 -658 1041 132 -105 1794 621 1121 862 2004 -176 452 820 909 2517 282 1028 -1178 502 -1007 -379 -190 1049 383 1858 796 674 1078 1187 217 470 180 -399 321 -124 1307 768 -757 159 -31 995 1025 -1559 -1223 -1286 -1254 33 661 108 -148 456 -608 1477 749 259 -1662 1047 -127 -89 -792 -212 -2362 -1315 -991 -825 -2183 309 -1402 -1285 -9 -490 26 393 513 356 113 497 1757 1129 -438 -417 376 1091 414 1578 799 -341 1280 529 -794 1439 1077 334 -963 3 -816 322 -309 216 -439 -737 -183 -521 SS 20221201T142418.4Z 8370.600213 109 1 1.94 2 76.07 138.10 136.93 44.34 0.00 1 0.00 1 0 17 1.853e-01 1.178e-02 2.036e-01 9.639e-03 5.020089e-01 4.874760e-03 5.998194e-03 -6.000000e+00 1.036580e-01 222.65 -2.00 3.54 -2.00 319.63 0.00e+00 2.528480e-03 1.396057e-03 5.877218e-04 -6.000000e+00 4.528617e-03 276.59 -2.00 20.00 -2.00 319.09 0.00e+00 4.062 0.001 302.00 328.00 3 5.8858e-01 1.3651e-02 4.7176e-02 -6.0000e+00 2.5531e-01 5.5690e-02 1.6209e-02 2.5949e-02 -6.0000e+00 2.7779e-01 -4.8098e-02 1.3864e-02 1.3611e-02 -6.0000e+00 1.6542e-01 1.2606e-02 7.3593e-03 4.7165e-03 -6.0000e+00 7.2118e-02 3.1436e-03 -1.3203e-03 2.6460e-04 4.7684e-05 -6.0000e+00 4.8768e-03 -1.6507e-02 -2.2636e-05 12 9 9 12 1 1 999.00 16.17 0.23 -0.01651 -0.02643 2 19 2 5 0 591.420 22.29 15.00 16.17 5.46 23.1 854.59 900000 22086 -42145 31872 -8436 -19848 5873 -70455 -12047 -67385 25955 -83331 115820 -34148 67027 -43970 -11940 -32832 16169 -27343 13109 -21053 4864 -13857 15518 -1344 -8627 -9628 -2428 11248 -3110 6371 716 1760 -3212 3086 -7566 8219 -7682 3522 -669 1017 -5310 12812 1823 3594 1073 3393 -39 -729 4262 1656 1972 -151 2593 -792 3634 1811 1590 -2214 5322 -759 3929 2247 4555 -590 1302 -1848 -135 2989 -645 1182 -1468 388 -915 -487 -800 1221 -2911 -1159 -4572 -1687 -723 39 -1807 678 -1179 586 436 400 1188 -394 -1380 -1463 -240 -790 713 526 1140 -39 -1011 -712 630 -505 -72 -1312 -33 -891 -392 -857 -90 497 508 613 -106 -232 -397 1220 -565 296 388 2425 -778 564 -724 1060 547 -288 818 437 -461 -109 -153 37 -512 917 -288 314 235 -1467 -173 -487 626 900000 236 -913 354 -130 -314 73 -1986 -226 -2340 388 -3524 1089 -1326 1231 -2721 -613 -2263 773 -2056 718 -1566 292 -1020 964 -101 -726 -811 -182 758 -253 551 76 207 -400 340 -951 1004 -1277 638 -141 230 -1355 2834 456 895 279 868 -11 -204 1209 514 670 -56 1011 -320 1454 750 648 -913 2116 -328 1801 1137 2447 -333 681 -977 -73 1763 -435 814 -1062 268 -619 -297 -456 667 -1646 -732 -3275 -1345 -616 34 -1704 650 -1224 608 461 416 1196 -384 -1259 -1323 -218 -787 777 637 1454 -53 -1330 -880 732 -566 -83 -1601 -42 -1168 -545 -1240 -139 800 832 974 -163 -342 -582 1803 -876 473 640 3863 -1236 879 -1095 1549 787 -407 1193 698 -777 -191 -279 69 -989 1821 -587 650 494 -3098 -352 -962 1190 SS 20221201T142848.2Z 8370.603335 112 1 1.32 2 75.52 139.01 136.35 45.65 0.00 1 0.00 1 0 17 2.854e-01 1.005e-02 1.257e-01 6.508e-03 4.826413e-01 3.269246e-03 5.772990e-03 -6.000000e+00 1.596143e-01 222.65 -2.00 3.54 -2.00 319.42 0.00e+00 3.339226e-04 8.792172e-04 4.912039e-04 -6.000000e+00 6.973861e-03 276.59 -2.00 20.00 -2.00 318.86 0.00e+00 3.917 0.001 302.00 328.00 3 8.1094e-01 9.0666e-03 4.5438e-02 -6.0000e+00 3.9312e-01 2.0744e-02 1.0665e-02 2.4942e-02 -6.0000e+00 4.2777e-01 -2.1954e-02 8.8164e-03 1.2646e-02 -6.0000e+00 2.5473e-01 4.8052e-03 4.7059e-03 3.7473e-03 -6.0000e+00 1.1103e-01 3.0000e-03 -8.9701e-04 1.7797e-04 4.0532e-05 -6.0000e+00 7.5110e-03 -1.5485e-02 -3.5310e-05 12 9 9 12 1 1 93.46 16.18 0.25 -0.01549 -0.02223 4 48 1 5 0 230.180 22.29 15.00 16.18 5.48 23.2 855.18 900000 287248 -76439 32027 -88250 -28230 -42028 26706 -59206 7725 -42969 -22331 -29700 -29347 -14497 -13971 6300 -6521 6042 -9603 11575 -5322 6225 -9210 2990 -9357 9411 -12381 7030 -10842 6645 -10285 4804 -1389 -2803 -6316 -907 2390 1354 3226 -1309 4651 -2620 4279 536 1103 -3638 4121 -1764 2341 -958 4298 1266 2045 833 2748 1899 1399 -722 -1532 2801 -909 1521 2353 3358 -63 1602 -3077 1840 -1166 1678 288 989 -509 878 34 63 -841 -1508 -994 -796 -521 -2691 -1505 -1875 -483 -1119 903 17 2350 -195 1207 -778 -216 -1625 -696 -934 1178 622 361 -553 -1008 -760 -1349 866 -1725 -179 -763 -14 -806 803 801 838 198 -265 -546 1088 -315 75 425 262 389 396 199 497 445 -800 396 75 1001 -264 239 257 243 -98 -562 -484 325 -30 57 95 -221 -658 900000 1823 -2716 421 -3323 -537 -942 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