File name: Pandora147s1_SWDetroitMI_20230716_L2Fit_fout2c9d20221206p1-8.txt File generation date: 20260323T003527.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v9d20221206.txt Level 1 file used: Pandora147s1_SWDetroitMI_20230716_L1_smca1c9d20221206p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20230716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 236 378 Nominal wavelengths inside fitting window [nm]: 305.0989 305.2398 305.3807 305.5215 305.6624 305.8032 305.9440 306.0848 306.2256 306.3664 306.5072 306.6479 306.7887 306.9294 307.0701 307.2108 307.3516 307.4922 307.6329 307.7736 307.9143 308.0549 308.1955 308.3362 308.4768 308.6174 308.7580 308.8985 309.0391 309.1797 309.3202 309.4607 309.6013 309.7418 309.8823 310.0227 310.1632 310.3037 310.4441 310.5846 310.7250 310.8654 311.0058 311.1462 311.2866 311.4270 311.5673 311.7077 311.8480 311.9883 312.1286 312.2689 312.4092 312.5495 312.6898 312.8300 312.9703 313.1105 313.2507 313.3909 313.5311 313.6713 313.8115 313.9517 314.0918 314.2319 314.3721 314.5122 314.6523 314.7924 314.9325 315.0725 315.2126 315.3526 315.4927 315.6327 315.7727 315.9127 316.0527 316.1927 316.3326 316.4726 316.6125 316.7525 316.8924 317.0323 317.1722 317.3121 317.4519 317.5918 317.7317 317.8715 318.0113 318.1511 318.2909 318.4307 318.5705 318.7103 318.8500 318.9898 319.1295 319.2692 319.4089 319.5486 319.6883 319.8280 319.9677 320.1073 320.2469 320.3866 320.5262 320.6658 320.8054 320.9450 321.0845 321.2241 321.3636 321.5032 321.6427 321.7822 321.9217 322.0612 322.2007 322.3401 322.4796 322.6190 322.7584 322.8979 323.0373 323.1767 323.3160 323.4554 323.5948 323.7341 323.8734 324.0128 324.1521 324.2914 324.4307 324.5699 324.7092 324.8485 324.9877 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230716T114015.0Z 8597.486284 117 1 50.31 2 75.51 74.14 61.62 77.69 0.00 1 0.00 1 0 17 2.856e-01 1.176e-02 2.096e-01 8.042e-03 5.352655e-01 4.207160e-03 6.126369e-03 -6.000000e+00 1.636566e-01 232.90 -2.00 3.54 -2.00 320.73 0.00e+00 4.259587e-03 1.713215e-03 9.050211e-04 -6.000000e+00 7.279301e-03 287.84 -2.00 20.00 -2.00 320.01 0.00e+00 3.912 0.001 302.00 328.00 3 4.2481e+00 1.3574e-02 4.8064e-02 -6.0000e+00 4.1108e-01 1.0098e-01 1.7061e-02 2.8734e-02 -6.0000e+00 4.4538e-01 -9.7747e-02 1.4825e-02 1.4966e-02 -6.0000e+00 2.6493e-01 3.3776e-02 7.3807e-03 5.9424e-03 -6.0000e+00 1.1133e-01 8.5290e-05 -5.7635e-04 2.2989e-04 6.4176e-05 -6.0000e+00 7.5119e-03 -1.8345e-04 -2.9568e-05 12 8 8 10 0 0 74.63 16.13 0.57 -0.00018 -0.00451 14 3 1 5 0 3592.970 22.19 15.00 16.13 28.04 29.5 1032.36 -89439 -43726 -79740 -143992 -149409 -144257 -77474 -18991 -40408 -44193 97157 25630 -16071 -2525 9250 -42089 -19975 -34064 1688 -32611 21928 -24401 4698 -23162 14567 -8588 14018 -17976 -19036 -18698 11668 -12341 25502 -9427 -1323 897 1500 29055 -6289 14851 -9629 7991 -1468 6003 -98 2464 6479 4753 206 -305 438 11077 3227 5702 3351 2105 5200 1734 3096 -57 2720 1449 9149 2868 2903 -1719 5024 -2727 2482 195 597 2397 258 -269 -866 -4378 -4212 -56 -1650 -1528 -428 979 -2393 -1509 -3072 1 -1416 1679 403 2542 -220 -657 -736 -1013 -290 -485 339 37 -431 299 225 -1480 -866 -1432 351 -1799 411 -2302 1429 43 259 844 -185 -4 -226 -851 -63 -259 548 351 244 441 -279 1225 657 767 319 1241 -129 285 -334 291 -117 71 -282 69 220 191 55 139 -313 -829 -423 -1368 -480 -1313 -4235 -4218 -3847 -1154 -188 -550 -657 762 222 -265 -46 183 -1535 -642 -1376 51 -1458 606 -1014 161 -1072 517 -381 521 -839 -888 -946 539 -803 1358 -695 -85 57 106 1869 -703 1572 -1431 1056 -223 862 -15 380 971 740 35 -55 86 2163 738 1364 855 562 1372 468 802 -15 743 446 2935 1076 1102 -649 1728 -1042 1009 93 308 1250 134 -133 -391 -1833 -1650 -22 -724 -788 -251 636 -1726 -1139 -2527 1 -1281 1507 363 2134 -176 -489 -522 -746 -237 -457 362 43 -528 355 259 -1562 -854 -1483 387 -2126 501 -3070 1905 65 419 1393 -302 -6 -325 -1245 -93 -386 863 576 396 690 -447 1855 958 1068 431 1756 -206 479 -609 551 -230 149 -631 160 521 462 132 318 -681 -1719 -860 SS 20230716T115117.5Z 8597.493952 120 1 48.14 2 73.54 75.85 59.68 79.26 0.00 1 0.00 1 0 17 1.830e-01 8.126e-03 1.853e-01 5.832e-03 4.908651e-01 3.021720e-03 5.636724e-03 -6.000000e+00 1.048644e-01 232.90 -2.00 3.54 -2.00 320.38 0.00e+00 5.437999e-04 1.101130e-03 1.396240e-03 -6.000000e+00 4.661816e-03 287.84 -2.00 20.00 -2.00 319.64 0.00e+00 3.471 0.001 302.00 328.00 3 4.2759e+00 9.2988e-03 4.3552e-02 -6.0000e+00 2.6341e-01 4.2937e-02 1.1542e-02 2.7504e-02 -6.0000e+00 2.8535e-01 -1.8139e-02 9.9149e-03 1.3149e-02 -6.0000e+00 1.6975e-01 -4.5487e-04 5.0184e-03 3.5040e-03 -6.0000e+00 7.1355e-02 1.3392e-04 -2.0065e-04 1.6745e-04 3.9648e-05 -6.0000e+00 4.8105e-03 -8.8065e-04 4.7382e-05 11 8 0 10 0 0 98.63 16.13 0.43 -0.00088 -0.00239 17 4 1 5 0 2831.290 22.19 15.00 16.13 28.61 29.6 1037.25 39350 -28674 136413 -44750 -17552 -63506 31236 -59230 -19782 -39271 54224 6788 -56012 18670 -2024 26008 -19382 20508 -20256 18563 -21212 21789 -15608 21393 -8643 15907 -14270 9187 -7068 1333 -10055 10014 -3558 -2696 -365 -13772 -1908 -759 7801 -4904 3402 -4354 4157 -4817 3059 -4019 979 -2591 4813 -3287 3725 986 2509 1142 1732 3940 -1469 2380 -884 -380 -1902 3486 1516 3912 -1857 56 -2313 1556 445 2139 2042 2211 529 -581 -686 464 -899 -1312 -110 -379 993 -3243 -1559 -1631 -84 -1154 -111 322 1340 422 1002 -461 597 -641 760 -136 600 709 72 -117 -938 -957 -1166 -418 -1422 -717 -1511 -117 110 144 491 1011 249 -275 -584 559 -76 88 493 218 0 303 811 1053 -351 -331 92 34 633 5 -388 -461 -133 -596 92 -656 671 166 222 108 292 -699 -138 237 -362 776 -650 -188 -1023 230 -1179 -300 -769 453 102 -1823 354 -57 633 -808 622 -986 645 -1119 750 -828 858 -505 764 -924 447 -393 72 -705 661 -303 -234 -29 -1275 -177 -84 976 -777 546 -799 728 -934 553 -790 194 -539 950 -705 866 246 666 330 520 1201 -484 747 -279 -119 -631 1208 600 1647 -833 23 -953 631 204 1107 1149 1282 306 -321 -346 219 -400 -590 -55 -208 618 -2357 -1195 -1321 -72 -1066 -106 315 1284 388 848 -365 444 -496 644 -133 659 875 95 -149 -1119 -1031 -1189 -443 -1648 -867 -1936 -157 160 217 796 1668 402 -421 -879 798 -111 135 805 353 -1 497 1280 1590 -514 -463 123 48 986 9 -681 -845 -253 -1199 197 -1473 1517 385 508 238 608 -1398 -270 SS 20230716T124925.0Z 8597.534318 149 1 47.09 2 62.96 84.95 49.30 87.89 0.00 1 0.00 1 0 17 2.666e-02 6.494e-03 1.964e-02 3.472e-03 3.160166e-01 1.751781e-03 3.707529e-03 -6.000000e+00 1.527673e-02 232.90 -2.00 3.54 -2.00 318.58 0.00e+00 2.642023e-04 3.554709e-04 2.262352e-04 -6.000000e+00 6.793338e-04 287.84 -2.00 20.00 -2.00 317.71 0.00e+00 2.187 0.000 302.00 328.00 3 5.0120e+00 4.8202e-03 2.7385e-02 -6.0000e+00 3.8373e-02 3.7730e-02 5.5082e-03 1.6743e-02 -6.0000e+00 4.1572e-02 -3.1828e-03 3.5851e-03 8.0618e-03 -6.0000e+00 2.4730e-02 -6.2447e-03 1.8394e-03 2.1690e-03 -6.0000e+00 1.0393e-02 2.7266e-04 -3.8822e-04 9.9889e-05 2.2298e-05 -6.0000e+00 7.0099e-04 -3.5714e-04 1.4833e-05 11 9 0 11 8 0 88.95 16.13 0.47 -0.00036 -0.00327 14 3 1 5 0 3362.930 22.19 15.00 16.13 29.94 29.8 1048.64 -14947 3041 -13518 -4851 -6821 -11883 -2763 1426 -4441 -2911 4137 -7415 3132 -3814 -2042 -3181 4278 -829 3157 2593 754 -3436 1435 -968 1208 358 -1759 -3213 -1737 582 -733 1054 489 1685 -5103 -3821 -2519 -253 -1581 621 -1212 1149 -834 255 98 1397 -896 222 -1473 34 903 947 1490 58 588 1025 1135 -623 244 215 2040 708 2837 1734 887 81 -902 -702 860 180 729 -463 410 871 -438 -125 -1640 -103 -1527 -764 -1729 -1390 -1778 -942 -1243 -52 367 1501 893 332 526 -106 -1219 -50 202 -356 373 833 314 -353 -629 -1403 -681 -120 -552 -950 -466 -681 226 27 435 356 364 114 -250 -329 109 156 149 322 41 506 -157 569 282 269 206 791 32 331 -588 57 32 250 55 -309 340 244 50 70 -336 -129 -850 -891 165 -877 -279 -359 -648 -150 85 -312 -209 274 -587 258 -394 -239 -413 541 -116 443 381 114 -540 223 -165 213 66 -327 -566 -285 94 -132 205 104 358 -1078 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