File name: Pandora147s1_SWDetroitMI_20230802_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20230804T132627.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20230802_L1_smca1c1d20210609p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20230802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230802T121650.7Z 8614.511698 233 1 48.93 2 71.24 82.76 101.88 254.06 0.00 1 0.00 1 0 17 6.949e-02 6.787e-03 6.290e-02 4.612e-03 4.208903e-01 2.408612e-03 5.006834e-03 -6.000000e+00 4.039840e-02 232.28 -2.00 3.54 -2.00 319.66 0.00e+00 5.865742e-04 6.880706e-04 6.309030e-04 -6.000000e+00 1.784929e-03 288.19 -2.00 20.00 -2.00 318.89 0.00e+00 3.071 0.000 302.00 328.00 3 3.8823e+00 6.9347e-03 3.7863e-02 -6.0000e+00 1.0136e-01 6.2824e-02 8.2250e-03 2.2866e-02 -6.0000e+00 1.0922e-01 -1.7292e-02 6.4091e-03 1.1204e-02 -6.0000e+00 6.4986e-02 1.3952e-03 3.3556e-03 3.1246e-03 -6.0000e+00 2.8108e-02 3.1011e-04 -6.6861e-04 1.3219e-04 3.3439e-05 -6.0000e+00 1.8316e-03 -3.0793e-02 1.4657e-05 11 8 0 10 0 0 65.92 16.12 0.39 -0.03079 -0.03582 15 3 1 5 0 3261.260 22.19 15.00 16.12 28.15 29.9 1019.96 900000 -38478 -23918 -45626 182 -6110 12636 -10708 -18833 6161 -6919 -2639 -23051 13392 -1852 -11140 -1897 3825 -7885 7585 1277 -2585 -11126 1342 -8711 2148 -2089 -3791 -5752 -2803 7425 666 4659 2120 1398 -10165 1709 -6113 -3474 -3387 -2423 -2342 2496 -1175 4054 1173 893 -813 -761 -3239 -1344 1987 216 1424 719 2555 1700 669 568 630 773 1385 69 3028 1835 813 -308 1049 -55 1883 634 1343 49 306 342 -207 378 -1614 -791 -1732 -788 -1356 -878 -2569 -580 -1088 -292 292 963 535 1034 -638 122 -528 -272 -45 -497 872 493 188 -401 -306 -988 -359 -513 -557 -1605 -269 -1083 352 262 921 52 -40 -98 32 -3 108 -13 178 452 37 218 263 750 493 268 26 824 -435 610 -664 193 -316 171 -131 -220 221 380 108 -528 -316 -214 900000 -1030 -611 -1483 4 -118 203 -241 -528 150 -202 -75 -884 427 -83 -617 -107 219 -543 473 89 -189 -887 100 -775 183 -193 -353 -538 -246 617 67 508 263 169 -1288 205 -856 -570 -677 -558 -586 625 -316 1042 312 240 -221 -207 -912 -389 608 73 512 277 1003 695 282 236 255 312 583 32 1527 1007 446 -159 514 -28 1041 405 920 35 213 225 -125 203 -859 -418 -980 -511 -1005 -719 -2278 -531 -1030 -293 305 1019 563 1073 -620 108 -444 -233 -42 -533 996 630 253 -523 -368 -1135 -392 -592 -666 -2031 -352 -1513 521 422 1506 87 -68 -153 46 -4 154 -20 285 753 62 352 412 1116 701 381 36 1175 -662 1000 -1168 348 -591 323 -265 -462 472 823 232 -1101 -625 -422 SS 20230802T122222.1Z 8614.515534 236 1 49.85 2 70.23 83.65 102.81 254.92 0.00 1 0.00 1 0 25 5.948e-02 6.735e-03 3.917e-02 3.718e-03 4.009740e-01 1.926812e-03 4.787427e-03 -6.000000e+00 3.457433e-02 232.28 -2.00 3.54 -2.00 319.38 0.00e+00 1.237228e-03 5.000734e-04 3.549784e-04 -6.000000e+00 1.527826e-03 288.19 -2.00 20.00 -2.00 318.59 0.00e+00 2.923 0.000 302.00 328.00 3 3.7832e+00 5.4376e-03 3.5992e-02 -6.0000e+00 8.6747e-02 6.2984e-02 6.3607e-03 2.1572e-02 -6.0000e+00 9.3481e-02 -2.3508e-02 4.7605e-03 1.0613e-02 -6.0000e+00 5.5620e-02 5.6902e-03 2.5113e-03 3.0895e-03 -6.0000e+00 2.4053e-02 4.0411e-04 -7.7136e-04 1.0600e-04 3.2616e-05 -6.0000e+00 1.5680e-03 -3.0131e-02 -1.0895e-05 11 8 0 10 0 0 72.41 16.12 0.45 -0.03013 -0.03593 18 4 1 5 0 2768.860 22.19 15.00 16.12 28.38 29.9 1021.69 900000 -10237 -15453 -22502 7512 -29368 -3728 -25871 -14467 -16057 -22874 -5889 -17798 -7897 -13436 -9376 -6659 4277 -5424 12838 -3754 -1198 -4007 -4133 -5258 9398 -6130 1297 -5969 -125 -2241 2270 -348 -1855 -2091 -5505 1039 -2684 -977 -2185 1075 71 1079 251 1599 1855 1863 -684 527 -860 753 710 -2 1052 2520 1561 114 103 879 737 -408 258 1913 3595 2463 1435 243 -604 -1262 1451 -374 577 619 345 312 -607 -916 -2139 -1403 -907 -827 -1933 -1833 -2143 -1046 -1133 -55 428 1145 236 982 323 571 -838 -277 47 392 705 602 459 -866 -550 -1017 -755 -508 -575 -1305 -238 -554 140 212 749 385 457 226 -87 44 -442 -74 209 271 -272 384 84 570 244 120 227 357 47 615 -101 -91 -420 156 -224 -70 86 520 29 -253 -260 -606 900000 -277 -484 -771 176 -900 -88 -844 -481 -603 -957 -210 -786 -377 -815 -643 -496 304 -454 943 -340 -107 -367 -398 -551 904 -715 139 -645 -12 -236 257 -45 -272 -309 -787 141 -428 -184 -505 279 20 319 77 489 569 575 -215 163 -272 245 252 -1 432 1083 701 53 49 411 336 -188 124 995 1862 1384 803 139 -335 -715 819 -245 404 445 244 208 -407 -552 -1208 -785 -560 -589 -1448 -1519 -1894 -964 -1123 -58 467 1266 261 1021 311 503 -704 -236 44 413 833 793 633 -1170 -682 -1152 -817 -579 -710 -1702 -323 -795 215 324 1212 631 720 361 -129 62 -642 -114 342 462 -465 633 134 868 356 167 304 499 72 1020 -179 -153 -732 284 -437 -143 178 1091 60 -510 -501 -1116 SS 20230802T122815.2Z 8614.519621 239 1 48.48 2 69.14 84.60 103.80 255.83 0.00 1 0.00 1 0 25 4.396e-02 6.525e-03 2.909e-02 2.964e-03 3.815949e-01 1.541362e-03 4.553569e-03 -6.000000e+00 2.555468e-02 232.28 -2.00 3.54 -2.00 319.20 0.00e+00 8.411424e-04 3.806685e-04 3.184692e-04 -6.000000e+00 1.129187e-03 288.19 -2.00 20.00 -2.00 318.41 0.00e+00 2.781 0.000 302.00 328.00 3 3.5601e+00 4.3198e-03 3.4236e-02 -6.0000e+00 6.4117e-02 5.1961e-02 5.0130e-03 2.0489e-02 -6.0000e+00 6.9092e-02 -5.6514e-03 3.6601e-03 1.0059e-02 -6.0000e+00 4.1109e-02 -4.1625e-03 1.9328e-03 2.8630e-03 -6.0000e+00 1.7780e-02 5.9469e-04 -6.6019e-04 8.4819e-05 2.9428e-05 -6.0000e+00 1.1588e-03 -3.0978e-02 -1.9988e-05 11 8 0 10 0 0 41.40 16.12 0.24 -0.03098 -0.03594 23 5 1 5 0 2107.440 22.19 15.00 16.12 28.60 29.9 1023.57 900000 2463 -7726 3541 -23877 -1739 -22726 2568 -19640 14203 -10705 1159 -14978 -196 -9231 7010 -4504 3655 2971 622 -376 -425 1932 -2083 -3887 -1375 1707 -5093 449 -5954 4742 -3588 5746 -4212 1293 -6069 -347 -6088 -434 -1352 854 -1114 445 -816 -375 63 -216 342 -784 1661 -1244 1633 -516 1680 89 1988 780 1918 111 960 -1160 2503 723 2353 1641 602 -259 -889 -217 225 765 612 837 -204 1172 -1398 -205 -2047 -95 -1091 -561 -848 -1145 -2092 -1158 -1030 -361 334 795 875 747 924 -223 -70 -349 410 -299 1277 347 237 -410 -522 -1498 -587 -551 -532 -1217 -710 -527 -270 377 340 619 225 288 -182 105 -426 437 333 243 -433 382 -41 818 180 226 488 590 209 257 -224 -184 -79 -131 255 -549 341 -44 254 -460 148 -525 900000 68 -259 108 -881 -47 -752 73 -797 457 -460 44 -740 -10 -610 461 -370 294 256 58 -37 -42 187 -220 -450 -165 207 -650 51 -691 515 -474 774 -692 202 -953 -52 -1097 -89 -339 232 -334 138 -264 -122 20 -71 110 -266 551 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