File name: Pandora147s1_SWDetroitMI_20231028_L2Fit_fout2c9d20221206p1-8.txt File generation date: 20260323T005424.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v9d20221206.txt Level 1 file used: Pandora147s1_SWDetroitMI_20231028_L1_smca1c9d20221206p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20231028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 236 378 Nominal wavelengths inside fitting window [nm]: 305.0989 305.2398 305.3807 305.5215 305.6624 305.8032 305.9440 306.0848 306.2256 306.3664 306.5072 306.6479 306.7887 306.9294 307.0701 307.2108 307.3516 307.4922 307.6329 307.7736 307.9143 308.0549 308.1955 308.3362 308.4768 308.6174 308.7580 308.8985 309.0391 309.1797 309.3202 309.4607 309.6013 309.7418 309.8823 310.0227 310.1632 310.3037 310.4441 310.5846 310.7250 310.8654 311.0058 311.1462 311.2866 311.4270 311.5673 311.7077 311.8480 311.9883 312.1286 312.2689 312.4092 312.5495 312.6898 312.8300 312.9703 313.1105 313.2507 313.3909 313.5311 313.6713 313.8115 313.9517 314.0918 314.2319 314.3721 314.5122 314.6523 314.7924 314.9325 315.0725 315.2126 315.3526 315.4927 315.6327 315.7727 315.9127 316.0527 316.1927 316.3326 316.4726 316.6125 316.7525 316.8924 317.0323 317.1722 317.3121 317.4519 317.5918 317.7317 317.8715 318.0113 318.1511 318.2909 318.4307 318.5705 318.7103 318.8500 318.9898 319.1295 319.2692 319.4089 319.5486 319.6883 319.8280 319.9677 320.1073 320.2469 320.3866 320.5262 320.6658 320.8054 320.9450 321.0845 321.2241 321.3636 321.5032 321.6427 321.7822 321.9217 322.0612 322.2007 322.3401 322.4796 322.6190 322.7584 322.8979 323.0373 323.1767 323.3160 323.4554 323.5948 323.7341 323.8734 324.0128 324.1521 324.2914 324.4307 324.5699 324.7092 324.8485 324.9877 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231028T125359.8Z 8701.537497 281 1 48.55 2 81.67 116.35 102.75 298.75 0.00 1 0.00 1 0 17 5.405e-01 1.025e-02 2.548e-01 5.454e-03 6.929128e-01 2.898312e-03 7.788230e-03 -6.000000e+00 3.002693e-01 224.48 -2.00 3.54 -2.00 321.71 0.00e+00 4.969305e-03 1.590175e-03 2.019380e-03 -6.000000e+00 1.336120e-02 280.65 -2.00 20.00 -2.00 321.19 0.00e+00 6.484 0.005 302.00 328.00 3 6.8896e-01 1.0629e-02 7.3433e-02 -6.0000e+00 7.4109e-01 1.7022e-01 1.5469e-02 3.8620e-02 -6.0000e+00 8.0890e-01 -2.0744e-01 1.6305e-02 2.1741e-02 -6.0000e+00 4.8242e-01 7.6747e-02 7.5178e-03 8.3679e-03 -6.0000e+00 2.0509e-01 2.5140e-04 -8.6255e-04 1.5196e-04 1.1428e-04 -6.0000e+00 1.4182e-02 -3.5420e-03 -3.3852e-05 12 8 8 10 0 0 99.72 16.17 0.38 -0.00354 -0.01002 131 30 1 5 0 370.530 22.29 15.00 16.17 17.37 30.4 930.35 24096 -205054 -104827 -223267 -169696 -220876 -248404 -125801 -160657 -199834 -118140 24608 -142226 -29703 -89860 -51700 -62263 -54719 -39977 -54195 10737 -43920 -34940 -22779 -31570 -3582 -13282 -58602 -43279 -35713 -25794 -16619 2519 -9346 -24299 -13691 -1869 -13483 -966 -1673 4584 16399 18853 6652 10411 2056 6044 2503 3751 5441 3659 12764 9342 5204 1926 3876 6255 2492 2456 4591 3403 3889 7458 8956 6696 4712 2044 2018 3238 6166 1703 2216 3087 214 2424 2000 -2433 -4634 -1118 258 -648 -2003 -2221 -2673 294 337 165 863 2058 665 1500 -456 -1458 -730 -1163 -878 56 1061 -53 -734 -1087 -1530 -1716 -685 -2192 -1871 -1951 -953 102 32 657 558 9 -44 -550 -326 -344 -72 528 696 214 574 552 920 944 -261 435 490 406 436 102 -206 -196 -372 79 -177 264 151 192 232 -314 -348 -570 128 -2280 -558 -3023 -1354 -2670 -4324 -803 -1624 -2899 -880 131 -2118 -190 -1338 -632 -960 -873 -595 -980 103 -724 -558 -351 -571 -51 -212 -1434 -921 -798 -645 -460 67 -293 -840 -430 -59 -574 -45 -93 242 907 1073 399 614 136 397 179 281 437 338 1210 1007 637 257 528 853 348 332 604 477 611 1305 1745 1389 973 434 451 809 1729 544 726 978 65 652 486 -589 -1203 -326 89 -265 -947 -1146 -1468 168 205 105 561 1310 409 853 -249 -786 -416 -764 -674 50 1067 -58 -796 -1091 -1376 -1429 -583 -2049 -1837 -2035 -1063 125 45 1008 900 15 -69 -814 -467 -504 -111 859 1163 351 898 836 1343 1328 -358 579 702 668 814 209 -449 -413 -841 190 -449 678 393 496 571 -726 -826 -1332 SS 20231028T131029.9Z 8701.548957 286 1 48.75 2 78.97 119.38 105.23 301.83 0.00 1 0.00 1 0 25 2.445e-01 5.695e-03 5.406e-02 1.577e-03 5.667906e-01 8.162690e-04 6.430325e-03 -6.000000e+00 1.358304e-01 224.48 -2.00 3.54 -2.00 321.01 0.00e+00 2.381301e-03 3.629911e-04 1.098679e-03 -6.000000e+00 6.043966e-03 280.65 -2.00 20.00 -2.00 320.42 0.00e+00 5.041 0.002 302.00 328.00 3 2.7499e-01 2.6517e-03 5.7304e-02 -6.0000e+00 3.3524e-01 5.1738e-02 3.5031e-03 3.0148e-02 -6.0000e+00 3.6591e-01 -4.2394e-02 3.4639e-03 1.6108e-02 -6.0000e+00 2.1823e-01 7.9331e-03 1.6936e-03 5.4558e-03 -6.0000e+00 9.2777e-02 1.6480e-03 -6.7767e-04 4.5161e-05 6.2643e-05 -6.0000e+00 6.4151e-03 -3.6378e-03 -3.3519e-05 10 0 0 10 0 0 54.84 16.16 0.30 -0.00364 -0.00873 382 88 1 5 0 127.600 22.29 15.00 16.16 18.57 30.6 940.62 -76792 -74661 -82671 -68685 -99620 -104952 -90220 -61227 -76417 -50628 -69366 -53863 -38946 -31338 -40764 -42337 -14140 -24053 -15483 -11885 -19145 -13710 -19166 -11438 -6677 -11713 -9336 -15331 -11712 -13050 -4301 -1517 699 -3740 -8078 -4610 -9530 -2153 -2228 -162 -881 1461 533 504 647 653 681 1622 1207 1303 2226 3884 3460 3571 3514 1182 1653 114 52 808 1777 2163 3163 2857 1701 417 176 -701 1441 1328 1605 723 968 627 125 -589 -2293 -2132 -1946 -1236 -1145 -1111 -1989 -1465 -993 -109 200 665 921 671 806 -360 -541 -457 -227 54 660 720 273 -112 -493 -1322 -885 -686 -878 -1034 -681 -616 143 366 733 524 290 -56 -333 -158 -26 150 86 98 88 318 365 562 232 -226 162 465 192 139 -198 -182 -377 -198 -32 -213 196 337 205 14 -92 -222 -304 -579 -632 -801 -549 -996 -1114 -916 -537 -881 -483 -832 -638 -503 -477 -846 -1048 -294 -607 -386 -302 -533 -363 -569 -345 -207 -403 -316 -530 -387 -478 -171 -69 36 -208 -445 -248 -553 -140 -179 -15 -92 159 61 59 77 80 84 205 160 184 348 664 647 721 747 267 382 27 12 180 412 557 915 920 566 135 56 -233 527 559 734 345 451 275 50 -214 -798 -758 -784 -585 -626 -686 -1339 -1038 -751 -87 168 567 777 542 603 -254 -367 -323 -180 49 687 778 316 -128 -568 -1378 -859 -691 -960 -1192 -826 -732 185 525 1144 849 462 -85 -476 -217 -37 220 134 159 142 491 546 808 351 -329 227 690 295 239 -368 -355 -771 -430 -74 -517 483 843 510 33 -207 -474 -641 SS 20231028T131608.6Z 8701.552877 289 1 48.75 2 78.07 120.43 106.06 302.90 0.00 1 0.00 1 0 25 1.919e-01 5.460e-03 3.299e-02 1.199e-03 5.315772e-01 6.138643e-04 6.123387e-03 -6.000000e+00 1.065911e-01 224.48 -2.00 3.54 -2.00 320.72 0.00e+00 1.617577e-03 2.510207e-04 8.896546e-04 -6.000000e+00 4.742325e-03 280.65 -2.00 20.00 -2.00 320.11 0.00e+00 4.689 0.002 302.00 328.00 3 1.8636e-01 1.9330e-03 5.3419e-02 -6.0000e+00 2.6308e-01 4.0757e-02 2.4769e-03 2.8191e-02 -6.0000e+00 2.8714e-01 -2.9231e-02 2.3453e-03 1.4610e-02 -6.0000e+00 1.7125e-01 2.6280e-03 1.1658e-03 4.5903e-03 -6.0000e+00 7.2810e-02 2.5969e-03 -5.8984e-04 3.4457e-05 5.4547e-05 -6.0000e+00 5.0338e-03 -3.7018e-03 -1.5150e-05 10 0 0 10 0 0 84.11 16.16 0.22 -0.00370 -0.00813 503 116 1 5 0 96.900 22.29 15.00 16.16 18.90 30.5 942.81 -77348 -70490 -49370 -65927 -72705 -70040 -72893 -56463 -53402 -45031 -53309 -37909 -39037 -17606 -26349 -14523 -17350 -12436 -6627 -2119 -8970 -11107 -10508 -10009 -8868 -7480 -4427 -12220 -10745 -13354 -3241 -3339 1251 -3995 -3908 -6323 -4155 -3162 621 254 1253 868 545 718 883 581 634 -18 -227 1271 1925 2670 2447 2781 1089 2145 1311 1141 -788 666 589 2147 3331 2937 1193 690 -362 -324 1158 684 1349 618 682 359 -182 -1062 -1836 -1710 -1197 -1218 -928 -1458 -1844 -1501 -732 -107 294 560 854 697 307 29 -616 -253 -140 91 551 890 316 -141 -663 -1074 -882 -275 -1024 -1024 -744 -604 50 331 647 499 268 59 -343 -154 2 111 180 -8 73 214 377 430 384 -221 160 512 289 138 -201 -158 -363 -205 -123 -153 190 354 207 61 -96 -160 -330 -859 -833 -497 -740 -799 -754 -895 -680 -706 -585 -779 -541 -703 -321 -644 -367 -497 -371 -200 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