File name: Pandora147s1_SWDetroitMI_20231030_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20231103T032807.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20231030_L1_smca1c1d20210609p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20231030 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231030T153343.1Z 8703.648416 365 1 49.03 2 60.88 151.30 101.71 315.59 0.00 1 0.00 1 0 17 8.149e-02 1.934e-02 7.711e-02 1.933e-02 2.539171e-01 9.636505e-03 3.270842e-03 -6.000000e+00 4.604213e-02 224.29 -2.00 3.54 -2.00 317.94 0.00e+00 1.995904e-03 1.618647e-03 7.451448e-04 -6.000000e+00 2.023863e-03 280.38 -2.00 20.00 -2.00 317.28 0.00e+00 2.045 0.000 302.00 328.00 3 6.5660e+00 2.5516e-02 2.3920e-02 -6.0000e+00 1.1367e-01 7.6375e-02 2.8806e-02 1.3201e-02 -6.0000e+00 1.2330e-01 5.1645e-03 1.7998e-02 6.6887e-03 -6.0000e+00 7.3494e-02 1.1955e-03 9.3118e-03 2.1073e-03 -6.0000e+00 3.2171e-02 7.1672e-05 -7.2070e-04 5.4949e-04 2.1637e-05 -6.0000e+00 2.1411e-03 -4.2277e-02 7.1933e-05 12 8 8 10 0 0 99.81 16.17 0.70 -0.04228 -0.04769 21 5 1 5 0 2334.140 22.29 15.00 16.17 11.90 29.7 886.17 900000 36962 -33883 2227 -11047 -17016 6940 16058 18201 1069 51369 13164 -13734 -13518 -14719 -15106 1619 10911 -3068 -2800 -3163 -5170 -5556 -9216 7964 17344 3551 1075 1305 -10802 12764 8112 5829 8562 3521 -7568 -5482 -7393 2149 -2036 -5253 -12 -2765 5793 511 1390 2394 5716 1713 -2001 2968 2918 -110 5461 -1696 4833 73 1719 2412 -2520 -1341 1097 1489 2514 2384 2133 3456 -4322 1081 2445 -1856 157 -588 1017 2722 -5062 4048 -3690 -2577 -1420 -1308 -2141 -2320 -1361 -3220 -2326 302 83 474 2214 -1064 -1317 117 -3184 -128 -3309 -1063 1378 2602 831 -281 -1487 -1385 -1761 -700 -691 -1160 -2365 1725 -266 70 3138 2837 944 -1050 -567 -1360 -941 687 -1540 1729 2010 1901 -381 815 -366 358 555 -827 476 531 -101 -1542 -1609 459 541 -717 1427 309 994 -1087 -1366 -597 900000 2508 -4586 222 -1150 -1665 543 1226 1526 111 3485 1278 -1738 -1953 -2497 -2942 291 1851 -622 -588 -690 -1160 -1232 -2167 1658 3440 832 254 287 -2520 2360 1689 1350 2090 907 -2010 -1417 -2156 671 -795 -2433 -6 -1397 2761 258 696 1186 2678 815 -968 1383 1446 -60 2975 -1040 2837 46 1072 1477 -1586 -834 694 1017 1848 1855 1625 2370 -2975 695 1688 -1518 136 -529 890 2238 -4143 2834 -2532 -1685 -984 -1027 -1808 -2152 -1321 -3335 -2564 347 100 585 2669 -1262 -1511 120 -3090 -119 -3405 -1187 1669 3435 1166 -386 -1918 -1632 -1996 -828 -887 -1571 -3387 2475 -410 114 5230 4739 1530 -1601 -787 -1802 -1252 946 -2333 2687 3154 2927 -583 1173 -506 466 686 -1057 646 770 -154 -2429 -2580 753 941 -1319 2627 586 1872 -2025 -2454 -1022 SS 20231030T162908.7Z 8703.686906 399 1 48.98 2 57.18 166.40 107.76 326.56 0.00 1 0.00 1 0 17 1.147e-02 6.421e-03 5.041e-04 1.893e-04 2.309284e-01 9.448629e-05 2.864586e-03 -6.000000e+00 6.476359e-03 224.29 -2.00 3.54 -2.00 317.00 0.00e+00 5.304967e-04 1.249069e-05 1.143248e-04 -6.000000e+00 2.848072e-04 280.38 -2.00 20.00 -2.00 316.33 0.00e+00 1.839 0.000 302.00 328.00 3 -3.0320e-01 2.4628e-04 2.1501e-02 -6.0000e+00 1.5989e-02 1.0839e-02 2.7602e-04 1.1858e-02 -6.0000e+00 1.7345e-02 -4.2718e-03 1.6505e-04 5.9152e-03 -6.0000e+00 1.0339e-02 -9.4170e-04 8.2003e-05 1.7294e-03 -6.0000e+00 4.5240e-03 9.1376e-02 -5.8919e-04 5.3027e-06 1.8898e-05 -6.0000e+00 3.0133e-04 -4.0775e-02 3.5299e-05 11 8 0 10 0 0 96.78 16.17 0.26 -0.04077 -0.04520 2312 535 1 5 0 21.070 22.29 14.99 16.17 12.86 29.8 894.41 900000 -662 -727 -1462 -3815 -4525 -3493 -2101 -691 -867 -2565 -3671 -2733 -1705 -563 297 -79 198 601 1015 1096 436 435 953 747 785 743 64 -867 -919 164 932 1603 1447 -1314 -3015 -3043 -2651 -1082 -172 -158 -427 -283 -299 -339 163 -80 -175 -299 -609 242 698 937 1224 1001 856 1103 829 475 213 373 880 1398 2022 1660 315 -415 -1048 -822 465 532 495 413 437 456 -8 -455 -1204 -1561 -989 -1009 -1084 -1443 -2041 -1692 -1053 -493 -16 328 518 503 459 -104 -505 -158 -10 94 744 903 410 -66 -512 -1087 -798 -285 -809 -803 -643 -674 24 410 659 564 379 116 -232 -84 -6 136 314 211 91 305 357 555 550 91 314 638 432 349 18 -164 -307 -122 31 -155 158 108 5 -181 -416 -712 900000 -93 -109 -221 -538 -569 -423 -271 -99 -138 -425 -598 -458 -320 -120 71 -20 52 164 285 318 128 126 283 235 259 252 21 -272 -269 47 284 523 510 -475 -1022 -1030 -993 -472 -81 -85 -249 -171 -185 -210 100 -49 -105 -174 -347 138 421 602 826 708 620 813 621 353 155 272 666 1137 1771 1408 263 -346 -816 -629 384 456 459 395 414 413 -7 -373 -902 -1129 -761 -878 -968 -1418 -2129 -1845 -1226 -611 -19 402 629 630 529 -109 -487 -149 -11 106 922 1136 540 -84 -662 -1299 -916 -345 -1071 -1030 -861 -942 36 635 1066 911 582 165 -302 -112 -8 179 443 317 138 456 519 768 784 124 405 838 611 487 26 -245 -465 -193 52 -253 264 184 8 -301 -720 -1191 SS 20231030T163507.7Z 8703.691061 403 1 48.99 2 56.94 168.11 108.31 327.82 0.00 1 0.00 1 0 17 1.151e-02 6.445e-03 4.819e-04 1.842e-04 2.297233e-01 9.196829e-05 2.842629e-03 -6.000000e+00 6.500442e-03 224.29 -2.00 3.54 -2.00 316.94 0.00e+00 5.398846e-04 1.199574e-05 1.049210e-04 -6.000000e+00 2.858982e-04 280.38 -2.00 20.00 -2.00 316.28 0.00e+00 1.827 0.000 302.00 328.00 3 -3.4152e-01 2.3925e-04 2.1361e-02 -6.0000e+00 1.6049e-02 1.1068e-02 2.6813e-04 1.1782e-02 -6.0000e+00 1.7410e-02 -4.2287e-03 1.6026e-04 5.8691e-03 -6.0000e+00 1.0377e-02 -8.4739e-04 7.9626e-05 1.7127e-03 -6.0000e+00 4.5405e-03 9.6206e-02 -6.3023e-04 5.1542e-06 1.8558e-05 -6.0000e+00 3.0249e-04 -4.0650e-02 1.5926e-05 11 8 0 10 0 0 51.99 16.15 0.27 -0.04065 -0.04539 2378 551 1 5 0 20.490 22.29 15.00 16.15 13.21 30.0 898.46 900000 -584 -522 -1465 -3676 -4506 -3645 -2071 -796 -764 -2688 -3657 -2819 -1624 -484 407 -148 215 569 963 1194 461 496 957 812 759 846 45 -843 -931 176 831 1605 1460 -1367 -3013 -3065 -2684 -1079 -282 -134 -439 -302 -308 -300 229 -72 -170 -310 -574 274 762 965 1251 1016 864 1096 822 461 226 375 869 1396 2030 1675 324 -438 -1064 -798 466 556 492 437 426 450 11 -451 -1267 -1506 -1005 -1032 -1093 -1429 -2036 -1697 -1048 -477 -11 347 545 481 484 -133 -511 -154 9 102 759 888 433 -48 -460 -1099 -805 -329 -806 -800 -650 -621 19 427 682 564 388 131 -230 -65 -57 137 337 204 100 312 380 562 583 112 317 607 438 355 -8 -169 -306 -97 30 -184 147 103 5 -194 -406 -725 900000 -84 -80 -227 -528 -579 -452 -272 -117 -123 -454 -608 -483 -310 -105 99 -39 58 158 275 352 138 146 289 259 255 292 15 -269 -277 52 257 532 522 -501 -1036 -1052 -1021 -477 -135 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