File name: Pandora147s1_SWDetroitMI_20231107_L2Fit_fout2c9d20221206p1-8.txt File generation date: 20260323T005513.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v9d20221206.txt Level 1 file used: Pandora147s1_SWDetroitMI_20231107_L1_smca1c9d20221206p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20231107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 236 378 Nominal wavelengths inside fitting window [nm]: 305.0989 305.2398 305.3807 305.5215 305.6624 305.8032 305.9440 306.0848 306.2256 306.3664 306.5072 306.6479 306.7887 306.9294 307.0701 307.2108 307.3516 307.4922 307.6329 307.7736 307.9143 308.0549 308.1955 308.3362 308.4768 308.6174 308.7580 308.8985 309.0391 309.1797 309.3202 309.4607 309.6013 309.7418 309.8823 310.0227 310.1632 310.3037 310.4441 310.5846 310.7250 310.8654 311.0058 311.1462 311.2866 311.4270 311.5673 311.7077 311.8480 311.9883 312.1286 312.2689 312.4092 312.5495 312.6898 312.8300 312.9703 313.1105 313.2507 313.3909 313.5311 313.6713 313.8115 313.9517 314.0918 314.2319 314.3721 314.5122 314.6523 314.7924 314.9325 315.0725 315.2126 315.3526 315.4927 315.6327 315.7727 315.9127 316.0527 316.1927 316.3326 316.4726 316.6125 316.7525 316.8924 317.0323 317.1722 317.3121 317.4519 317.5918 317.7317 317.8715 318.0113 318.1511 318.2909 318.4307 318.5705 318.7103 318.8500 318.9898 319.1295 319.2692 319.4089 319.5486 319.6883 319.8280 319.9677 320.1073 320.2469 320.3866 320.5262 320.6658 320.8054 320.9450 321.0845 321.2241 321.3636 321.5032 321.6427 321.7822 321.9217 322.0612 322.2007 322.3401 322.4796 322.6190 322.7584 322.8979 323.0373 323.1767 323.3160 323.4554 323.5948 323.7341 323.8734 324.0128 324.1521 324.2914 324.4307 324.5699 324.7092 324.8485 324.9877 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231107T153556.1Z 8711.649955 339 1 0.54 2 63.01 152.87 43.83 234.43 0.00 1 0.00 1 0 17 1.444e-02 6.957e-03 6.524e-03 2.653e-03 2.811809e-01 1.305449e-03 3.441963e-03 -6.000000e+00 7.998793e-03 223.58 -2.00 3.54 -2.00 316.75 0.00e+00 5.098029e-04 1.644536e-04 7.226224e-05 -6.000000e+00 3.550516e-04 279.37 -2.00 20.00 -2.00 316.09 0.00e+00 2.192 0.000 302.00 328.00 3 9.1641e-01 3.3839e-03 2.5687e-02 -6.0000e+00 1.9711e-02 2.3187e-02 3.8136e-03 1.4280e-02 -6.0000e+00 2.1529e-02 -7.9841e-03 2.2500e-03 7.0994e-03 -6.0000e+00 1.2839e-02 1.9072e-03 1.0857e-03 2.0377e-03 -6.0000e+00 5.4658e-03 1.7751e-02 -6.2670e-04 7.3158e-05 2.2982e-05 -6.0000e+00 3.7881e-04 -6.7697e-03 -2.3660e-05 12 9 1 12 1 1 19.97 16.20 0.36 -0.00677 -0.01148 7 169 1 5 0 66.820 22.29 14.99 16.20 17.60 30.6 940.16 -3536 1468 -1844 -3333 -7780 -1687 -4513 -61 -3496 -3040 -4954 -3566 -1663 -260 1195 358 1529 169 3053 -1386 554 -100 1411 1250 2160 -183 693 -1549 -289 -929 803 1255 1662 -1413 -2339 -1754 -3214 132 132 279 -719 329 -408 1082 -931 422 -435 133 -1241 789 340 1143 1239 918 799 1363 306 689 110 306 1070 1109 2124 1484 209 -250 -538 -962 1221 408 398 13 316 -25 -202 -489 -1514 -1094 -1389 -727 -735 -1561 -2228 -1774 -1158 -498 -360 206 756 628 344 331 -305 -52 188 7 891 630 410 -155 -474 -1024 -723 -318 -760 -718 -466 -768 298 374 465 477 592 227 -33 68 -186 -147 444 -6 -95 221 363 623 621 225 721 852 305 488 5 327 -549 161 -362 -122 258 40 -238 -15 -357 -735 -378 -534 229 -300 -506 -1096 -218 -647 -10 -625 -561 -916 -682 -327 -59 304 101 442 48 871 -428 170 -30 437 413 747 -67 248 -528 -91 -296 272 462 663 -587 -908 -673 -1290 60 68 156 -440 208 -267 699 -613 274 -279 83 -774 490 226 764 876 685 614 1006 232 515 86 237 807 907 1777 1328 186 -216 -436 -774 1049 381 382 13 311 -23 -185 -424 -1205 -888 -1148 -643 -695 -1561 -2379 -1978 -1316 -576 -437 255 927 735 389 357 -320 -53 199 8 1060 798 546 -202 -598 -1244 -836 -386 -963 -916 -621 -1031 418 541 708 730 865 321 -45 87 -241 -200 621 -8 -138 327 519 885 839 302 919 1108 414 681 8 490 -816 249 -575 -195 421 67 -398 -25 -577 -1146 -601 SS 20231107T153947.9Z 8711.652638 342 1 47.78 2 62.69 153.85 44.42 235.47 0.00 1 0.00 1 0 17 2.119e-02 6.432e-03 1.218e-02 2.861e-03 2.785424e-01 1.392346e-03 3.359352e-03 -6.000000e+00 1.174146e-02 223.58 -2.00 3.54 -2.00 318.18 0.00e+00 4.794683e-04 2.520777e-04 1.840747e-04 -6.000000e+00 5.208683e-04 279.37 -2.00 20.00 -2.00 317.48 0.00e+00 2.168 0.000 302.00 328.00 3 4.6248e+00 3.7137e-03 2.5428e-02 -6.0000e+00 2.8935e-02 4.8784e-02 4.2409e-03 1.4166e-02 -6.0000e+00 3.1595e-02 -2.7146e-04 2.7037e-03 7.0599e-03 -6.0000e+00 1.8843e-02 -3.9037e-03 1.3879e-03 2.0420e-03 -6.0000e+00 8.0278e-03 4.4038e-04 1.4281e-04 8.1914e-05 2.1840e-05 -6.0000e+00 5.5541e-04 -9.0255e-03 9.0052e-05 12 9 1 12 1 1 99.99 16.19 0.43 -0.00903 -0.00795 41 10 1 5 0 1137.370 22.29 15.00 16.19 17.68 30.6 941.34 -3371 -1030 1701 -9321 -4932 -14261 -1774 -4931 -1840 -5775 -5606 -7493 -2466 -2352 1309 -816 -427 1610 2178 1178 -93 543 960 2320 278 823 -716 -1855 -1193 818 -439 1177 2069 -1080 -3648 -2416 -2974 -619 548 147 268 -153 306 -836 27 -760 688 -778 -146 -491 404 519 1496 1118 1385 501 450 397 518 99 912 1225 2155 1966 183 93 -1026 -381 610 1142 667 876 267 -28 -150 -345 -1497 -1677 -745 -1308 -924 -1505 -2082 -1775 -987 -651 273 708 748 368 865 -219 -579 -689 57 135 745 653 358 -347 -561 -1237 -609 -286 -913 -824 -616 -340 276 415 489 830 117 263 -390 123 -313 101 -51 137 -133 353 279 488 634 -75 319 569 430 373 91 -308 -113 -490 -17 -39 403 185 308 -58 -353 -391 -588 -256 -83 135 -757 -363 -1122 -133 -433 -174 -589 -561 -800 -286 -296 182 -127 -69 266 372 211 -17 104 189 479 62 189 -164 -401 -240 162 -95 273 517 -281 -903 -586 -805 -194 192 60 118 -70 144 -399 13 -361 315 -354 -65 -223 194 267 806 636 807 301 275 240 305 59 555 806 1530 1485 138 65 -669 -244 422 894 568 770 233 -24 -116 -254 -1014 -1099 -519 -977 -773 -1393 -2055 -1830 -1084 -762 333 882 926 436 938 -218 -532 -627 56 146 891 866 499 -472 -710 -1441 -673 -332 -1159 -1097 -856 -493 395 636 789 1338 182 401 -548 164 -420 142 -77 220 -203 560 429 716 883 -100 403 732 598 558 143 -497 -186 -844 -29 -70 738 346 576 -106 -619 -700 -1037 SS 20231107T154440.8Z 8711.656028 345 1 47.48 2 62.30 155.10 45.17 236.75 0.00 1 0.00 1 0 17 4.675e-02 1.121e-02 3.586e-02 7.663e-03 2.787862e-01 3.748305e-03 3.419284e-03 -6.000000e+00 2.590429e-02 223.58 -2.00 3.54 -2.00 318.27 0.00e+00 -2.968178e-04 6.903902e-04 6.581078e-04 -6.000000e+00 1.149138e-03 279.37 -2.00 20.00 -2.00 317.57 0.00e+00 2.140 0.000 302.00 328.00 3 6.0136e+00 1.0042e-02 2.5346e-02 -6.0000e+00 6.3837e-02 7.4473e-02 1.1456e-02 1.4660e-02 -6.0000e+00 6.9706e-02 4.8838e-03 7.3506e-03 7.0764e-03 -6.0000e+00 4.1572e-02 -6.7958e-03 3.7840e-03 2.0612e-03 -6.0000e+00 1.7711e-02 1.1126e-04 2.1753e-04 2.1986e-04 2.1517e-05 -6.0000e+00 1.2253e-03 -8.4482e-03 1.1640e-04 12 9 9 12 9 1 99.99 16.20 0.85 -0.00845 -0.00681 14 3 1 5 0 3164.890 22.29 15.00 16.20 17.93 30.6 944.06 4914 31222 -2818 -10867 -7879 19733 8212 -5810 -8118 -7882 1887 -10703 4996 -5162 4988 -7734 3640 -4388 8458 -5842 -1282 -10136 10578 -1228 10760 -1298 5006 576 -539 3725 -2541 7278 142 3150 -7122 1933 -6897 -1373 -5797 1991 -3153 2850 -2113 3705 209 -859 -1870 279 -1567 -916 -908 1352 1722 250 -97 -70 999 -851 392 -598 2795 1215 1951 249 1029 -120 5863 -3112 2497 1165 2363 537 849 -253 -1415 -273 -1835 72 -2654 -1092 -1774 449 -2281 -665 -1168 478 -166 1124 -27 1361 -115 -291 -1025 -1944 -683 193 556 1094 913 -599 -641 -2183 -1160 -1453 -201 -1684 -118 -1242 682 935 1119 170 955 -199 -33 -1441 -447 186 230 672 436 1075 627 860 -474 681 218 1298 -777 -67 -1174 485 -737 121 370 -27 -126 129 492 0 -464 -221 -560 344 1822 -234 -897 -561 1039 526 -488 -777 -783 167 -1124 510 -674 673 -1294 565 -768 1354 -1118 -237 -2027 1777 -248 2041 -288 1026 115 -101 704 -524 1482 34 733 -1701 440 -1811 -404 -2154 792 -1429 1267 -1012 1679 98 -405 -869 124 -698 -411 -435 681 913 142 -57 -42 600 -515 228 -350 1642 785 1362 188 755 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