File name: Pandora147s1_SWDetroitMI_20231123_L2Fit_fout2c9d20221206p1-8.txt File generation date: 20260323T005605.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v9d20221206.txt Level 1 file used: Pandora147s1_SWDetroitMI_20231123_L1_smca1c9d20221206p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20231123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 236 378 Nominal wavelengths inside fitting window [nm]: 305.0989 305.2398 305.3807 305.5215 305.6624 305.8032 305.9440 306.0848 306.2256 306.3664 306.5072 306.6479 306.7887 306.9294 307.0701 307.2108 307.3516 307.4922 307.6329 307.7736 307.9143 308.0549 308.1955 308.3362 308.4768 308.6174 308.7580 308.8985 309.0391 309.1797 309.3202 309.4607 309.6013 309.7418 309.8823 310.0227 310.1632 310.3037 310.4441 310.5846 310.7250 310.8654 311.0058 311.1462 311.2866 311.4270 311.5673 311.7077 311.8480 311.9883 312.1286 312.2689 312.4092 312.5495 312.6898 312.8300 312.9703 313.1105 313.2507 313.3909 313.5311 313.6713 313.8115 313.9517 314.0918 314.2319 314.3721 314.5122 314.6523 314.7924 314.9325 315.0725 315.2126 315.3526 315.4927 315.6327 315.7727 315.9127 316.0527 316.1927 316.3326 316.4726 316.6125 316.7525 316.8924 317.0323 317.1722 317.3121 317.4519 317.5918 317.7317 317.8715 318.0113 318.1511 318.2909 318.4307 318.5705 318.7103 318.8500 318.9898 319.1295 319.2692 319.4089 319.5486 319.6883 319.8280 319.9677 320.1073 320.2469 320.3866 320.5262 320.6658 320.8054 320.9450 321.0845 321.2241 321.3636 321.5032 321.6427 321.7822 321.9217 322.0612 322.2007 322.3401 322.4796 322.6190 322.7584 322.8979 323.0373 323.1767 323.3160 323.4554 323.5948 323.7341 323.8734 324.0128 324.1521 324.2914 324.4307 324.5699 324.7092 324.8485 324.9877 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231123T131910.3Z 8727.554980 155 1 50.11 2 83.48 125.27 133.49 343.15 0.00 1 0.00 1 0 17 4.953e-01 3.837e-02 4.691e-01 3.387e-02 8.356022e-01 1.917087e-02 9.787338e-03 -6.000000e+00 2.800237e-01 222.76 -2.00 3.54 -2.00 322.09 0.00e+00 1.719375e-02 1.004867e-02 1.005055e-03 -6.000000e+00 1.391957e-02 277.49 -2.00 20.00 -2.00 321.64 0.00e+00 7.992 0.010 302.00 328.00 3 1.6969e+00 6.9069e-02 9.1592e-02 -6.0000e+00 6.9077e-01 1.2248e+00 8.4639e-02 5.6504e-02 -6.0000e+00 7.5807e-01 -1.4446e+00 6.6569e-02 2.2765e-02 -6.0000e+00 4.4929e-01 5.7074e-01 3.3296e-02 1.7588e-02 -6.0000e+00 1.9130e-01 1.5144e-05 -6.8526e-04 9.3239e-04 2.2191e-04 -6.0000e+00 1.3759e-02 -8.5025e-03 -1.1093e-05 12 8 8 10 0 0 98.93 16.15 0.86 -0.00850 -0.01365 15 3 1 5 0 3339.980 22.29 15.00 16.15 9.93 29.6 887.75 40338 900000 -83156 900000 -38554 900000 -134961 4401 900000 -5800 -131475 56363 15717 -71168 6439 -32916 900000 -28886 900000 -30429 900000 256442 900000 67955 900000 8206 900000 67743 900000 35781 46500 76522 -3168 40186 -66849 -9046 -24323 47831 900000 90744 37942 261121 69456 34458 1160 52895 -19725 112585 38341 13900 11237 55178 75149 18471 97255 36253 37480 84699 36612 41366 75636 31263 58013 35667 19577 3464 66503 6138 27028 10997 1908 19925 84 -2340 1315 21651 2653 -21565 -10741 20327 -7718 20292 -3481 4241 2049 8564 743 1787 -10585 5760 -8262 6407 -9822 -14400 -241 -6985 1660 -1572 -1580 -3952 575 -6013 16321 -3022 4749 -5153 -4928 -10641 1555 -4989 4133 420 3202 -105 -4577 -592 -1525 1004 -711 1299 665 4174 758 4241 -1285 4286 374 6466 -2054 2790 761 943 480 -255 -506 -894 -1810 1747 2660 -1197 -930 -1336 -1535 1329 900000 -5023 900000 -1270 900000 -7782 145 900000 -191 -6695 1857 518 -4050 212 -1873 900000 -1817 900000 -1914 900000 8450 900000 2239 900000 270 900000 2232 900000 1179 1532 2521 -190 1565 -6808 -488 -1603 1719 900000 2990 2046 8604 2913 2064 97 2694 -2127 3710 2527 1249 1144 3967 4727 2158 5244 3584 3593 4820 3180 3345 4984 3278 5387 4701 3167 643 6574 1158 4615 2503 509 4476 22 -568 272 3243 461 -5103 -2703 4567 -2705 6139 -1449 1715 896 3694 361 872 -5771 2536 -3885 2457 -4384 -7289 -124 -4603 1189 -1351 -1476 -3741 479 -4701 9240 -2109 3300 -4168 -4237 -10582 1551 -6142 5249 591 4431 -146 -6375 -774 -2065 1401 -1069 1953 971 5577 1010 5298 -1644 5020 448 7980 -3243 4839 1498 1991 1083 -620 -1324 -2443 -5053 4750 7060 -3113 -2227 -2974 -3329 SS 20231123T133858.9Z 8727.568738 161 1 48.68 2 80.56 128.91 134.23 349.63 0.00 1 0.00 1 0 17 5.061e-01 1.038e-02 2.238e-01 5.069e-03 6.896779e-01 2.668637e-03 7.782017e-03 -6.000000e+00 2.794584e-01 222.76 -2.00 3.54 -2.00 321.53 0.00e+00 2.969170e-03 1.359754e-03 2.749396e-03 -6.000000e+00 1.234212e-02 277.48 -2.00 20.00 -2.00 321.03 0.00e+00 5.807 0.004 302.00 328.00 3 1.3980e+00 9.2256e-03 6.7971e-02 -6.0000e+00 6.8788e-01 1.7068e-01 1.3188e-02 3.9712e-02 -6.0000e+00 7.5188e-01 -2.0231e-01 1.4046e-02 2.2195e-02 -6.0000e+00 4.4818e-01 7.4346e-02 6.6062e-03 7.3812e-03 -6.0000e+00 1.9090e-01 2.2887e-04 -8.0683e-04 1.3946e-04 9.7996e-05 -6.0000e+00 1.3267e-02 -9.4766e-03 -1.8244e-05 12 8 8 10 0 0 99.89 16.13 0.32 -0.00948 -0.01554 82 19 1 5 0 593.510 22.29 14.99 16.13 10.83 29.7 895.15 -158037 -168901 -179268 -157847 -176500 -28564 -204758 155410 -208726 -45143 -200679 -74776 -114365 -59993 -88050 -34596 -52093 -29421 -39455 -22971 -32986 -48286 -40018 -41673 -15114 -47773 10768 -58650 -14802 -37561 180 -19340 6516 -9981 18419 -6788 458 -6796 1709 -2093 4789 9703 8561 3710 2805 6712 8880 9299 3475 12688 2892 14574 6484 13660 3686 9430 702 7210 269 5465 4353 4415 6818 5787 2797 3218 4308 1814 2546 2395 4281 1034 3630 -959 1870 -3315 -1424 -5296 -837 -1038 -996 -2571 -2203 -2284 -951 267 241 944 886 1147 -910 -273 -2079 41 -1713 48 -122 928 5 -99 -1032 -1618 -1917 -561 -1850 -1164 -1002 -952 102 375 958 325 396 -336 239 -129 427 -53 541 -155 689 139 1134 323 629 18 87 597 243 305 -122 -212 -295 -351 -212 -137 223 418 -45 165 -337 -58 -481 -1207 -1670 -2095 -1419 -1745 -141 -2945 768 -4033 -223 -4058 -554 -1639 -652 -1610 -445 -901 -451 -722 -375 -603 -1026 -831 -968 -291 -1346 170 -1798 -293 -1040 4 -660 200 -345 501 -238 17 -293 84 -127 303 628 589 273 212 501 666 727 305 1101 312 1572 833 1780 561 1415 118 1121 43 823 693 786 1363 1321 686 767 1013 458 720 784 1501 387 1290 -333 571 -955 -382 -1537 -268 -399 -449 -1345 -1251 -1374 -604 178 169 671 625 770 -580 -163 -1227 25 -1220 39 -116 918 6 -105 -1115 -1565 -1712 -507 -1833 -1206 -1097 -1123 121 502 1416 509 617 -507 339 -177 593 -78 839 -250 1076 208 1776 492 922 26 120 877 410 535 -235 -434 -637 -810 -524 -353 583 1106 -119 412 -793 -127 -1040 SS 20231123T134756.0Z 8727.574953 167 1 48.73 2 79.29 130.61 134.43 352.60 0.00 1 0.00 1 0 17 3.286e-01 6.499e-03 1.395e-01 2.822e-03 6.241532e-01 1.469960e-03 7.070174e-03 -6.000000e+00 1.814591e-01 222.76 -2.00 3.54 -2.00 321.23 0.00e+00 3.357420e-03 6.903661e-04 1.286115e-03 -6.000000e+00 8.014143e-03 277.48 -2.00 20.00 -2.00 320.70 0.00e+00 5.179 0.003 302.00 328.00 3 1.1380e+00 4.8640e-03 6.0052e-02 -6.0000e+00 4.4666e-01 6.9030e-02 6.6966e-03 3.3453e-02 -6.0000e+00 4.8822e-01 -6.2807e-02 7.0784e-03 1.8651e-02 -6.0000e+00 2.9102e-01 1.6836e-02 3.4075e-03 6.9392e-03 -6.0000e+00 1.2395e-01 5.7131e-04 -6.5627e-04 7.9245e-05 8.3181e-05 -6.0000e+00 8.6146e-03 -9.2465e-03 -1.6271e-05 11 9 0 11 8 0 99.52 16.13 0.34 -0.00925 -0.01418 151 35 1 5 0 322.630 22.29 15.00 16.13 11.31 30.0 899.34 -55866 -105192 -79242 -127067 -103505 -154911 -58233 -122726 -64451 -134507 -88850 -80845 -31113 -76546 -45024 -55454 -31997 -40108 -10505 -32353 -41613 -6761 -4809 -2938 -20390 -6867 -20498 2480 -19540 -2389 -19174 398 -14273 4817 -18538 -4371 -18666 -1456 -3226 -2064 2278 1480 49 1749 6758 3769 3897 2301 3275 -1326 2391 1839 4960 990 5333 1544 2542 39 575 724 1432 2172 3469 3478 2754 1051 106 34 1417 2305 1266 2665 -121 1362 -966 -559 -3114 -1209 -2056 -410 -1076 -1228 -2358 -1668 -1262 -44 363 759 917 761 191 -335 -722 -688 344 -573 602 639 614 -54 -244 -1630 -967 -883 -712 -1191 -1042 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