File name: Pandora147s1_SWDetroitMI_20240219_L2Fit_fout2c9d20221206p1-8.txt File generation date: 20240220T055229.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v9d20221206.txt Level 1 file used: Pandora147s1_SWDetroitMI_20240219_L1_smca1c9d20221206p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20240219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 236 378 Nominal wavelengths inside fitting window [nm]: 305.0989 305.2398 305.3807 305.5215 305.6624 305.8032 305.9440 306.0848 306.2256 306.3664 306.5072 306.6479 306.7887 306.9294 307.0701 307.2108 307.3516 307.4922 307.6329 307.7736 307.9143 308.0549 308.1955 308.3362 308.4768 308.6174 308.7580 308.8985 309.0391 309.1797 309.3202 309.4607 309.6013 309.7418 309.8823 310.0227 310.1632 310.3037 310.4441 310.5846 310.7250 310.8654 311.0058 311.1462 311.2866 311.4270 311.5673 311.7077 311.8480 311.9883 312.1286 312.2689 312.4092 312.5495 312.6898 312.8300 312.9703 313.1105 313.2507 313.3909 313.5311 313.6713 313.8115 313.9517 314.0918 314.2319 314.3721 314.5122 314.6523 314.7924 314.9325 315.0725 315.2126 315.3526 315.4927 315.6327 315.7727 315.9127 316.0527 316.1927 316.3326 316.4726 316.6125 316.7525 316.8924 317.0323 317.1722 317.3121 317.4519 317.5918 317.7317 317.8715 318.0113 318.1511 318.2909 318.4307 318.5705 318.7103 318.8500 318.9898 319.1295 319.2692 319.4089 319.5486 319.6883 319.8280 319.9677 320.1073 320.2469 320.3866 320.5262 320.6658 320.8054 320.9450 321.0845 321.2241 321.3636 321.5032 321.6427 321.7822 321.9217 322.0612 322.2007 322.3401 322.4796 322.6190 322.7584 322.8979 323.0373 323.1767 323.3160 323.4554 323.5948 323.7341 323.8734 324.0128 324.1521 324.2914 324.4307 324.5699 324.7092 324.8485 324.9877 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240219T125718.4Z 8815.539796 190 1 48.96 2 84.91 110.37 108.78 345.75 0.00 1 0.00 1 0 17 5.562e-01 5.950e-02 6.181e-01 6.514e-02 1.473736e+00 3.973865e-02 1.621312e-02 -6.000000e+00 3.181524e-01 224.91 -2.00 3.54 -2.00 322.64 0.00e+00 1.533880e-02 1.627453e-02 1.908019e-03 -6.000000e+00 1.497639e-02 273.38 -2.00 20.00 -2.00 322.23 0.00e+00 9.712 0.017 302.00 328.00 3 -5.3887e-01 1.3902e-01 1.2180e-01 -6.0000e+00 7.9069e-01 3.3960e+00 1.6082e-01 7.6606e-02 -6.0000e+00 8.6796e-01 -3.2166e+00 9.5838e-02 3.7212e-02 -6.0000e+00 5.0751e-01 1.0303e+00 5.7573e-02 1.5975e-02 -6.0000e+00 2.1263e-01 7.8405e-06 -1.6765e-03 1.3327e-03 2.3009e-04 -6.0000e+00 1.5249e-02 -1.7165e-02 -7.4924e-05 12 8 8 10 0 0 -43.07 16.10 1.12 -0.01716 -0.02976 25 6 1 5 0 1958.280 22.19 15.00 16.10 2.81 30.0 882.44 14246 10877 129739 10897 -45973 900000 -10372 900000 -99226 -18918 -23909 900000 900000 900000 3784 96893 173550 2370 50208 900000 -38045 -56887 42739 36209 26484 15450 900000 -48341 -37810 900000 900000 48365 46790 -51916 900000 -60428 151267 -21056 168535 38331 900000 -7086 52458 11246 96972 -43966 -41837 -28518 -54050 -34867 201501 900000 46785 42824 52130 150839 64369 9740 -65718 248990 -42468 -20786 43384 96058 -30016 18421 42937 95047 48564 23358 11559 -17059 57471 -40850 97760 -63922 -55606 56724 26324 -19112 -5303 -15990 84235 8518 8412 72277 25306 -2124 2145 43532 6223 24250 -7937 -10302 -17308 7059 16317 9583 -1843 5322 -1403 -12420 -8183 -4488 -11625 6583 -12731 -6442 10479 778 7929 5529 4080 -3605 -1242 -3695 -80 478 -1052 -1687 7430 -4329 6757 -632 7593 -8664 13054 -957 6056 -3417 -4293 -925 -1674 2953 -3610 -1786 2114 4841 464 2877 -3879 -44 -1415 1279 1034 8222 748 -4127 900000 -657 900000 -8575 -1199 -1515 900000 900000 900000 283 6140 10998 232 3182 900000 -3945 -5899 2708 2295 1678 979 900000 -3063 -2396 900000 900000 3065 2965 -6281 900000 -5918 9586 -1456 10680 2429 900000 -531 3324 713 6145 -4053 -3856 -2464 -6539 -3817 12769 900000 3261 3257 3634 9559 4079 864 -9844 15779 -4844 -2108 2749 6087 -5136 1985 3809 6023 4924 3404 1978 -3784 5463 -8802 6195 -12152 -9514 3595 2836 -4118 -1210 -4762 10142 2267 2292 10535 5934 -646 598 7448 1420 4456 -2113 -3264 -7349 2953 7652 5769 -1264 3744 -960 -7950 -4201 -2105 -6114 3004 -7503 -4001 6574 666 7638 6202 4513 -4403 -1467 -4428 -104 593 -1369 -2384 8758 -5157 6765 -664 7218 -9499 11581 -1128 8482 -6540 -8903 -2106 -4263 7912 -11170 -5639 6430 14279 1389 7739 -9900 -106 -3255 SS 20240219T130907.0Z 8815.547997 193 1 48.90 2 82.87 112.44 109.25 348.34 0.00 1 0.00 1 0 17 4.778e-01 1.754e-02 4.645e-01 1.213e-02 1.291647e+00 7.126133e-03 1.340403e-02 -6.000000e+00 2.662133e-01 224.91 -2.00 3.54 -2.00 322.75 0.00e+00 5.201276e-03 4.291515e-03 1.175900e-02 -6.000000e+00 1.164300e-02 273.38 -2.00 20.00 -2.00 322.39 0.00e+00 7.426 0.008 302.00 328.00 3 1.6898e-02 2.8503e-02 1.2482e-01 -6.0000e+00 6.5930e-01 1.6524e+00 4.2374e-02 1.1955e-01 -6.0000e+00 7.1974e-01 -2.0412e+00 4.3713e-02 5.1094e-02 -6.0000e+00 4.2752e-01 7.7941e-01 2.0027e-02 1.4056e-02 -6.0000e+00 1.8142e-01 8.3905e-05 -1.9134e-03 2.7638e-04 2.3108e-04 -6.0000e+00 1.2743e-02 -1.9015e-02 -4.1388e-05 12 8 8 10 0 0 38.69 16.11 0.36 -0.01902 -0.03339 105 24 1 5 0 465.660 22.19 14.99 16.11 3.59 30.0 888.91 -85841 -66812 -158206 900000 -168289 33161 -140363 -9762 -9041 -119484 -137938 -137643 79999 -97638 -14480 -116245 -54099 -21949 104410 99891 50275 -114073 38720 -77419 -60030 -83411 -73885 -12980 -14642 -27428 -44298 3170 -24044 44336 -46809 44813 -34643 14989 9974 10920 -9867 81065 8999 141459 10848 61746 -13802 54477 382 34598 11617 24282 31408 35045 61289 55346 57796 -570 57502 -9908 -1217 -3281 51405 14421 38302 21476 46491 18285 50185 23593 27528 21505 14406 14358 -2202 24402 -17596 7462 -4312 11059 4338 2890 7112 9431 3554 8363 7403 9444 4384 6445 1499 -2152 -1482 -7618 -265 165 -1845 -1920 605 -1963 -253 -4223 -3154 -4948 -2793 -4348 -2195 -3928 -1288 -2759 169 -969 9 -2001 -1849 -1449 -125 1000 119 923 109 2810 533 2734 947 2642 1175 185 1042 1501 -345 458 -874 -208 -89 373 509 457 230 -174 -121 -993 -1535 -1015 -790 -3743 900000 -3077 392 -1660 -115 -107 -1413 -1632 -1924 946 -1680 -171 -3750 -1047 -330 1235 1182 595 -3435 458 -1665 -1097 -1884 -1430 -154 -173 -389 -996 56 -654 629 -1359 530 -943 284 236 297 -362 1247 287 1673 321 1096 -539 1160 15 1105 536 1120 1486 1741 2465 2423 2461 -37 2109 -656 -73 -225 2432 1070 2719 1686 3300 1711 4274 2740 3316 2775 1875 1652 -256 2078 -2025 746 -598 1665 854 684 1805 2475 1036 2410 2213 2783 1325 1802 409 -590 -419 -2614 -104 80 -1111 -1384 476 -1602 -188 -2793 -1774 -2741 -1604 -2665 -1405 -2847 -1069 -2828 201 -1200 12 -2692 -2443 -1875 -178 1357 171 1421 157 3615 663 3240 1116 2989 1340 239 1654 2885 -720 1059 -2243 -578 -267 1160 1584 1422 698 -492 -305 -2263 -3629 SS 20240219T132000.8Z 8815.555565 196 1 48.64 2 81.02 114.38 109.60 350.75 0.00 1 0.00 1 0 17 6.992e-01 1.582e-02 2.189e-01 4.363e-03 1.089783e+00 2.493269e-03 1.142557e-02 -6.000000e+00 3.919219e-01 224.91 -2.00 3.54 -2.00 322.41 0.00e+00 7.838067e-03 1.443811e-03 6.218379e-03 -6.000000e+00 1.729120e-02 273.38 -2.00 20.00 -2.00 322.02 0.00e+00 6.076 0.004 302.00 328.00 3 1.3768e-01 9.5570e-03 9.4645e-02 -6.0000e+00 9.6970e-01 8.4357e-01 1.5321e-02 8.6741e-02 -6.0000e+00 1.0590e+00 -1.1165e+00 1.7185e-02 3.8752e-02 -6.0000e+00 6.2711e-01 4.4746e-01 7.7141e-03 1.3383e-02 -6.0000e+00 2.6547e-01 3.6141e-04 -1.5145e-03 1.0632e-04 1.5609e-04 -6.0000e+00 1.8653e-02 -1.9124e-02 -5.6224e-05 12 8 8 10 0 0 19.10 16.10 0.27 -0.01912 -0.03050 228 53 1 5 0 213.300 22.19 15.00 16.10 4.27 30.0 895.18 -218099 -211505 -252611 900000 -272717 900000 -285061 -123029 -276225 -171608 -222723 60809 -154536 -107894 -108001 -119435 -105039 -41350 -35586 -84886 -68092 -115155 852 -113427 -27551 -95407 -23015 -109598 -63954 -61910 -43746 -51138 5912 -33227 -12554 -6980 -9253 -8183 -89 8129 20597 23763 278 30408 6356 31543 6381 35251 725 50054 11136 39082 23295 40735 36808 36030 27405 25769 15463 15668 21801 9764 23985 16107 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