File name: Pandora147s1_SWDetroitMI_20240224_L2Fit_fout2c9d20221206p1-8.txt File generation date: 20240225T055356.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v9d20221206.txt Level 1 file used: Pandora147s1_SWDetroitMI_20240224_L1_smca1c9d20221206p1-8.txt Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20240224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 236 378 Nominal wavelengths inside fitting window [nm]: 305.0989 305.2398 305.3807 305.5215 305.6624 305.8032 305.9440 306.0848 306.2256 306.3664 306.5072 306.6479 306.7887 306.9294 307.0701 307.2108 307.3516 307.4922 307.6329 307.7736 307.9143 308.0549 308.1955 308.3362 308.4768 308.6174 308.7580 308.8985 309.0391 309.1797 309.3202 309.4607 309.6013 309.7418 309.8823 310.0227 310.1632 310.3037 310.4441 310.5846 310.7250 310.8654 311.0058 311.1462 311.2866 311.4270 311.5673 311.7077 311.8480 311.9883 312.1286 312.2689 312.4092 312.5495 312.6898 312.8300 312.9703 313.1105 313.2507 313.3909 313.5311 313.6713 313.8115 313.9517 314.0918 314.2319 314.3721 314.5122 314.6523 314.7924 314.9325 315.0725 315.2126 315.3526 315.4927 315.6327 315.7727 315.9127 316.0527 316.1927 316.3326 316.4726 316.6125 316.7525 316.8924 317.0323 317.1722 317.3121 317.4519 317.5918 317.7317 317.8715 318.0113 318.1511 318.2909 318.4307 318.5705 318.7103 318.8500 318.9898 319.1295 319.2692 319.4089 319.5486 319.6883 319.8280 319.9677 320.1073 320.2469 320.3866 320.5262 320.6658 320.8054 320.9450 321.0845 321.2241 321.3636 321.5032 321.6427 321.7822 321.9217 322.0612 322.2007 322.3401 322.4796 322.6190 322.7584 322.8979 323.0373 323.1767 323.3160 323.4554 323.5948 323.7341 323.8734 324.0128 324.1521 324.2914 324.4307 324.5699 324.7092 324.8485 324.9877 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240224T135158.9Z 8820.577765 284 1 28.06 2 74.30 119.21 103.25 299.74 0.00 1 0.00 1 0 17 4.317e-01 1.207e-02 2.558e-01 7.050e-03 6.806658e-01 3.699079e-03 7.717650e-03 -6.000000e+00 2.414019e-01 225.12 -2.00 3.54 -2.00 320.84 0.00e+00 3.457741e-03 1.505945e-03 9.118246e-04 -6.000000e+00 1.078696e-02 273.73 -2.00 20.00 -2.00 320.36 0.00e+00 3.630 0.001 302.00 328.00 3 4.0646e+00 1.1271e-02 5.0307e-02 -6.0000e+00 5.9764e-01 1.5244e-01 1.4970e-02 3.5815e-02 -6.0000e+00 6.5246e-01 -1.2506e-01 1.5721e-02 1.9746e-02 -6.0000e+00 3.8733e-01 4.6381e-02 7.7953e-03 7.6972e-03 -6.0000e+00 1.6451e-01 1.0944e-04 -3.7069e-04 1.8782e-04 8.1801e-05 -6.0000e+00 1.1662e-02 -2.0590e-02 3.5089e-05 12 9 9 12 1 1 99.50 16.09 0.24 -0.02059 -0.02338 8 4 1 5 0 3116.210 22.19 14.99 16.09 0.74 29.7 863.48 -169412 92933 -141772 900000 900000 -153632 -96187 -133970 64227 -154119 161541 -135753 81881 -102823 900000 -104820 117143 -65018 44137 -24781 26996 -26868 61035 -30568 5918 -806 -28938 -19431 -27352 -34727 -28417 49696 -22209 43211 -26137 221 -13962 19886 -7352 28392 -5957 17772 790 10339 -5967 12855 -8146 2250 5540 2499 -3112 3594 12457 3627 6416 -835 10212 1930 6866 -2380 6223 661 5596 1115 5197 1940 -75 983 1987 2261 -60 246 87 3965 -2181 562 -2667 -265 -3213 -1133 -2575 915 -2529 543 -2501 800 -899 1379 801 333 -642 -711 -766 -3767 -679 542 1190 305 942 -165 -16 -1571 -1317 -1507 -940 -1052 -338 -1425 311 -902 114 231 262 51 -110 834 -374 732 -256 741 -385 917 398 572 -257 1281 361 1542 360 821 -1 351 -593 -112 -147 -791 182 -62 227 -511 181 -448 65 -2379 639 -1906 900000 900000 -2020 -811 -1801 441 -3085 1110 -2758 563 -2550 900000 -3901 805 -2137 551 -622 430 -698 724 -950 138 -21 -1020 -604 -915 -1380 -1290 1304 -1278 1433 -1579 11 -824 1046 -600 1935 -641 1618 90 1089 -750 1373 -1101 285 715 358 -529 641 2229 740 1400 -196 2286 445 1514 -565 1406 168 1555 365 1711 642 -25 337 752 985 -29 124 43 1750 -925 207 -992 -99 -1349 -556 -1499 586 -1755 385 -1950 641 -766 1173 678 271 -488 -505 -546 -2774 -549 503 1222 361 1196 -210 -19 -1660 -1314 -1530 -1022 -1158 -389 -1775 418 -1333 184 378 428 82 -168 1208 -554 1122 -420 1238 -636 1426 598 857 -372 1751 480 2142 556 1420 -3 682 -1217 -235 -328 -1799 415 -144 536 -1158 380 -915 128 SS 20240224T135805.7Z 8820.582011 288 1 26.67 2 73.31 120.40 104.21 300.85 0.00 1 0.00 1 0 17 3.403e-01 9.213e-03 1.846e-01 6.492e-03 6.456608e-01 3.336474e-03 7.374141e-03 -6.000000e+00 1.897995e-01 225.12 -2.00 3.54 -2.00 320.64 0.00e+00 -3.115542e-05 1.273429e-03 1.029258e-03 -6.000000e+00 8.176039e-03 273.73 -2.00 20.00 -2.00 320.15 0.00e+00 3.429 0.001 302.00 328.00 3 4.1410e+00 1.0001e-02 4.7738e-02 -6.0000e+00 4.7026e-01 1.2133e-01 1.2921e-02 3.4200e-02 -6.0000e+00 5.1315e-01 -9.8813e-02 1.3094e-02 1.7722e-02 -6.0000e+00 3.0467e-01 3.5095e-02 6.5827e-03 5.3032e-03 -6.0000e+00 1.2898e-01 1.2977e-04 -5.2554e-04 1.7388e-04 6.0636e-05 -6.0000e+00 8.9160e-03 -2.1414e-02 2.6037e-05 12 9 1 12 1 1 99.90 16.08 0.30 -0.02141 -0.02536 8 4 1 5 0 2962.910 22.19 15.00 16.08 0.83 29.9 864.51 -98139 -112050 -115650 -131907 -143930 -103812 45056 -129461 -99504 -60204 -99716 -145259 -46962 -44420 -14572 -14224 -9345 -45541 -7439 -5759 -88 -22361 2417 -4367 -8762 9345 -12511 -16770 -12128 9757 -12791 -9391 -2609 -7468 -22271 -895 -2486 11425 -2668 3181 229 10893 -710 7809 2910 6527 3219 2223 1501 2541 5356 5530 1365 -779 1630 3704 -1545 2933 952 112 1399 793 5135 702 3629 1603 -1493 1890 2119 1593 2279 763 1741 609 170 -1286 -3323 -1475 684 -1897 -1357 -1124 -1315 -1307 -520 -65 583 332 -442 -1408 1062 -1234 -880 -569 -1109 -1113 335 1074 24 -591 424 -464 -504 -793 -1220 -1198 -353 -387 -446 441 642 702 284 197 -73 266 -211 -381 -66 -97 -320 781 305 584 684 167 554 635 458 783 -161 -247 -540 72 -360 -338 282 222 683 -546 -393 -305 -110 -932 -1419 -1621 -2088 -2343 -1127 285 -2342 -1530 -681 -1759 -4291 -701 -824 -250 -289 -203 -1461 -188 -151 -2 -708 63 -136 -313 296 -498 -667 -450 313 -613 -518 -145 -463 -1523 -53 -154 743 -248 334 28 1273 -97 999 393 865 448 323 229 412 943 1088 307 -194 420 977 -442 795 253 29 374 235 1660 266 1391 606 -573 724 903 738 1149 404 896 297 80 -550 -1356 -601 307 -974 -807 -759 -968 -1014 -427 -57 527 308 -409 -1255 855 -948 -647 -432 -952 -1105 355 1286 31 -766 504 -495 -524 -841 -1318 -1361 -418 -489 -618 641 1025 1173 474 314 -110 403 -323 -578 -106 -160 -521 1274 481 883 991 233 741 891 728 1315 -298 -482 -1104 147 -787 -772 650 519 1577 -1216 -817 -627 -219 SS 20240224T140709.9Z 8820.588309 294 1 48.84 2 71.88 122.20 105.62 302.53 0.00 1 0.00 1 0 17 3.309e-01 9.282e-03 2.449e-01 8.433e-03 5.957873e-01 4.360529e-03 6.808853e-03 -6.000000e+00 1.846381e-01 225.12 -2.00 3.54 -2.00 320.73 0.00e+00 3.906468e-03 1.687011e-03 8.109361e-04 -6.000000e+00 7.952666e-03 273.73 -2.00 20.00 -2.00 320.24 0.00e+00 3.174 0.001 302.00 328.00 3 4.7592e+00 1.3157e-02 4.3972e-02 -6.0000e+00 4.5748e-01 1.0565e-01 1.6911e-02 3.1221e-02 -6.0000e+00 4.9914e-01 -7.4874e-02 1.6945e-02 1.7402e-02 -6.0000e+00 2.9634e-01 2.7653e-02 8.5261e-03 7.5384e-03 -6.0000e+00 1.2550e-01 9.2800e-05 -1.5471e-04 2.3271e-04 7.8164e-05 -6.0000e+00 8.6697e-03 -2.2332e-02 9.5166e-05 11 8 0 10 0 0 99.96 16.05 0.37 -0.02233 -0.02349 26 6 1 5 0 1878.130 22.19 15.00 16.05 1.10 29.9 867.31 225895 -127794 -61193 -55672 -105902 -114393 -43441 -90848 -13107 -92844 -101592 -59509 -47453 -32820 -26264 -42887 57716 -14171 -13004 -39296 2144 28036 32178 2569 -16569 -13879 2963 -16239 -30330 -36332 -5141 -8543 -11958 22423 8367 -5870 -14885 2039 -3658 3071 11481 3795 3139 3414 874 4703 -3733 6876 -2966 4807 326 1291 7016 5121 228 -1386 -899 4836 4912 -561 5927 1274 5500 1888 -136 606 776 -1153 2094 1345 3810 1916 -302 -254 -3292 -1026 -3663 -2851 -2399 -1072 202 243 -2011 -2389 -1737 804 548 -117 1081 1 663 -320 -1919 74 513 -1088 285 400 77 -317 543 -436 -320 -324 -957 -898 -518 -1233 -126 1162 -410 481 -138 488 -661 191 -129 -236 -382 889 155 915 37 1142 116 -175 174 787 -521 831 -371 -108 -477 -235 35 74 385 464 -508 210 -507 -453 201 1858 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