File name: Pandora154s1_SaltLakeCityUT_20221213_L2Fit_fnvs4c7d20220523p1-8.txt File generation date: 20241003T155416.0Z Data description: Level 2 spectral fitting results file Data file version: fnvs4c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 154 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora154_OF_v2d20220401.txt Instrument calibration file used: Pandora154s1_CF_v7d20220523.txt Level 1 file used: Pandora154s1_SaltLakeCityUT_20221213_L1_smca1c7d20220523p1-8.txt Full location name: University of Utah, William Browning Building Short location name: SaltLakeCityUT Country of location: United States Location latitude [deg]: 40.7663 Location longitude [deg]: -111.8478 Location altitude [m]: 1455 Local noon date: 20221213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 930 1475 Nominal wavelengths inside fitting window [nm]: 400.1160 400.2481 400.3802 400.5123 400.6444 400.7764 400.9085 401.0405 401.1725 401.3045 401.4365 401.5685 401.7004 401.8324 401.9643 402.0962 402.2281 402.3600 402.4919 402.6237 402.7556 402.8874 403.0192 403.1510 403.2828 403.4146 403.5463 403.6781 403.8098 403.9415 404.0732 404.2049 404.3366 404.4683 404.5999 404.7315 404.8632 404.9948 405.1264 405.2579 405.3895 405.5210 405.6526 405.7841 405.9156 406.0471 406.1786 406.3100 406.4415 406.5729 406.7043 406.8357 406.9671 407.0985 407.2298 407.3612 407.4925 407.6238 407.7552 407.8864 408.0177 408.1490 408.2802 408.4115 408.5427 408.6739 408.8051 408.9362 409.0674 409.1986 409.3297 409.4608 409.5919 409.7230 409.8541 409.9851 410.1162 410.2472 410.3782 410.5092 410.6402 410.7712 410.9022 411.0331 411.1640 411.2950 411.4259 411.5568 411.6876 411.8185 411.9493 412.0802 412.2110 412.3418 412.4726 412.6033 412.7341 412.8648 412.9956 413.1263 413.2570 413.3877 413.5184 413.6490 413.7797 413.9103 414.0409 414.1715 414.3021 414.4327 414.5632 414.6938 414.8243 414.9548 415.0853 415.2158 415.3462 415.4767 415.6071 415.7376 415.8680 415.9984 416.1288 416.2591 416.3895 416.5198 416.6501 416.7805 416.9107 417.0410 417.1713 417.3015 417.4318 417.5620 417.6922 417.8224 417.9526 418.0827 418.2129 418.3430 418.4732 418.6033 418.7334 418.8634 418.9935 419.1235 419.2536 419.3836 419.5136 419.6436 419.7736 419.9035 420.0335 420.1634 420.2933 420.4232 420.5531 420.6830 420.8128 420.9427 421.0725 421.2023 421.3321 421.4619 421.5917 421.7214 421.8512 421.9809 422.1106 422.2403 422.3700 422.4996 422.6293 422.7589 422.8885 423.0181 423.1477 423.2773 423.4069 423.5364 423.6660 423.7955 423.9250 424.0545 424.1840 424.3134 424.4429 424.5723 424.7017 424.8311 424.9605 425.0899 425.2192 425.3486 425.4779 425.6072 425.7365 425.8658 425.9950 426.1243 426.2535 426.3828 426.5120 426.6412 426.7703 426.8995 427.0287 427.1578 427.2869 427.4160 427.5451 427.6742 427.8032 427.9323 428.0613 428.1903 428.3193 428.4483 428.5773 428.7062 428.8352 428.9641 429.0930 429.2219 429.3508 429.4797 429.6085 429.7374 429.8662 429.9950 430.1238 430.2526 430.3813 430.5101 430.6388 430.7675 430.8962 431.0249 431.1536 431.2822 431.4109 431.5395 431.6681 431.7967 431.9253 432.0539 432.1824 432.3110 432.4395 432.5680 432.6965 432.8250 432.9534 433.0819 433.2103 433.3387 433.4671 433.5955 433.7239 433.8523 433.9806 434.1089 434.2372 434.3655 434.4938 434.6221 434.7503 434.8786 435.0068 435.1350 435.2632 435.3914 435.5195 435.6477 435.7758 435.9039 436.0321 436.1601 436.2882 436.4163 436.5443 436.6723 436.8003 436.9283 437.0563 437.1843 437.3122 437.4402 437.5681 437.6960 437.8239 437.9518 438.0796 438.2075 438.3353 438.4631 438.5909 438.7187 438.8465 438.9742 439.1020 439.2297 439.3574 439.4851 439.6128 439.7405 439.8681 439.9957 440.1234 440.2510 440.3785 440.5061 440.6337 440.7612 440.8887 441.0163 441.1438 441.2712 441.3987 441.5262 441.6536 441.7810 441.9084 442.0358 442.1632 442.2905 442.4179 442.5452 442.6725 442.7998 442.9271 443.0544 443.1816 443.3089 443.4361 443.5633 443.6905 443.8177 443.9448 444.0720 444.1991 444.3262 444.4533 444.5804 444.7075 444.8345 444.9616 445.0886 445.2156 445.3426 445.4696 445.5965 445.7235 445.8504 445.9773 446.1042 446.2311 446.3580 446.4848 446.6117 446.7385 446.8653 446.9921 447.1189 447.2456 447.3724 447.4991 447.6258 447.7525 447.8792 448.0059 448.1326 448.2592 448.3858 448.5124 448.6390 448.7656 448.8922 449.0187 449.1452 449.2718 449.3983 449.5247 449.6512 449.7777 449.9041 450.0305 450.1569 450.2833 450.4097 450.5361 450.6624 450.7887 450.9151 451.0414 451.1676 451.2939 451.4202 451.5464 451.6726 451.7988 451.9250 452.0512 452.1774 452.3035 452.4296 452.5558 452.6819 452.8079 452.9340 453.0601 453.1861 453.3121 453.4381 453.5641 453.6901 453.8160 453.9420 454.0679 454.1938 454.3197 454.4456 454.5715 454.6973 454.8232 454.9490 455.0748 455.2006 455.3263 455.4521 455.5778 455.7036 455.8293 455.9550 456.0806 456.2063 456.3320 456.4576 456.5832 456.7088 456.8344 456.9600 457.0855 457.2110 457.3366 457.4621 457.5876 457.7130 457.8385 457.9639 458.0894 458.2148 458.3402 458.4656 458.5909 458.7163 458.8416 458.9669 459.0922 459.2175 459.3428 459.4681 459.5933 459.7185 459.8437 459.9689 460.0941 460.2193 460.3444 460.4695 460.5947 460.7198 460.8448 460.9699 461.0950 461.2200 461.3450 461.4700 461.5950 461.7200 461.8449 461.9699 462.0948 462.2197 462.3446 462.4695 462.5944 462.7192 462.8440 462.9689 463.0937 463.2184 463.3432 463.4680 463.5927 463.7174 463.8421 463.9668 464.0915 464.2161 464.3408 464.4654 464.5900 464.7146 464.8392 464.9638 465.0883 465.2128 465.3374 465.4619 465.5863 465.7108 465.8353 465.9597 466.0841 466.2085 466.3329 466.4573 466.5816 466.7060 466.8303 466.9546 467.0789 467.2032 467.3274 467.4517 467.5759 467.7001 467.8243 467.9485 468.0727 468.1968 468.3210 468.4451 468.5692 468.6933 468.8174 468.9414 469.0654 469.1895 469.3135 469.4375 469.5614 469.6854 469.8093 469.9333 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-709: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 710-1255: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221213T213212.6Z 8382.897367 514 1 50.30 2 70.77 211.65 113.66 323.97 0.00 1 0.00 1 0 33 1.782e-03 1.642e-03 1.504e-03 1.395e-03 1.424899e+03 2.773595e+02 1.290320e+02 2.870259e+02 3.497147e+02 268.83 -2.00 20.00 -2.00 447.84 0.00e+00 -1.975570e-04 1.619203e-04 1.047826e-05 1.279578e-05 1.956617e-04 268.83 -2.00 20.00 -2.00 457.15 0.00e+00 2.692834e-04 1.496653e-05 1.890741e-05 8.825224e-06 1.891820e-05 268.83 -2.00 20.00 -2.00 439.22 0.00e+00 1.429638e+06 1.997065e+05 3.085059e+04 1.849906e+05 2.580069e+05 251.82 -2.00 11.21 -2.00 459.60 0.00e+00 1.952687e-01 3.633394e-02 5.427745e-03 6.886121e-03 5.574273e-02 222.22 -2.00 3.47 -2.00 456.51 0.00e+00 -1.460732e-05 4.756773e-06 5.319739e-07 9.378177e-07 6.911473e-06 268.83 -2.00 20.00 -2.00 457.48 0.00e+00 3.003 0.000 397.00 473.00 4 7.7494e+00 1.6367e-03 6.4501e-03 3.1872e-04 1.8781e-03 3.9684e-02 1.8820e-03 1.3370e-03 1.9926e-04 2.2819e-03 -8.1601e-03 1.0887e-03 1.7603e-04 8.2567e-05 1.3035e-03 -2.2871e-04 3.6223e-04 3.9607e-05 2.0369e-05 4.3805e-04 1.3709e-03 1.9034e-04 2.9740e-05 1.1882e-05 2.1915e-04 4.5455e-04 4.7015e-03 1.1449e-03 9.6630e-05 3.7793e-05 1.1445e-03 7.5354e-05 1.8665e-05 4.8614e-07 3.1161e-07 2.1680e-05 -1.0981e-04 2.5501e-05 5.3457e-07 3.9620e-07 2.9351e-05 2.3859e-02 -2.6059e-04 3.8017e+00 1.5685e-01 4.5634e-03 1.5941e-03 1.7262e-01 12 9 8 11 4 0 99.99 18.27 1.47 0.02386 0.03485 97 19 1 4 0 518.440 24.14 20.00 18.27 7.89 5.9 816.52 47 -347 -550 147 -230 100 -374 -180 32 -302 125 -216 85 26 311 277 -12 478 36 210 -306 67 -103 -434 -1 25 261 -142 191 168 317 4 -317 390 -230 269 -209 -11 -29 -202 169 -447 205 139 205 -281 93 189 -67 27 -189 49 -306 325 -95 -9 159 -377 415 145 105 94 229 40 -39 156 -231 104 103 236 22 47 94 -52 -62 -27 -176 -118 -201 172 -248 186 -65 143 19 89 62 -92 542 119 131 -145 42 -107 -214 17 31 231 -246 -10 -70 -180 241 -125 146 -197 -116 -183 47 198 -87 -101 -160 191 -59 -168 33 -34 238 -70 134 -115 169 -219 -57 -148 -227 138 -146 266 -58 55 228 -48 187 -396 -79 -191 -37 155 -215 -169 -107 -46 -139 1 -75 -70 90 -203 158 -304 -63 -122 66 154 -125 165 -290 294 -126 123 -190 -34 320 -161 81 -77 112 -245 -55 39 63 19 -278 21 -83 117 -36 -71 358 31 248 -338 -33 120 34 261 27 211 -61 287 -335 -80 162 -86 90 -412 363 -19 60 61 -193 111 24 367 -33 68 74 112 78 -112 196 -27 28 42 -87 6 135 385 -323 398 335 75 116 37 263 -163 121 -77 -132 67 -146 261 -477 303 -51 267 -723 182 99 63 120 -83 93 10 63 -146 -61 6 -321 36 -140 179 -6 119 -142 -133 264 2 -91 -335 -57 -463 -111 -32 -299 289 -156 74 -139 -205 12 -240 97 -165 270 -410 111 11 127 9 -250 27 -165 -40 -68 -266 93 -121 222 -4 374 -539 -250 126 -250 123 -59 116 -75 222 149 29 204 -52 139 -154 225 152 -274 98 -195 109 24 182 99 132 88 -11 299 -354 202 -258 274 -91 -98 70 -194 40 20 172 59 64 -53 -138 218 -146 213 -256 -77 -84 -192 180 -47 277 -147 151 32 -54 -56 -165 258 241 136 -121 -189 124 5 216 -379 172 -464 38 -16 -251 -11 7 24 -182 -106 -154 -49 50 4 109 -394 20 -41 -47 158 -238 328 -198 -76 -121 52 4 122 186 52 190 -144 0 174 163 54 68 25 -107 44 -3 0 124 2 104 38 189 115 66 239 21 215 -76 296 7 347 38 -101 -53 -58 232 -40 220 -138 107 96 146 270 -249 295 -250 -126 18 -40 50 -106 -32 -182 -87 -207 -43 -38 -192 3 33 -10 -124 5 79 34 -38 -296 195 3 47 -110 -22 -27 -176 -22 -91 73 5 6 -10 -218 49 2 161 124 91 153 -68 -30 -6 45 -12 97 105 -17 170 -30 -63 -218 45 -49 -65 95 -193 98 -80 100 -33 -75 -47 -131 24 -124 94 -220 100 -117 152 162 -49 232 -64 87 -256 16 -149 -105 10 -386 87 -98 106 24 6 320 -33 242 29 56 -124 -200 5 -6 148 -206 100 53 91 83 -154 -72 -3 232 12 139 -82 4 -92 11 134 32 -234 -377 98 -154 68 -266 -126 22 -215 93 -160 63 19 232 208 -9 360 27 161 -234 50 -73 -299 0 17 191 -110 151 133 247 3 -223 260 -154 186 -155 -9 -23 -156 126 -328 156 106 157 -214 69 137 -49 20 -146 39 -243 254 -75 -7 122 -289 317 114 86 79 193 34 -33 137 -208 94 93 210 19 40 77 -41 -47 -20 -128 -87 -156 135 -206 158 -56 125 16 81 57 -85 500 109 119 -132 38 -98 -195 15 27 204 -214 -8 -60 -155 214 -116 139 -188 -108 -165 41 173 -77 -92 -148 176 -53 -151 29 -30 210 -63 123 -109 163 -215 -56 -143 -217 129 -134 239 -51 48 196 -42 166 -357 -72 -173 -33 139 -192 -151 -95 -42 -127 1 -71 -66 82 -180 135 -259 -54 -106 60 142 -119 161 -273 276 -120 116 -177 -31 303 -146 75 -72 104 -218 -48 32 50 16 -243 18 -76 106 -32 -61 306 26 216 -304 -30 111 31 238 24 183 -52 246 -293 -71 145 -77 79 -358 310 -17 54 57 -183 104 22 314 -27 53 58 90 66 -99 176 -25 25 37 -78 5 116 322 -266 324 275 63 97 31 209 -122 84 -51 -86 43 -95 168 -303 188 -32 173 -510 141 82 57 116 -82 92 9 57 -122 -49 5 -267 32 -131 173 -6 115 -134 -119 219 1 -68 -251 -44 -390 -99 -30 -285 273 -146 67 -125 -186 11 -218 89 -154 255 -395 108 11 124 8 -238 25 -152 -36 -61 -237 83 -110 202 -3 321 -460 -203 101 -207 102 -51 102 -67 200 135 27 191 -49 130 -143 203 134 -239 85 -173 99 23 177 94 125 82 -10 277 -335 194 -252 267 -88 -94 67 -187 38 19 165 56 60 -50 -130 208 -142 199 -240 -71 -77 -179 170 -45 265 -141 142 30 -50 -51 -148 229 214 123 -111 -176 113 4 201 -357 161 -442 36 -16 -251 -11 7 24 -179 -102 -147 -47 49 3 109 -394 19 -40 -46 154 -235 323 -198 -76 -123 54 4 128 198 56 205 -155 0 194 180 59 73 26 -116 48 -3 0 134 2 108 39 188 117 68 243 22 224 -80 317 8 388 43 -115 -61 -65 260 -44 242 -151 116 104 159 296 -277 330 -286 -147 22 -48 59 -129 -38 -220 -106 -253 -52 -46 -237 4 42 -13 -154 6 95 40 -47 -363 240 4 59 -140 -28 -34 -223 -28 -114 91 6 8 -13 -275 62 3 206 161 119 202 -91 -39 -7 60 -16 127 138 -22 225 -39 -84 -292 60 -66 -87 126 -259 137 -112 139 -45 -103 -64 -179 33 -170 129 -299 134 -156 200 214 -66 313 -87 119 -351 22 -206 -147 15 -545 120 -134 141 31 7 408 -43 319 40 76 -171 -276 7 -9 201 -278 136 73 125 114 -213 -100 -4 319 17 192 -114 6 -127 15 179 SQ 20221213T215515.1Z 8382.913369 524 1 16.33 2 73.22 216.58 116.04 329.16 0.00 1 0.00 1 0 33 1.643e-03 1.551e-03 1.594e-03 1.521e-03 1.233702e+03 2.955426e+02 1.423472e+02 2.870273e+02 3.225254e+02 268.83 -2.00 20.00 -2.00 446.81 0.00e+00 8.918569e-05 1.735578e-04 1.219219e-05 1.245372e-05 1.799892e-04 268.83 -2.00 20.00 -2.00 456.19 0.00e+00 3.123566e-04 1.615541e-05 2.228720e-05 8.819517e-06 1.744622e-05 268.83 -2.00 20.00 -2.00 437.91 0.00e+00 1.066939e+06 2.143085e+05 3.943089e+04 1.850902e+05 2.378643e+05 251.81 -2.00 11.21 -2.00 458.50 0.00e+00 2.980222e-01 4.074369e-02 6.435764e-03 7.166224e-03 5.135575e-02 222.22 -2.00 3.47 -2.00 455.56 0.00e+00 -3.451238e-06 5.270291e-06 5.854769e-07 9.339023e-07 6.371660e-06 268.83 -2.00 20.00 -2.00 456.61 0.00e+00 3.413 0.001 397.00 473.00 4 7.4346e+00 1.7099e-03 7.3350e-03 3.2099e-04 1.7295e-03 1.5631e-02 2.0374e-03 1.5189e-03 1.9538e-04 2.1174e-03 -6.3694e-03 1.1539e-03 1.9952e-04 7.9987e-05 1.1905e-03 1.5248e-04 3.8873e-04 3.7220e-05 2.0242e-05 4.0420e-04 8.3771e-04 2.0148e-04 2.5020e-05 1.1757e-05 2.0197e-04 5.7082e-04 2.3864e-03 1.1396e-03 1.0362e-04 2.9880e-05 1.0358e-03 8.5011e-05 1.9739e-05 4.2328e-07 3.0404e-07 1.9984e-05 -9.4887e-05 2.7367e-05 4.6018e-07 3.8653e-07 2.7052e-05 2.5667e-02 -2.7271e-04 3.4898e+00 1.6370e-01 5.3709e-03 1.4940e-03 1.5936e-01 12 9 9 12 5 1 99.96 18.27 1.82 0.02567 0.03560 6 4 1 4 0 2308.790 24.14 20.00 18.27 7.43 5.8 814.51 -145 -93 279 -530 -328 44 34 384 -135 -155 -133 5 420 133 337 -71 140 48 106 180 -117 -201 -354 -234 -3 -218 -282 154 7 131 30 -262 -6 44 112 91 -99 50 141 128 -260 377 -330 345 121 -508 36 347 141 60 -97 -256 -270 98 -3 121 97 292 -23 -177 -257 4 -41 53 42 -143 168 -199 -155 332 458 158 118 84 -35 -68 -201 15 88 30 -190 -68 207 190 -34 45 -224 -104 625 397 165 -296 172 100 69 407 144 -61 -283 -183 -61 -114 22 33 3 -143 -99 -355 128 -168 10 -37 -184 -46 -353 39 -189 36 30 117 195 78 67 -31 -140 30 -87 20 -38 -158 125 187 -82 4 -87 239 -496 -44 -53 128 -85 115 234 -518 -157 351 -72 -6 58 118 -90 75 246 297 338 38 -5 -162 33 -28 -238 -1 -163 -23 -179 -47 -42 -86 -91 97 45 -32 -98 173 -210 -153 114 -116 81 31 -54 17 -167 76 20 214 -283 73 18 103 58 272 40 202 -61 -150 -109 -117 -15 19 103 180 -172 86 -71 102 58 313 -234 -179 141 90 1 98 206 -76 -198 103 146 -60 -84 87 138 -82 358 177 -264 50 -238 -218 -18 -186 77 -110 218 43 321 -35 3 -69 -130 0 31 105 94 -13 -243 244 109 -46 -4 -82 -95 40 -203 12 144 90 -58 37 -204 -236 -47 -126 -178 2 -301 -154 -152 405 -126 -265 104 70 -207 83 -198 47 165 -80 19 -129 27 -173 256 -99 -203 -198 -69 -29 62 149 60 -346 -68 77 129 -155 -130 -25 -149 207 30 223 75 -150 78 380 15 -91 94 -62 89 -29 -21 182 -191 269 -128 428 132 29 234 -21 145 -286 -94 168 -163 -37 91 71 86 -28 204 177 -5 142 147 -118 -173 -360 -40 -257 372 -193 7 202 248 -316 -255 363 450 -26 -121 -1 70 117 -118 -6 -120 151 -33 59 -643 55 88 6 83 109 -98 -69 43 -30 97 170 -49 54 -202 317 40 48 -214 -38 -67 -135 130 43 -80 76 208 139 91 113 -77 10 257 -41 239 -55 94 -120 -39 -232 36 -65 114 244 105 260 19 -30 83 -55 189 -17 -82 -57 63 -35 -139 -63 49 -163 -15 45 -93 -26 -105 142 -162 153 -11 -151 -21 -50 -122 -54 -108 -249 -49 -207 -139 145 47 134 -39 94 -63 104 -253 -214 -115 -35 -94 62 92 40 -43 9 -41 27 63 17 -35 64 -90 -11 -154 -55 84 -134 38 3 -69 -19 -9 55 -44 -73 25 -11 -163 108 104 -135 15 132 -152 151 39 -67 -70 162 -6 0 -50 -17 264 146 -45 -100 -144 112 124 25 -180 140 248 -17 -117 -45 1 -156 83 134 88 43 -62 -39 123 89 85 179 51 25 46 -276 52 -12 -19 -130 120 8 43 61 169 -128 119 -90 162 11 -148 -199 27 -239 -106 -67 197 -385 -238 31 25 290 -104 -119 -102 4 321 103 262 -56 110 38 84 143 -93 -155 -274 -174 -2 -166 -217 124 6 108 24 -204 -5 32 81 69 -80 40 115 103 -204 300 -262 273 97 -404 28 261 106 46 -78 -212 -223 80 -2 98 78 233 -18 -146 -219 3 -35 45 36 -127 151 -182 -141 295 398 140 101 69 -29 -53 -153 12 71 24 -167 -61 179 167 -31 42 -210 -98 582 366 151 -272 158 93 64 371 131 -54 -249 -165 -55 -104 20 31 3 -139 -94 -326 114 -150 9 -35 -172 -43 -328 35 -171 32 27 107 183 75 63 -29 -134 29 -81 19 -35 -146 112 165 -72 3 -79 220 -462 -40 -49 118 -78 105 213 -480 -148 323 -68 -5 54 108 -79 65 215 264 311 35 -5 -156 32 -27 -234 -1 -157 -22 -169 -45 -40 -83 -87 90 41 -27 -84 146 -190 -142 108 -110 75 28 -48 15 -153 72 19 199 -265 69 17 93 51 244 37 187 -57 -141 -101 -106 -14 17 93 168 -165 81 -64 92 49 267 -200 -152 125 80 1 90 188 -69 -178 91 132 -53 -73 75 120 -72 317 154 -223 41 -182 -166 -13 -138 57 -82 158 31 229 -26 2 -57 -114 0 30 103 93 -13 -224 217 92 -39 -3 -75 -92 38 -198 11 139 82 -52 32 -169 -197 -40 -114 -165 2 -285 -146 -141 379 -117 -249 100 66 -199 80 -196 47 161 -79 19 -125 26 -170 246 -95 -191 -184 -64 -27 60 140 54 -306 -60 67 111 -139 -118 -23 -139 195 29 215 71 -144 74 356 14 -85 86 -57 83 -27 -21 180 -186 261 -127 418 130 28 231 -21 144 -285 -92 165 -162 -36 90 70 84 -27 195 171 -5 137 142 -115 -166 -346 -39 -253 368 -193 7 198 238 -306 -240 334 410 -24 -113 -1 67 115 -113 -6 -118 148 -33 59 -661 56 90 6 83 111 -98 -69 43 -31 100 171 -51 56 -207 323 41 50 -222 -40 -71 -140 136 45 -86 82 226 152 100 124 -84 11 273 -44 260 -59 103 -132 -43 -254 38 -68 120 252 108 264 19 -31 87 -58 203 -18 -89 -63 70 -39 -153 -71 54 -180 -16 49 -101 -28 -115 157 -183 175 -12 -178 -25 -59 -143 -63 -125 -290 -57 -244 -164 171 55 159 -47 112 -74 124 -298 -249 -134 -40 -112 74 111 49 -52 11 -49 33 75 20 -42 77 -108 -14 -187 -68 104 -167 48 4 -88 -24 -11 69 -55 -92 32 -14 -206 137 132 -172 19 168 -194 192 50 -85 -89 210 -7 0 -64 -22 339 188 -58 -127 -181 139 154 32 -229 179 319 -22 -152 -59 1 -201 106 176 113 54 -76 -47 148 109 106 227 66 33 60 -359 67 -15 -24 -166 154 10 54 77 213 -161 150 -114 205 13 -187 -251 33 -303