File name: Pandora88s1_SanAntonioTX_20251007_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20251008T062840.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alberto Mestas-Nunez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora88_OF_v3d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20251007_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas at San Antonio Short location name: SanAntonioTX Country of location: United States Location latitude [deg]: 29.4230 Location longitude [deg]: -98.5025 Location altitude [m]: 222 Local noon date: 20251007 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251007T140601.3Z 9411.587515 282 1 53.92 2 70.63 108.66 103.94 290.30 0.00 1 0.00 1 0 17 1.977e-02 6.176e-03 1.099e-03 3.002e-04 3.444263e-01 1.486402e-04 3.778552e-03 -6.000000e+00 1.100986e-02 227.25 -2.00 3.23 -2.00 317.53 0.00e+00 4.920867e-04 2.348708e-05 1.492697e-04 -6.000000e+00 5.034822e-04 290.89 -2.00 20.00 -2.00 316.65 0.00e+00 2.980 0.000 302.00 328.00 3 7.6899e-01 3.9421e-04 3.3175e-02 -6.0000e+00 2.7267e-02 -1.5508e-02 4.4656e-04 1.6319e-02 -6.0000e+00 2.9574e-02 6.1338e-04 2.7379e-04 7.9669e-03 -6.0000e+00 1.7703e-02 -1.7821e-03 1.3954e-04 2.2581e-03 -6.0000e+00 7.6859e-03 9.1394e-03 2.6277e-04 7.9230e-06 2.2271e-05 -6.0000e+00 4.9067e-04 2.5120e-02 0.0000e+00 10 0 0 10 0 0 99.97 25.66 0.29 0.02512 0.02709 1287 145 1 5 0 41.890 33.75 20.00 25.66 33.51 0.0 1005.54 -4975 -4905 -4417 -5517 -10669 -5982 -8438 -4183 -1404 -4733 -5525 -5213 -3067 -2454 -246 -182 -295 1075 1270 1694 1769 923 1228 2092 603 1444 260 115 -1293 682 1247 1829 1594 -395 -2724 -3036 -2201 -1082 -400 -15 -352 -418 -132 -535 265 -26 -186 -229 -711 -199 857 855 1150 1268 867 973 768 559 204 163 619 1156 1541 2085 772 -123 -457 -873 29 434 574 449 160 413 50 -411 -866 -1573 -1179 -1165 -1145 -1121 -1953 -1673 -1088 -510 -8 230 737 671 559 301 33 -269 -11 64 237 867 563 -93 -345 -803 -1125 -528 -578 -748 -662 -481 -96 352 631 576 581 267 -87 -212 -19 -29 223 223 -97 8 491 330 582 269 46 457 468 277 220 -105 -154 -190 -39 47 -89 220 238 -159 -200 -485 -591 -428 -467 -437 -516 -918 -484 -760 -408 -151 -562 -650 -642 -395 -369 -42 -36 -61 213 264 367 391 203 279 511 157 394 73 30 -319 167 337 538 485 -129 -835 -912 -734 -414 -172 -7 -175 -217 -71 -294 144 -15 -101 -123 -384 -108 499 510 726 809 579 663 540 393 140 111 432 825 1207 1687 643 -95 -352 -664 23 363 530 414 148 384 44 -336 -679 -1185 -933 -1010 -1074 -1125 -2043 -1739 -1211 -584 -9 274 884 778 622 321 34 -268 -12 71 280 1107 752 -124 -446 -999 -1339 -636 -713 -975 -870 -644 -135 514 960 875 888 397 -124 -291 -26 -40 318 329 -147 11 735 475 818 377 61 601 649 403 331 -164 -241 -306 -65 81 -157 384 424 -275 -342 -823 -970 SS 20251007T141016.8Z 9411.590473 285 1 53.88 2 69.76 109.30 104.76 290.89 0.00 1 0.00 1 0 17 2.006e-02 6.487e-03 5.137e-03 1.200e-03 3.301969e-01 5.939095e-04 3.616606e-03 -6.000000e+00 1.117012e-02 227.25 -2.00 3.23 -2.00 317.78 0.00e+00 6.644047e-04 1.013673e-04 2.575693e-04 -6.000000e+00 5.107774e-04 290.89 -2.00 20.00 -2.00 316.91 0.00e+00 2.859 0.000 302.00 328.00 3 3.5234e+00 1.5845e-03 3.1830e-02 -6.0000e+00 2.7664e-02 1.2619e-02 1.8000e-03 1.5664e-02 -6.0000e+00 3.0004e-02 -3.2233e-03 1.1277e-03 7.6524e-03 -6.0000e+00 1.7961e-02 -1.1433e-03 5.8307e-04 2.1739e-03 -6.0000e+00 7.7983e-03 6.5480e-04 3.0797e-04 3.1990e-05 2.1129e-05 -6.0000e+00 4.9774e-04 2.4510e-02 0.0000e+00 11 8 0 10 0 0 99.98 25.66 0.19 0.02451 0.02682 130 15 1 5 0 414.450 33.75 20.00 25.66 33.88 0.0 1006.60 -6012 -2821 -6291 -4255 -13829 1895 -6829 -4013 -187 -2584 -1822 -3640 -4295 -4203 -103 657 -1652 1585 2108 -991 1663 941 409 2414 401 652 -917 590 -2405 -1407 344 2201 1599 -450 -3158 -3654 -2772 -1090 350 705 382 -492 410 -1879 185 -481 -363 -514 -937 -651 1385 724 1201 1289 979 1187 599 307 362 111 314 1440 1691 2290 899 299 27 -952 61 329 710 245 255 769 213 -439 -1198 -1591 -1464 -1093 -1124 -894 -1804 -1603 -1062 -640 114 266 850 714 676 73 -211 -465 -156 -46 69 854 672 -154 -395 -1031 -1062 -800 -713 -786 -617 -542 -226 616 681 388 447 430 -187 -210 -79 93 361 271 -83 -20 633 386 757 382 116 345 428 59 114 -168 -160 -284 -125 184 94 355 133 -89 -251 -526 -636 -449 -226 -542 -335 -1044 120 -511 -329 -17 -251 -172 -366 -509 -583 -16 104 -281 276 383 -194 324 181 82 513 91 156 -225 133 -519 -303 81 550 448 -135 -892 -1011 -849 -381 134 322 178 -241 207 -983 95 -250 -186 -260 -472 -330 741 424 741 789 626 771 403 207 237 72 209 1029 1325 1815 732 225 20 -716 48 280 622 226 235 677 188 -347 -925 -1173 -1134 -905 -990 -879 -1818 -1675 -1188 -725 135 326 1046 850 741 78 -222 -472 -158 -53 82 1085 877 -210 -508 -1297 -1225 -938 -876 -1018 -834 -734 -322 890 1059 594 697 630 -266 -293 -110 127 528 405 -127 -30 928 573 1056 541 156 458 588 88 172 -265 -258 -451 -212 315 165 638 244 -158 -428 -907 -1058 SS 20251007T143732.8Z 9411.609407 300 1 1.74 2 64.23 113.58 109.94 294.89 0.00 1 0.00 1 0 17 1.686e-02 9.233e-03 1.680e-02 7.084e-03 2.706723e-01 3.517182e-03 2.991751e-03 -6.000000e+00 9.393528e-03 227.25 -2.00 3.23 -2.00 316.58 0.00e+00 5.222282e-05 4.368364e-04 1.804672e-04 -6.000000e+00 4.295174e-04 290.89 -2.00 20.00 -2.00 315.74 0.00e+00 2.286 0.000 302.00 328.00 3 3.6903e+00 9.1624e-03 2.5580e-02 -6.0000e+00 2.3264e-02 -2.1159e-03 1.0278e-02 1.2755e-02 -6.0000e+00 2.5231e-02 6.5111e-03 6.0160e-03 6.2197e-03 -6.0000e+00 1.5104e-02 -5.1132e-03 2.9220e-03 1.7456e-03 -6.0000e+00 6.5583e-03 1.0456e-03 4.8900e-04 1.8749e-04 1.8523e-05 -6.0000e+00 4.1854e-04 2.4106e-02 0.0000e+00 12 9 1 12 1 1 999.00 25.70 0.38 0.02411 0.02778 1 7 1 5 0 869.990 33.75 20.00 25.70 34.45 0.0 1008.64 -1141 -1527 -1243 1942 -6970 -2508 -4220 592 -5315 1658 663 -5862 -795 -2943 3017 1496 -2331 1056 -2199 -3315 7011 3036 -2884 2277 1456 1928 -160 -416 856 -421 1166 -1409 1607 983 -1498 -1253 -334 -1234 2825 411 1313 -2324 -2133 -1977 -1490 -68 -936 526 -776 -522 1207 594 -2156 1716 -581 1671 1204 -31 -20 1674 147 1146 1598 1414 1253 722 -275 65 -162 1100 591 927 575 1535 -101 -704 -1210 -1788 -1876 -944 -764 -524 -1894 -714 -2180 -387 884 978 435 656 1178 -452 -42 -605 111 34 -208 -224 461 -439 -1775 -409 -928 -1250 -342 -652 -1435 -472 95 1192 -343 -240 512 741 418 532 -948 -307 913 1194 919 338 -653 593 1112 -314 81 220 1667 129 525 76 59 45 -428 -17 -199 336 32 -460 -579 -18 -933 -173 -253 -211 296 -1007 -339 -625 94 -1008 311 122 -1182 -175 -695 771 431 -722 330 -683 -1084 2284 1009 -969 779 526 726 -62 -150 303 -150 408 -542 660 424 -602 -489 -144 -576 1434 238 823 -1475 -1402 -1308 -974 -44 -600 344 -505 -339 822 413 -1533 1248 -448 1278 950 -25 -15 1265 116 916 1386 1261 1124 623 -223 54 -135 986 560 915 571 1455 -95 -629 -1033 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