File name: Pandora88s1_SanAntonioTX_20251224_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20251225T063846.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alberto Mestas-Nunez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora88_OF_v3d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20251224_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas at San Antonio Short location name: SanAntonioTX Country of location: United States Location latitude [deg]: 29.4230 Location longitude [deg]: -98.5025 Location altitude [m]: 222 Local noon date: 20251224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251224T150902.7Z 9489.631281 91 1 3.24 2 72.19 131.31 111.17 95.81 0.00 1 0.00 1 0 25 1.964e-02 6.671e-03 1.224e-02 3.090e-03 3.445210e-01 1.510998e-03 3.790832e-03 -6.000000e+00 1.080424e-02 224.19 -2.00 3.23 -2.00 317.64 0.00e+00 7.372425e-04 2.441010e-04 1.062006e-04 -6.000000e+00 4.875916e-04 284.95 -2.00 20.00 -2.00 316.87 0.00e+00 3.224 0.000 302.00 328.00 3 2.3090e+00 3.9926e-03 3.5110e-02 -6.0000e+00 2.6628e-02 -6.0602e-03 4.5186e-03 1.6145e-02 -6.0000e+00 2.8981e-02 -5.5354e-03 2.8212e-03 7.9428e-03 -6.0000e+00 1.7327e-02 -6.8691e-04 1.4577e-03 2.3555e-03 -6.0000e+00 7.5225e-03 1.5670e-03 3.1472e-04 8.1998e-05 2.3116e-05 -6.0000e+00 4.8721e-04 2.9928e-02 0.0000e+00 12 9 1 12 1 1 98.49 24.75 0.31 0.02993 0.03229 9 19 1 5 0 323.650 33.25 20.00 24.75 27.65 0.0 978.66 -7741 -580 -8307 -9653 -5567 2095 -1915 -4451 -2481 -3350 -3757 -1689 -2142 -7126 819 615 73 -420 3208 168 3234 318 2726 -635 593 -445 2401 -242 -3509 -1383 2948 683 1153 806 -2708 -4560 -2841 -1198 769 -47 -10 -111 -424 -1836 316 -464 158 185 -344 88 383 1462 1148 355 389 300 935 799 1124 262 1320 716 1709 2184 1008 -810 114 -1089 219 291 277 290 697 498 365 -730 -870 -1301 -1608 -292 -839 -1297 -1999 -1741 -834 -678 333 236 456 267 1156 225 295 -900 61 -515 564 808 546 -416 -46 -790 -878 -737 -637 -599 -742 -359 -287 321 815 593 341 358 -283 -256 -398 -185 213 443 159 -155 638 -159 449 675 7 235 550 70 312 269 20 -281 -17 -166 391 310 221 -357 -369 -489 -603 -637 -49 -791 -867 -419 145 -149 -402 -248 -360 -398 -185 -254 -1042 130 111 14 -85 661 37 710 71 616 -147 143 -114 604 -59 -815 -320 727 188 354 261 -828 -1396 -958 -427 305 -22 -5 -57 -226 -1005 169 -253 85 98 -183 47 222 854 715 224 256 202 644 548 749 174 898 503 1310 1725 816 -647 86 -813 172 251 250 261 655 450 306 -581 -666 -958 -1260 -247 -770 -1277 -2040 -1844 -903 -757 386 284 553 313 1290 243 295 -925 63 -580 675 1008 737 -556 -58 -953 -1014 -869 -799 -759 -986 -485 -408 474 1245 903 524 535 -407 -343 -534 -258 307 659 242 -231 961 -232 638 921 10 316 776 104 476 428 32 -458 -28 -288 692 546 396 -620 -634 -837 -999 SS 20251224T162749.1Z 9489.685985 149 1 20.62 2 60.89 146.71 94.74 104.37 0.00 1 0.00 1 0 17 9.525e-03 6.508e-03 1.139e-03 6.720e-04 2.211334e-01 3.314980e-04 2.474529e-03 -6.000000e+00 5.240435e-03 224.19 -2.00 3.23 -2.00 315.62 0.00e+00 5.411101e-04 3.286228e-05 2.963549e-05 -6.000000e+00 2.364554e-04 284.94 -2.00 20.00 -2.00 314.94 0.00e+00 2.046 0.000 302.00 328.00 3 2.5334e+00 8.4821e-04 2.2320e-02 -6.0000e+00 1.2915e-02 -2.9185e-03 9.4878e-04 1.0314e-02 -6.0000e+00 1.4056e-02 2.1583e-03 5.4691e-04 5.0660e-03 -6.0000e+00 8.4033e-03 -3.1766e-03 2.5364e-04 1.4846e-03 -6.0000e+00 3.6493e-03 4.5636e-03 3.8277e-04 1.7700e-05 1.6312e-05 -6.0000e+00 2.3624e-04 2.8070e-02 0.0000e+00 12 9 1 12 1 1 99.98 24.84 0.30 0.02807 0.03095 130 39 1 5 0 157.360 33.25 20.00 24.84 29.40 0.0 986.61 -725 -152 -429 -2841 -3945 -2645 -1118 63 394 -494 -1892 -1769 -960 -484 1084 243 450 718 1093 1497 935 899 1284 1140 711 764 401 -292 -692 253 1456 1118 1588 -206 -2671 -2840 -1951 -1247 -173 -1 -549 -601 -300 -759 -122 -416 -362 -431 -635 -217 708 582 883 1059 823 837 686 592 399 171 695 1128 1587 1747 626 -383 -619 -1002 -44 440 561 428 128 499 233 -437 -942 -1690 -1218 -1003 -1210 -1047 -1815 -1624 -1016 -505 -70 225 714 623 536 250 46 -315 -137 96 283 977 597 103 -191 -680 -1129 -495 -510 -657 -730 -492 -98 489 662 586 629 203 -172 -311 -227 -30 145 308 75 223 434 374 558 360 17 190 459 227 75 -84 -264 -187 -44 150 -6 153 285 -172 -217 -479 -675 -182 -41 -118 -736 -964 -621 -277 16 111 -147 -548 -519 -294 -167 392 97 184 302 475 628 401 402 550 520 338 378 200 -136 -314 112 639 521 803 -103 -1315 -1364 -973 -711 -106 -1 -388 -439 -226 -578 -92 -314 -267 -308 -465 -157 512 451 683 865 663 682 573 492 325 145 577 1004 1463 1655 596 -347 -542 -849 -39 409 550 439 132 495 225 -396 -804 -1422 -1055 -901 -1172 -1078 -1938 -1792 -1157 -596 -84 279 889 748 613 281 49 -318 -145 108 329 1215 771 131 -236 -810 -1297 -581 -621 -843 -947 -649 -134 685 954 857 884 274 -226 -393 -285 -39 190 423 106 313 596 509 736 471 21 239 598 306 103 -116 -369 -267 -65 228 -10 238 452 -266 -334 -716 -1009 SS 20251224T163222.1Z 9489.689145 152 1 3.25 2 60.35 147.74 93.80 104.88 0.00 1 0.00 1 0 17 9.918e-03 6.685e-03 3.276e-03 1.990e-03 2.174305e-01 9.823204e-04 2.433472e-03 -6.000000e+00 5.457055e-03 224.19 -2.00 3.23 -2.00 315.51 0.00e+00 4.667340e-04 9.523280e-05 2.953938e-05 -6.000000e+00 2.462213e-04 284.94 -2.00 20.00 -2.00 314.84 0.00e+00 2.013 0.000 302.00 328.00 3 2.8173e+00 2.5114e-03 2.1951e-02 -6.0000e+00 1.3449e-02 -2.2204e-03 2.8078e-03 1.0128e-02 -6.0000e+00 1.4636e-02 3.1860e-03 1.6173e-03 4.9788e-03 -6.0000e+00 8.7505e-03 -3.4313e-03 7.4643e-04 1.4495e-03 -6.0000e+00 3.8003e-03 3.5675e-03 4.9271e-04 5.2445e-05 1.6230e-05 -6.0000e+00 2.4599e-04 2.7744e-02 0.0000e+00 12 9 1 12 1 1 93.13 24.85 0.29 0.02774 0.03145 10 21 1 5 0 294.560 33.25 20.00 24.85 29.59 0.0 986.45 -1234 -284 -2292 -2571 -3608 -2462 -1403 -263 757 -1859 -1325 -931 -600 -337 618 1450 567 1306 1919 950 864 751 1508 1303 794 1091 555 287 -1029 -435 68 1675 1484 -268 -2712 -2751 -2696 -722 125 244 -633 -909 -451 -1527 -432 -273 -51 -62 -585 -533 1248 639 987 1102 1073 798 389 180 924 275 466 976 1554 1533 432 -303 -469 -811 63 290 163 558 262 594 285 -444 -1088 -1820 -976 -952 -1309 -1095 -1794 -1598 -883 -322 21 229 736 726 407 438 -72 -345 -135 26 -56 874 330 101 -277 -714 -1048 -540 -581 -623 -622 -431 -79 351 537 843 602 28 -81 -308 -36 -166 323 557 6 23 694 320 698 180 -60 227 351 199 301 211 -358 -196 76 -44 -305 144 322 -118 -271 -247 -830 -344 -78 -659 -731 -893 -586 -354 -73 216 -573 -389 -277 -201 -119 246 587 236 559 845 437 381 344 703 608 387 552 283 136 -478 -198 31 791 765 -137 -1360 -1344 -1384 -418 78 171 -462 -687 -336 -1156 -321 -203 -38 -45 -419 -378 922 486 784 886 888 669 335 154 769 229 399 859 1419 1444 410 -271 -404 -703 55 277 165 567 268 606 272 -412 -952 -1501 -825 -876 -1252 -1116 -1899 -1748 -999 -378 25 283 915 870 464 487 -76 -357 -141 30 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