File name: Pandora88s1_SanAntonioTX_20260108_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20260109T064645.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alberto Mestas-Nunez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora88_OF_v3d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20260108_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas at San Antonio Short location name: SanAntonioTX Country of location: United States Location latitude [deg]: 29.4230 Location longitude [deg]: -98.5025 Location altitude [m]: 222 Local noon date: 20260108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260108T183757.3Z 9504.776357 449 1 10.91 2 51.59 179.14 110.51 281.30 0.00 1 0.00 1 0 17 1.344e-02 8.888e-03 6.711e-03 3.851e-03 2.033065e-01 1.896648e-03 2.280731e-03 -6.000000e+00 7.397729e-03 224.23 -2.00 3.23 -2.00 315.62 0.00e+00 1.006961e-03 1.889618e-04 3.537738e-05 -6.000000e+00 3.327038e-04 284.32 -2.00 20.00 -2.00 314.96 0.00e+00 1.606 0.000 302.00 328.00 3 5.3751e+00 4.8565e-03 1.8232e-02 -6.0000e+00 1.8238e-02 3.9501e-02 5.4368e-03 9.5188e-03 -6.0000e+00 1.9845e-02 3.5061e-03 3.1342e-03 4.6730e-03 -6.0000e+00 1.1859e-02 -4.9739e-03 1.4570e-03 1.4798e-03 -6.0000e+00 5.1508e-03 4.0627e-04 8.1595e-04 1.0115e-04 1.5340e-05 -6.0000e+00 3.3312e-04 2.3155e-02 0.0000e+00 12 9 1 12 9 1 99.83 25.16 0.20 0.02316 0.02929 3 2 1 5 0 2726.130 33.50 20.00 25.16 31.66 0.0 995.55 -2633 1026 496 -1863 -4994 538 -3474 -1993 -534 -3006 1536 2167 -1475 -5474 429 841 45 1438 1480 883 1788 919 1314 1708 1107 1799 3233 -1686 -904 498 2354 2214 271 184 -3020 -2576 -1245 -1196 -689 200 -1048 -631 259 -2697 -174 -1418 -826 -596 -499 80 891 494 388 1698 -424 240 282 589 558 547 1108 1340 1895 2347 1222 -649 -555 -443 -579 144 -379 576 420 952 706 -1466 -1251 -2507 -996 -44 -2001 -686 -1488 -1680 -548 -6 186 472 845 1178 1121 -300 -1339 -1114 -539 323 796 923 595 301 -634 -656 -1424 -1009 -749 -928 -1089 -626 243 417 888 1051 932 457 -502 -81 -412 -47 -431 366 127 -119 593 609 895 671 -361 45 157 81 538 -394 -718 -356 -362 220 236 940 253 -67 -106 -679 -844 -668 270 134 -470 -1115 110 -785 -493 -145 -873 408 576 -459 -1833 153 327 18 583 620 384 782 395 574 785 529 885 1569 -795 -386 206 1013 1003 136 96 -1455 -1197 -633 -643 -443 139 -745 -461 193 -2087 -130 -1075 -606 -451 -366 57 671 371 306 1390 -364 206 247 511 473 460 954 1160 1765 2325 1215 -592 -496 -379 -519 138 -377 592 434 943 695 -1318 -1073 -2029 -816 -41 -1959 -689 -1607 -1878 -615 -7 222 583 1052 1487 1300 -340 -1388 -1154 -581 358 916 1120 774 384 -808 -774 -1662 -1137 -934 -1156 -1416 -849 323 585 1312 1568 1337 642 -648 -102 -514 -61 -569 518 177 -164 840 825 1138 862 -441 54 201 105 722 -550 -1013 -512 -528 337 353 1430 396 -103 -163 -1023 -1234 SS 20260108T195312.4Z 9504.828616 499 1 53.84 2 54.44 200.70 125.80 292.44 0.00 1 0.00 1 0 17 1.283e-02 7.423e-03 3.969e-03 1.848e-03 2.146968e-01 9.076968e-04 2.385341e-03 -6.000000e+00 7.061917e-03 224.23 -2.00 3.23 -2.00 316.34 0.00e+00 8.279763e-04 1.061114e-04 9.099576e-05 -6.000000e+00 3.177043e-04 284.32 -2.00 20.00 -2.00 315.62 0.00e+00 1.715 0.000 302.00 328.00 3 5.4969e+00 2.3475e-03 1.9385e-02 -6.0000e+00 1.7410e-02 2.2766e-02 2.6354e-03 9.9712e-03 -6.0000e+00 1.8946e-02 4.9895e-03 1.5417e-03 4.9262e-03 -6.0000e+00 1.1323e-02 -6.4108e-03 7.3836e-04 1.4854e-03 -6.0000e+00 4.9154e-03 3.2004e-04 3.2357e-04 4.9336e-05 1.5232e-05 -6.0000e+00 3.1821e-04 2.6103e-02 0.0000e+00 11 8 0 10 0 0 99.99 25.28 0.39 0.02610 0.02853 97 11 1 5 0 554.970 33.50 20.00 25.28 33.51 0.0 1002.48 -2896 -1916 -1928 -2147 -2863 2284 -2061 -1667 -790 -3178 2763 -190 -3053 -4283 860 556 -284 1294 1150 574 2804 842 2365 2607 1025 348 2510 -907 -994 1376 1028 3013 2092 315 -2366 -3191 -2168 -277 236 326 -1074 -351 -572 -3020 -487 -1627 -500 -175 -1255 -51 706 306 1333 353 486 1277 1110 846 435 -33 1062 472 1398 2106 685 23 93 -1203 123 29 50 593 399 1186 591 -525 -1628 -2063 -875 -860 -1204 -671 -1787 -1491 -716 -349 291 308 582 733 679 -44 -528 -659 -632 303 16 770 486 -169 -292 -785 -1156 -903 -499 -941 -568 -160 -128 518 804 414 309 813 -324 -555 -307 -134 305 554 -222 549 971 423 828 204 -388 99 375 -217 -47 -60 -248 -317 41 274 33 422 253 -268 -257 -634 -529 -553 -391 -401 -411 -474 348 -350 -313 -164 -710 557 -40 -747 -1200 260 168 -88 410 377 196 950 284 802 935 387 137 972 -336 -371 493 394 1084 827 131 -913 -1204 -898 -129 132 196 -712 -239 -402 -2192 -342 -1157 -343 -115 -816 -32 470 219 986 278 393 1035 921 699 353 -27 874 388 1233 1975 649 19 80 -1005 106 27 50 620 419 1191 557 -448 -1364 -1620 -699 -778 -1128 -692 -1848 -1589 -814 -426 347 380 725 880 802 -48 -561 -663 -667 324 19 945 640 -219 -356 -953 -1305 -1043 -636 -1185 -743 -219 -183 728 1193 625 450 1164 -428 -726 -397 -167 409 802 -334 809 1404 589 1080 274 -494 123 499 -288 -66 -86 -361 -473 61 431 54 695 426 -441 -407 -979 -791 SS 20260108T195811.9Z 9504.832082 502 1 8.12 2 54.83 202.03 126.77 293.31 0.00 1 0.00 1 0 17 1.034e-02 7.017e-03 4.011e-03 2.335e-03 2.161967e-01 1.151824e-03 2.423842e-03 -6.000000e+00 5.692200e-03 224.23 -2.00 3.23 -2.00 315.63 0.00e+00 5.386699e-04 1.148095e-04 3.082875e-05 -6.000000e+00 2.560693e-04 284.32 -2.00 20.00 -2.00 314.98 0.00e+00 1.731 0.000 302.00 328.00 3 4.2278e+00 2.9488e-03 1.9568e-02 -6.0000e+00 1.4033e-02 -5.5914e-03 3.3001e-03 1.0053e-02 -6.0000e+00 1.5271e-02 1.0958e-02 1.9025e-03 4.9617e-03 -6.0000e+00 9.1263e-03 -7.4524e-03 8.8397e-04 1.4553e-03 -6.0000e+00 3.9622e-03 1.1301e-03 3.4065e-04 6.1317e-05 1.5836e-05 -6.0000e+00 2.5646e-04 2.5607e-02 0.0000e+00 12 9 1 12 1 1 94.84 25.29 0.25 0.02561 0.02817 7 6 1 5 0 1013.890 33.50 20.00 25.29 33.52 0.0 1002.65 -842 982 -1022 -2818 -4958 1142 -1728 -549 851 -1122 -1156 -94 -546 -1795 -932 -880 741 1245 545 576 1552 1105 1956 2128 692 691 1046 -697 -331 1145 615 943 2114 402 -2262 -2256 -2749 -1724 -105 -161 -781 -932 -1050 -530 319 -236 -918 -633 -1171 -669 1150 688 920 947 961 774 227 612 801 39 887 1503 1252 1778 809 -296 -637 -1103 -192 194 549 302 341 120 273 -374 -1114 -1477 -1360 -426 -1582 -826 -1700 -1635 -614 -369 -47 464 671 633 904 319 -84 -499 -276 257 380 1112 639 189 -274 -887 -1357 -766 -431 -588 -977 -273 -5 278 676 474 674 426 -157 -632 -64 -132 456 287 -76 -187 498 609 262 432 -277 313 499 220 66 -297 -37 -274 -107 205 -37 64 427 55 -133 -410 -864 -210 260 -282 -727 -1125 258 -393 -138 235 -333 -329 -27 -163 -615 -359 -346 293 506 231 253 685 478 860 992 317 329 499 -335 -145 486 279 451 1015 203 -1062 -1100 -1397 -935 -63 -109 -575 -673 -785 -397 235 -175 -669 -469 -851 -478 853 520 726 790 784 639 193 515 657 32 743 1345 1160 1676 767 -268 -562 -940 -169 187 553 305 345 123 261 -337 -953 -1246 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