File name: Pandora88s1_SanAntonioTX_20260707_L2Fit_fout2c2d20240901p1-8.txt File generation date: 20260708T064921.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alberto Mestas-Nunez Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 88 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora88_OF_v3d20240227.txt Instrument calibration file used: Pandora88s1_CF_v2d20240901.txt Level 1 file used: Pandora88s1_SanAntonioTX_20260707_L1_smca1c2d20240901p1-8.txt Full location name: University of Texas at San Antonio Short location name: SanAntonioTX Country of location: United States Location latitude [deg]: 29.4230 Location longitude [deg]: -98.5025 Location altitude [m]: 222 Local noon date: 20260707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0435 305.1841 305.3247 305.4653 305.6059 305.7464 305.8870 306.0275 306.1680 306.3086 306.4491 306.5895 306.7300 306.8705 307.0110 307.1514 307.2918 307.4323 307.5727 307.7131 307.8535 307.9939 308.1342 308.2746 308.4150 308.5553 308.6956 308.8359 308.9762 309.1165 309.2568 309.3971 309.5373 309.6776 309.8178 309.9581 310.0983 310.2385 310.3787 310.5189 310.6590 310.7992 310.9393 311.0795 311.2196 311.3597 311.4998 311.6399 311.7800 311.9201 312.0601 312.2002 312.3402 312.4803 312.6203 312.7603 312.9003 313.0403 313.1802 313.3202 313.4601 313.6001 313.7400 313.8799 314.0198 314.1597 314.2996 314.4395 314.5793 314.7192 314.8590 314.9988 315.1386 315.2785 315.4182 315.5580 315.6978 315.8376 315.9773 316.1170 316.2568 316.3965 316.5362 316.6759 316.8155 316.9552 317.0949 317.2345 317.3741 317.5138 317.6534 317.7930 317.9326 318.0721 318.2117 318.3513 318.4908 318.6303 318.7699 318.9094 319.0489 319.1884 319.3278 319.4673 319.6067 319.7462 319.8856 320.0250 320.1644 320.3038 320.4432 320.5826 320.7220 320.8613 321.0006 321.1400 321.2793 321.4186 321.5579 321.6972 321.8364 321.9757 322.1149 322.2542 322.3934 322.5326 322.6718 322.8110 322.9502 323.0893 323.2285 323.3676 323.5068 323.6459 323.7850 323.9241 324.0632 324.2023 324.3413 324.4804 324.6194 324.7585 324.8975 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260707T151827.0Z 9684.637813 324 1 54.42 2 45.27 86.53 48.43 253.51 0.00 1 0.00 1 0 25 1.184e-02 8.153e-03 3.159e-03 1.819e-03 1.919986e-01 9.134625e-04 2.099066e-03 -6.000000e+00 6.650798e-03 230.04 -2.00 3.23 -2.00 315.64 0.00e+00 8.363950e-04 9.288094e-05 9.226086e-05 -6.000000e+00 3.037587e-04 292.78 -2.00 20.00 -2.00 314.86 0.00e+00 1.419 0.000 302.00 328.00 3 5.8311e+00 2.3680e-03 1.6559e-02 -6.0000e+00 1.6571e-02 2.8360e-02 2.6385e-03 9.0681e-03 -6.0000e+00 1.7939e-02 5.0701e-03 1.5126e-03 4.3789e-03 -6.0000e+00 1.0726e-02 -7.0844e-03 6.9823e-04 1.2643e-03 -6.0000e+00 4.6298e-03 3.1421e-04 5.9644e-04 4.8047e-05 1.3302e-05 -6.0000e+00 2.9417e-04 3.5960e-02 0.0000e+00 11 9 0 11 8 0 99.98 26.02 0.38 0.03596 0.04044 15 2 1 5 0 3627.530 34.00 20.00 26.02 36.14 0.0 1012.09 -1216 550 -976 -3737 -4071 3869 -938 720 -807 -1031 -221 1201 -822 313 -1022 1232 -155 1437 661 -91 1553 601 566 3137 1170 1655 567 -950 575 -1012 274 2490 991 550 -3261 -3678 -2394 -1143 -493 434 -134 -1260 -537 -3274 -913 -594 -1131 -974 -753 561 992 385 1152 1554 446 1009 117 460 992 250 1301 1178 1715 2074 833 35 253 -1314 -259 -6 82 664 548 707 291 -734 -1066 -1801 -1082 -174 -1612 -983 -965 -1591 -525 -85 148 515 756 1027 612 -231 -858 -1077 -921 -43 391 894 510 68 -385 -1113 -1340 -598 -854 -664 -623 -901 175 821 858 210 637 682 -410 -105 -846 195 381 731 11 616 674 306 937 184 -160 -132 266 -747 -397 4 -703 -150 -137 21 316 605 551 113 -262 -630 -736 -302 144 -261 -931 -964 827 -225 172 -217 -288 -58 317 -249 105 -393 502 -65 609 291 -38 650 269 239 1361 534 779 269 -420 249 -440 124 1159 466 265 -1592 -1773 -1163 -631 -300 306 -102 -927 -405 -2543 -687 -445 -890 -737 -551 399 745 309 890 1259 373 847 101 393 823 208 1107 1079 1575 2018 805 32 218 -1103 -227 -5 84 702 580 721 277 -675 -883 -1511 -933 -156 -1524 -1019 -1060 -1706 -601 -105 179 643 949 1235 718 -266 -896 -1068 -961 -49 458 1091 663 87 -488 -1317 -1482 -682 -1083 -829 -811 -1232 247 1145 1259 312 900 943 -520 -131 -1058 252 498 1029 15 883 950 413 1181 237 -195 -158 341 -962 -534 5 -981 -214 -196 32 487 957 839 178 -399 -935 -1061 SS 20260707T152701.9Z 9684.643772 330 1 54.64 2 43.40 87.49 50.18 255.01 0.00 1 0.00 1 0 17 1.121e-02 7.761e-03 2.517e-03 1.544e-03 1.889262e-01 7.780462e-04 2.075189e-03 -6.000000e+00 6.297271e-03 230.04 -2.00 3.23 -2.00 315.41 0.00e+00 6.946753e-04 7.499675e-05 6.773926e-05 -6.000000e+00 2.875948e-04 292.78 -2.00 20.00 -2.00 314.64 0.00e+00 1.375 0.000 302.00 328.00 3 5.6196e+00 2.0105e-03 1.6134e-02 -6.0000e+00 1.5690e-02 2.8148e-02 2.2380e-03 8.9349e-03 -6.0000e+00 1.6985e-02 6.0280e-04 1.2813e-03 4.3185e-03 -6.0000e+00 1.0156e-02 -5.9256e-03 5.8420e-04 1.2307e-03 -6.0000e+00 4.3841e-03 4.0835e-04 5.8842e-04 4.0528e-05 1.3477e-05 -6.0000e+00 2.7849e-04 3.5246e-02 0.0000e+00 11 9 0 11 8 0 99.95 26.05 0.38 0.03525 0.03967 16 2 1 5 0 3414.920 34.00 20.01 26.05 36.62 0.0 1013.40 -285 -229 -1056 -3281 -5770 1109 -1032 -37 -457 268 -1367 266 -396 -200 616 1820 1240 1184 267 805 1100 409 1706 1914 1234 1416 79 -402 -738 -723 884 1726 1599 -109 -3145 -3241 -2664 -786 70 24 -658 -1144 -614 -3063 -406 -709 -1169 -1043 -670 671 745 232 861 1688 570 1065 84 1008 846 379 1139 1076 1674 1899 613 133 7 -1227 -457 207 252 444 656 882 71 -829 -1062 -2020 -955 -752 -1471 -1096 -1361 -1589 -308 -351 135 491 740 714 664 -30 -586 -706 -737 48 7 957 562 -93 -352 -691 -1273 -349 -894 -791 -513 -500 293 655 882 557 943 725 -355 -360 -774 215 204 474 -26 482 625 195 559 -40 -27 -26 11 -471 -210 -46 -539 -229 -94 -72 222 509 413 44 -246 -461 -469 -80 -69 -321 -925 -1433 251 -255 -10 -139 84 -413 80 -135 -70 240 758 526 516 121 375 517 189 796 940 629 689 39 -197 -331 -319 406 823 827 -59 -1558 -1579 -1436 -442 47 18 -483 -868 -478 -2447 -313 -548 -879 -808 -500 488 573 177 683 1399 488 915 74 876 720 322 994 1009 1579 1900 610 119 7 -1049 -408 197 263 454 668 919 70 -778 -897 -1721 -777 -690 -1418 -1161 -1443 -1746 -360 -417 168 631 956 886 755 -33 -623 -712 -781 53 8 1197 709 -121 -431 -833 -1439 -406 -1095 -1016 -649 -662 400 894 1265 807 1298 973 -462 -434 -933 267 274 650 -36 672 856 256 726 -50 -33 -32 14 -620 -274 -61 -728 -316 -138 -107 335 786 649 68 -367 -668 -693 SS 20260707T153552.4Z 9684.649912 336 1 54.22 2 41.48 88.50 51.99 256.48 0.00 1 0.00 1 0 17 1.120e-02 7.751e-03 2.700e-03 1.640e-03 1.820280e-01 8.258751e-04 2.004717e-03 -6.000000e+00 6.293937e-03 230.04 -2.00 3.23 -2.00 315.43 0.00e+00 6.833546e-04 7.970032e-05 8.316139e-05 -6.000000e+00 2.874464e-04 292.78 -2.00 20.00 -2.00 314.64 0.00e+00 1.333 0.000 302.00 328.00 3 5.7582e+00 2.1335e-03 1.5616e-02 -6.0000e+00 1.5681e-02 1.6335e-02 2.3746e-03 8.6076e-03 -6.0000e+00 1.6976e-02 3.1441e-03 1.3640e-03 4.1629e-03 -6.0000e+00 1.0150e-02 -5.9953e-03 6.2197e-04 1.1806e-03 -6.0000e+00 4.3817e-03 3.7638e-04 6.6020e-04 4.3140e-05 1.3074e-05 -6.0000e+00 2.7835e-04 3.5374e-02 0.0000e+00 11 9 0 11 8 0 99.96 26.07 0.47 0.03537 0.04033 20 2 1 5 0 2710.550 34.00 20.00 26.07 37.18 0.0 1015.74 -1439 1257 -1724 -2758 -5331 1873 -9 297 946 454 -2044 -350 -709 256 54 555 222 1541 1090 737 1344 152 1273 3035 1386 1214 886 -810 -10 -826 785 1473 490 525 -3727 -2846 -2453 -755 -137 -26 -557 -1377 -500 -2874 -802 -731 -911 -1047 -902 163 704 376 1405 1469 275 777 254 694 817 193 850 1374 1517 1948 802 367 218 -1150 -197 191 403 607 532 810 -75 -523 -551 -1878 -871 -625 -1439 -968 -1165 -1168 -406 -465 410 378 738 779 647 115 -757 -1182 -529 -200 70 803 654 -192 -826 -918 -1467 -446 -1015 -722 -448 -247 -38 810 841 567 908 981 -535 -429 -693 -5 277 459 95 422 376 388 690 57 -202 10 194 -601 -248 -124 -248 -208 -70 300 102 508 558 -46 -257 -577 -643 -405 367 -523 -765 -1304 416 -2 80 280 140 -613 -104 -238 95 21 229 93 654 479 335 615 69 582 1436 688 625 455 -389 -4 -355 350 682 248 270 -1794 -1335 -1276 -444 -89 -19 -422 -1082 -402 -2368 -641 -584 -706 -781 -649 123 519 296 1141 1254 243 688 215 580 715 169 714 1233 1466 1867 813 334 196 -1006 -180 186 402 628 550 807 -75 -468 -474 -1526 -725 -585 -1410 -975 -1247 -1293 -453 -559 513 463 910 975 742 128 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