File name: Pandora82s1_SanJose-UCR_20260326_L2Fit_fout2c2d20240415p1-8.txt File generation date: 20260327T055045.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 82 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora82_OF_v3d20230727.txt Instrument calibration file used: Pandora82s1_CF_v2d20240415.txt Level 1 file used: Pandora82s1_SanJose-UCR_20260326_L1_smca1c2d20240415p1-8.txt Full location name: GasLab, Universidad de Costa Rica Short location name: SanJose-UCR Country of location: Costa Rica Location latitude [deg]: 9.9396 Location longitude [deg]: -84.0422 Location altitude [m]: 1226 Local noon date: 20260326 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0740 305.2147 305.3554 305.4961 305.6368 305.7774 305.9181 306.0587 306.1993 306.3400 306.4806 306.6211 306.7617 306.9023 307.0428 307.1834 307.3239 307.4644 307.6049 307.7454 307.8859 308.0264 308.1668 308.3073 308.4477 308.5881 308.7285 308.8689 309.0093 309.1497 309.2900 309.4304 309.5707 309.7110 309.8513 309.9916 310.1319 310.2722 310.4125 310.5527 310.6930 310.8332 310.9734 311.1136 311.2538 311.3940 311.5341 311.6743 311.8144 311.9546 312.0947 312.2348 312.3749 312.5150 312.6550 312.7951 312.9351 313.0752 313.2152 313.3552 313.4952 313.6352 313.7752 313.9151 314.0551 314.1950 314.3349 314.4748 314.6147 314.7546 314.8945 315.0344 315.1742 315.3141 315.4539 315.5937 315.7335 315.8733 316.0131 316.1528 316.2926 316.4323 316.5721 316.7118 316.8515 316.9912 317.1308 317.2705 317.4102 317.5498 317.6894 317.8291 317.9687 318.1083 318.2478 318.3874 318.5270 318.6665 318.8061 318.9456 319.0851 319.2246 319.3641 319.5035 319.6430 319.7824 319.9219 320.0613 320.2007 320.3401 320.4795 320.6189 320.7582 320.8976 321.0369 321.1763 321.3156 321.4549 321.5942 321.7334 321.8727 322.0120 322.1512 322.2904 322.4296 322.5688 322.7080 322.8472 322.9864 323.1255 323.2647 323.4038 323.5429 323.6820 323.8211 323.9602 324.0993 324.2383 324.3774 324.5164 324.6554 324.7944 324.9334 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260326T120237.6Z 9581.501825 75 1 55.10 2 84.49 88.60 143.36 350.90 0.00 1 0.00 1 0 25 6.321e-01 2.508e-02 2.836e-01 8.696e-03 7.887698e-01 4.888416e-03 3.210138e-02 -6.000000e+00 3.638687e-01 227.07 -2.00 3.06 -2.00 321.81 0.00e+00 -6.051965e-03 3.114084e-03 8.415991e-02 -6.000000e+00 1.914650e-02 288.07 -2.00 20.00 -2.00 321.25 0.00e+00 9.140 0.001 302.00 328.00 3 1.3906e+00 2.0329e-02 4.9048e-01 -6.0000e+00 9.0563e-01 5.6402e-01 2.9650e-02 6.4714e-01 -6.0000e+00 9.9181e-01 -7.9940e-01 2.6710e-02 1.8031e-01 -6.0000e+00 5.8950e-01 3.1411e-01 1.1496e-02 4.2192e-02 -6.0000e+00 2.5091e-01 2.8518e-05 3.4626e-02 2.1845e-04 8.5650e-04 -6.0000e+00 1.7257e-02 1.8771e-01 12 8 8 10 0 0 41.93 24.43 0.90 0.18771 0.44790 29 3 1 5 0 1899.510 32.50 20.00 24.43 22.44 4.4 864.40 -218270 -135847 900000 900000 -129432 -152047 -219143 900000 900000 -78993 -88091 -110048 900000 900000 900000 900000 -26525 900000 -53720 -1126 -50104 -32736 -120050 900000 -21362 47297 -63563 -20226 25081 74676 -14641 -38314 -10658 198797 34898 26177 62082 266678 2211 900000 12746 270682 -12528 47582 77827 21164 230478 22165 26178 41305 70409 -11376 55719 25884 56295 92608 13749 14835 -1613 446 21218 14422 19334 9849 -6320 -544 14926 13964 5855 10063 5585 13495 505 5700 -584 12142 -5966 13144 -2932 6004 2838 3743 -4527 5447 7905 659 857 -9137 6978 -2295 733 -4408 -2668 1047 -1150 -4479 -1842 -2873 -3114 -5778 -4742 -1688 -1960 -245 1380 -1466 -744 1793 -438 147 -621 1319 -1909 -1524 264 -4229 2354 763 17 2703 -67 1827 -851 2811 1416 2845 1940 88 -22 -198 806 -690 1583 -107 -297 1082 142 -849 773 -1631 -779 -1169 900000 -5540 -1463 900000 900000 -1692 -2807 -8427 900000 900000 -1094 -1626 -3047 900000 900000 900000 900000 -449 900000 -1157 -16 -1272 -755 -6925 900000 -411 437 -1956 -482 444 919 -450 -1385 -295 1682 832 846 1671 2256 126 900000 722 2290 -901 1892 2370 1200 1950 1538 1949 2900 4051 -1578 4148 2672 4191 4544 1431 1569 -222 69 3016 2269 2830 1616 -1294 -119 3245 3343 1565 2503 1347 2694 103 1051 -121 2568 -1822 3903 -1181 2423 1256 1767 -2470 2807 4059 362 446 -4893 3028 -1085 361 -2651 -1856 746 -971 -4227 -1669 -2453 -2388 -4570 -3823 -1434 -1598 -209 1265 -1547 -895 2370 -632 213 -886 1762 -2560 -2083 374 -6655 3573 1147 25 3703 -92 2362 -1100 3422 1889 4353 3134 160 -43 -417 1800 -1563 3676 -257 -731 2600 325 -1991 1673 -3509 -1746 -2689 900000 SS 20260326T121405.5Z 9581.509786 78 1 54.16 2 81.66 89.09 143.71 354.93 0.00 1 0.00 1 0 33 3.457e-01 8.291e-03 3.927e-02 1.495e-03 6.340528e-01 7.612651e-04 1.644991e-02 -6.000000e+00 1.939699e-01 227.07 -2.00 3.06 -2.00 320.35 0.00e+00 1.308562e-03 3.167841e-04 2.290404e-02 -6.000000e+00 8.898968e-03 288.07 -2.00 20.00 -2.00 319.65 0.00e+00 6.487 0.000 302.00 328.00 3 8.4334e-01 2.3992e-03 1.2410e-01 -6.0000e+00 4.8028e-01 4.7506e-02 3.0865e-03 1.4673e-01 -6.0000e+00 5.2245e-01 -8.2808e-02 2.7953e-03 3.6414e-02 -6.0000e+00 3.1246e-01 2.5542e-02 1.3628e-03 1.2232e-02 -6.0000e+00 1.3436e-01 5.0415e-04 3.5109e-02 3.7299e-05 2.1367e-04 -6.0000e+00 9.1251e-03 1.8343e-01 11 8 0 10 0 0 55.43 24.50 0.35 0.18343 0.44726 172 18 1 5 0 314.860 32.50 20.01 24.50 23.42 4.4 871.48 -165980 -141507 -119927 -133540 -47656 -137966 -131613 -111669 -82370 -83645 -54379 -54931 -36719 -26610 -11376 6668 -28010 -21286 -34471 -28672 -23311 -15935 -29111 -18895 -25760 -28248 -22144 -13078 -10542 -7302 -10897 -19023 -8798 -8886 -6273 -2186 -1568 1675 -559 5176 1510 6142 1261 1987 -1448 540 4740 3614 4232 3705 3571 2792 3329 2558 2832 3180 1637 1540 2135 2550 3010 2899 1546 198 -174 -80 1632 835 886 870 690 -29 -1318 -2130 -2439 -1478 -1649 -941 -1414 -1816 -1457 -561 -109 89 964 904 654 464 -63 -596 -692 -156 -242 409 617 -108 -492 -784 -1349 -1280 -590 -1038 -616 -554 -238 281 312 749 369 202 -74 -141 -225 -156 -72 -251 9 -221 36 457 431 722 -19 505 771 314 470 207 212 -190 16 -118 -119 249 202 174 101 39 -205 -269 -520 -402 900000 -2551 -1575 -1224 -1752 -306 -2494 -2417 -1774 -1153 -1524 -943 -1201 -792 -582 -237 125 -788 -571 -1065 -907 -775 -532 -1180 -700 -980 -1095 -907 -591 -549 -427 -689 -1234 -530 -611 -507 -211 -180 208 -76 697 215 849 188 301 -236 91 826 720 851 821 867 723 896 716 782 850 441 436 671 913 1204 1193 623 81 -68 -36 821 463 509 490 365 -14 -580 -896 -1062 -730 -972 -592 -1020 -1328 -1123 -462 -96 81 837 784 581 383 -49 -453 -550 -140 -235 429 741 -131 -590 -935 -1457 -1355 -642 -1155 -717 -683 -296 383 451 1127 584 318 -112 -212 -326 -231 -106 -393 14 -354 55 681 651 1045 -27 685 1106 487 775 356 387 -366 32 -238 -251 534 423 379 210 80 -399 -510 -1034 -838 900000 SS 20260326T122649.1Z 9581.518624 83 1 53.59 2 78.53 89.63 143.87 359.48 0.00 1 0.00 1 0 33 1.013e-01 6.379e-03 6.387e-03 6.100e-04 4.970505e-01 3.014366e-04 6.728765e-03 -6.000000e+00 5.689528e-02 227.07 -2.00 3.06 -2.00 319.05 0.00e+00 1.036909e-03 8.122943e-05 6.487866e-03 -6.000000e+00 2.608018e-03 288.07 -2.00 20.00 -2.00 318.25 0.00e+00 4.864 0.000 302.00 328.00 3 6.1706e-01 8.5017e-04 4.9296e-02 -6.0000e+00 1.4088e-01 4.2756e-03 1.0046e-03 3.1453e-02 -6.0000e+00 1.5321e-01 -2.9932e-02 7.3954e-04 1.8784e-02 -6.0000e+00 9.1628e-02 7.7305e-03 3.8045e-04 7.1048e-03 -6.0000e+00 3.9434e-02 2.7141e-03 3.5614e-02 1.5927e-05 9.9219e-05 -6.0000e+00 2.6748e-03 1.7819e-01 10 0 0 10 0 0 84.70 24.63 0.28 0.17819 0.44581 464 49 1 5 0 115.480 32.50 20.01 24.63 24.26 4.4 877.72 -47924 -48235 -45853 -41412 -26537 -35310 -34354 -24034 -28053 -17051 -10589 -10000 -7875 -4351 -3663 -1258 -2403 -2176 -5576 -5019 -1986 -3234 -4199 -4237 -5208 -5730 -4475 -2880 -575 -430 -2042 -4205 -4433 -3120 -1873 -173 275 608 775 660 1465 1021 616 872 61 408 1080 1534 1150 1698 1639 1069 1376 1026 875 455 544 1140 1456 2367 2249 995 346 -365 -536 342 640 669 524 235 455 61 -503 -1288 -1547 -1046 -1234 -1095 -1462 -1987 -1422 -914 -548 -154 452 798 719 548 215 -37 22 58 -3 507 530 76 -420 -568 -1045 -994 -314 -803 -662 -719 -379 143 488 653 347 245 -55 -322 -131 -172 -43 -72 -114 -196 46 353 324 568 232 449 849 569 476 270 162 -203 65 37 -37 217 302 138 -69 -47 -290 -277 -554 -450 900000 -1286 -1185 -1121 -1074 -679 -1115 -1146 -743 -1023 -687 -491 -560 -496 -289 -263 -94 -191 -176 -467 -447 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