File name: Pandora86s1_SantaCruz_20250226_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260426T104016.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v1d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20250226_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20250226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250226T120723.8Z 9188.505136 21 1 31.12 2 63.27 90.73 44.21 98.74 0.00 1 0.00 1 0 17 1.857e-01 6.689e-02 9.786e-02 2.134e-02 2.583770e-01 1.040702e-02 3.459114e-03 -6.000000e+00 1.030542e-01 225.84 -2.00 3.04 -2.00 317.95 0.00e+00 4.051468e-03 1.837245e-03 1.557590e-03 -6.000000e+00 4.749734e-03 291.74 -2.00 20.00 -2.00 317.03 0.00e+00 2.211 0.000 302.00 328.00 3 7.4475e+00 2.7842e-02 2.4192e-02 -6.0000e+00 2.5433e-01 2.0926e-01 3.1715e-02 1.2141e-02 -6.0000e+00 2.7584e-01 -1.0383e-01 1.9562e-02 6.9774e-03 -6.0000e+00 1.6544e-01 2.7488e-02 1.0149e-02 3.3090e-03 -6.0000e+00 7.2163e-02 2.5999e-05 2.6898e-03 5.7597e-04 3.2155e-05 -6.0000e+00 4.6101e-03 -1.1111e-02 0.0000e+00 12 9 8 11 8 0 96.41 26.00 0.88 -0.01111 0.00910 8 8 1 5 0 3889.110 34.25 20.00 26.00 30.82 4.3 1008.86 59084 31835 99453 625 4209 42546 19777 15845 25570 94709 -5311 33850 -425 -10241 26726 27784 30225 25506 1528 19482 20720 16358 19400 28510 -28 478 20503 10934 4477 22178 29917 22546 32500 19584 -4409 12 -833 -88433 3472 14412 4126 5257 9587 12891 14762 1801 7859 6445 79 2675 9852 1638 13128 3489 9118 2343 3828 659 5990 -1516 7795 13318 5062 3382 2827 3379 2723 -1772 4546 2990 1469 507 -755 3840 141 -2702 -7220 -7916 -1234 4775 -5951 -2607 -1788 -1301 2348 70 86 1898 464 -301 -777 557 -4481 -4475 -2719 4332 2871 2090 -26 1486 -1046 -5690 -3356 -2164 -944 -1062 424 -1152 2685 3244 3954 195 739 -253 654 -5071 -2758 -160 -184 1148 -1217 1269 1866 335 -1002 -5064 -1485 1523 -1443 -476 -1088 400 -402 1422 2360 1741 -1313 1899 -437 168 -1047 195 -424 3689 2926 4830 78 438 2730 1612 1457 2350 4599 -682 2877 -57 -1758 3662 4241 5147 4681 370 4055 4352 3498 3964 5502 -7 129 4578 2545 1025 4112 5434 4778 6764 4928 -1310 3 -235 -68101 1268 5563 1944 2546 4590 6073 6787 947 3837 3097 39 1280 4567 886 6657 2046 5210 1441 2354 416 3491 -938 4484 7761 3496 2566 2204 2411 1777 -1153 2856 2178 1207 440 -667 3124 112 -1968 -4904 -5535 -822 3389 -4830 -2269 -1661 -1243 2301 76 98 2205 552 -351 -841 595 -4551 -4275 -2665 4382 3275 2684 -34 2066 -1398 -7295 -3863 -2491 -1183 -1412 578 -1674 3923 5023 6476 309 1237 -399 929 -7050 -3697 -217 -268 1778 -1991 1993 2847 498 -1425 -7166 -1904 1861 -1952 -686 -1669 622 -638 2279 3988 3134 -2494 3573 -856 318 -1928 342 -722 SS 20250226T121507.0Z 9188.510497 27 1 29.35 2 61.44 90.15 42.44 98.41 0.00 1 0.00 1 0 17 3.729e-02 1.515e-02 3.547e-02 1.020e-02 2.358622e-01 4.991465e-03 2.655943e-03 -6.000000e+00 2.070940e-02 225.84 -2.00 3.04 -2.00 317.71 0.00e+00 2.571743e-04 8.315625e-04 8.867896e-04 -6.000000e+00 9.573411e-04 291.74 -2.00 20.00 -2.00 316.83 0.00e+00 2.081 0.000 302.00 328.00 3 6.7775e+00 1.3265e-02 2.2426e-02 -6.0000e+00 5.1103e-02 4.9197e-02 1.5078e-02 1.1423e-02 -6.0000e+00 5.5436e-02 7.3585e-03 9.2716e-03 5.1226e-03 -6.0000e+00 3.3239e-02 -2.3091e-03 4.7636e-03 1.6334e-03 -6.0000e+00 1.4642e-02 6.2823e-05 5.6366e-05 2.7886e-04 1.6232e-05 -6.0000e+00 9.4811e-04 -1.6132e-02 0.0000e+00 12 8 8 10 0 0 99.99 26.11 0.42 -0.01613 -0.01571 16 16 1 5 0 1833.970 34.50 20.00 26.11 31.05 4.3 1011.08 900000 624 -11478 -8298 -1421 -9154 -13086 -12729 1591 -5480 -4674 -133 2857 17915 -1481 -1998 1051 1479 -45 4166 2737 -538 -6751 9996 -265 -5585 3601 -3925 4085 -6718 -3021 8410 -1815 616 -1318 -6593 60 900000 -6955 -2296 2270 -4451 3338 3267 3612 226 362 1349 -4340 -4180 650 6654 1429 2522 -1512 1012 249 1524 -945 -185 2059 3955 872 3082 2277 894 -1697 -2762 1975 -419 761 1581 2144 713 -1060 160 -2046 -6504 -1615 -1920 -962 -3513 -2287 -692 394 1428 -347 299 1858 1150 746 -415 -3767 -2774 -304 -2226 -1723 -226 546 525 -297 -1543 -1363 -2362 -1159 -1156 10 116 -81 1256 1657 1412 479 1121 965 -1116 173 -1090 878 -244 376 1736 1554 126 746 1561 -1906 -240 -383 49 -592 36 -941 -1944 376 708 564 49 829 499 426 -1123 -1480 900000 64 -1401 -960 -135 -844 -1278 -1369 168 -679 -575 -15 341 2105 -241 -369 199 285 -9 840 579 -117 -1544 2033 -63 -1469 886 -997 875 -1512 -742 1982 -511 183 -380 -1836 16 900000 -2780 -957 1018 -2246 1608 1607 1932 125 198 707 -2343 -2207 337 3501 838 1543 -1004 665 168 1027 -639 -122 1339 2675 662 2473 1909 709 -1247 -1942 1338 -329 666 1454 1995 656 -941 127 -1473 -4496 -1054 -1399 -787 -3277 -2290 -708 423 1641 -392 349 2175 1464 889 -456 -3870 -2612 -285 -2342 -1998 -288 754 731 -393 -1909 -1544 -2685 -1431 -1529 13 165 -121 1774 2485 2188 730 1746 1375 -1488 222 -1459 1230 -375 599 2710 2378 189 1048 2077 -2474 -295 -501 68 -882 55 -1471 -3138 627 1254 1032 84 1434 850 768 -1985 -2526 SS 20250226T122801.3Z 9188.519459 36 1 30.33 2 58.37 89.15 39.47 97.88 0.00 1 0.00 1 0 25 2.424e-02 1.197e-02 1.098e-02 4.153e-03 2.214424e-01 2.046640e-03 2.376319e-03 -6.000000e+00 1.345513e-02 225.84 -2.00 3.04 -2.00 317.06 0.00e+00 -2.942135e-04 2.855667e-04 2.633408e-04 -6.000000e+00 6.216557e-04 291.74 -2.00 20.00 -2.00 316.19 0.00e+00 1.899 0.000 302.00 328.00 3 5.8295e+00 5.3564e-03 2.0471e-02 -6.0000e+00 3.3207e-02 3.6580e-02 6.0426e-03 1.0010e-02 -6.0000e+00 3.6030e-02 9.7521e-04 3.5862e-03 4.8545e-03 -6.0000e+00 2.1599e-02 -6.6832e-03 1.7845e-03 1.4835e-03 -6.0000e+00 9.4831e-03 2.0034e-04 -2.4637e-04 1.1146e-04 1.5589e-05 -6.0000e+00 6.0712e-04 -1.2051e-02 0.0000e+00 12 8 8 10 0 0 99.99 26.22 0.54 -0.01205 -0.01390 28 28 1 5 0 1083.130 34.50 20.01 26.22 31.56 4.3 1014.95 900000 4195 -494 -382 -963 -5553 -952 -3185 583 -1899 -2957 1072 -2255 -5225 2284 -3159 1927 4185 1083 4988 4178 3956 2362 2839 -41 1427 1935 -685 -311 705 1087 803 3526 -2370 -3145 -2296 -2158 -21120 -851 386 398 713 15 112 338 -601 326 -1201 -662 -18 727 -598 642 1389 1298 844 1536 66 586 -60 793 738 2715 2832 898 249 632 -797 727 741 23 1127 276 608 -29 -342 -372 -1955 -2804 -1507 -1042 -715 -1828 -2143 -1195 -353 556 990 869 996 293 502 -891 -1462 -713 147 494 1396 27 -104 -5 -1163 -1362 -797 -1125 -1019 -231 -975 411 1562 1102 640 196 926 -44 -639 138 -644 -88 -98 -474 234 274 436 387 -290 -608 278 477 -96 252 -179 -539 -191 79 500 -9 719 311 -35 -360 -259 -745 900000 591 -76 -57 -128 -693 -116 -439 88 -320 -503 169 -395 -1073 493 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