File name: Pandora86s1_SantaCruz_20250227_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260426T104019.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v1d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20250227_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20250227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250227T123745.6Z 9189.526222 118 1 31.80 2 56.11 87.92 50.35 91.74 0.00 1 0.00 1 0 25 1.222e-01 7.125e-02 4.403e-02 1.427e-02 2.269267e-01 6.977323e-03 2.988109e-03 -6.000000e+00 6.781832e-02 225.86 -2.00 3.04 -2.00 317.39 0.00e+00 3.745539e-03 1.094344e-03 9.419229e-04 -6.000000e+00 3.133052e-03 291.74 -2.00 20.00 -2.00 316.50 0.00e+00 1.788 0.000 302.00 328.00 3 7.4527e+00 1.8385e-02 1.9978e-02 -6.0000e+00 1.6738e-01 1.8438e-01 2.0884e-02 1.0809e-02 -6.0000e+00 1.8161e-01 -5.6755e-02 1.2572e-02 5.9862e-03 -6.0000e+00 1.0887e-01 -2.7768e-03 6.3470e-03 3.5558e-03 -6.0000e+00 4.7796e-02 4.0701e-05 3.6386e-03 3.8226e-04 2.9344e-05 -6.0000e+00 3.0599e-03 -1.2063e-02 0.0000e+00 12 8 8 10 0 0 97.33 25.44 0.70 -0.01206 0.01528 8 8 1 5 0 3974.790 34.00 20.00 25.44 27.60 4.2 985.76 900000 35614 21757 23680 12015 13548 1371 54583 8586 7730 16160 7735 593 2638 15786 4325 26437 24661 16446 27584 5428 14865 15260 13695 7904 14725 12626 9209 10719 13019 8838 7980 15709 18402 -525 3639 8948 -87514 14605 12076 4273 11599 3129 6894 5380 3356 10312 7207 5686 -1081 2982 5351 8484 4790 3507 1073 4412 2919 -2387 -1044 6081 3056 5460 6856 3582 -613 3002 901 7521 1962 2109 4365 1585 -36 1486 -2928 -1623 -1610 -706 -429 -670 2817 -2928 -2007 -69 808 2363 909 4237 1698 -3758 515 -5068 -2326 -3982 1483 2979 815 2459 -2272 -2583 -3379 -4231 -1450 266 -991 1385 705 1627 1017 2957 2670 -473 -1386 -1251 -3433 -3940 -1061 1733 1387 14 -1128 683 -1159 -3470 -1933 -2447 -682 936 348 1159 -354 -537 2232 1182 596 403 3733 1170 -1264 -1161 -912 -450 900000 3716 2699 2995 1474 1491 173 4418 1216 1163 2166 1105 101 511 3075 1056 5383 5240 3931 6070 1524 3704 3744 3534 2229 3986 3513 2504 2644 3030 2258 2210 4351 5237 -167 1031 2569 -75155 5375 5361 2248 5883 1781 3836 3021 1931 5438 3792 2948 -588 1618 3039 4893 3005 2289 720 2908 1942 -1631 -695 3853 2137 4053 5393 2949 -481 2264 659 5305 1519 1803 3815 1429 -31 1334 -2456 -1197 -1100 -486 -333 -586 2626 -3096 -2169 -78 887 2693 1088 4952 1973 -4680 558 -5224 -2191 -3977 1548 3390 1056 3376 -3230 -3446 -4166 -4856 -1650 328 -1310 1860 997 2377 1587 4798 4015 -776 -2129 -1743 -4519 -5152 -1403 2392 2074 21 -1760 1024 -1696 -4896 -2565 -3061 -825 1195 478 1664 -530 -812 3375 1924 1033 715 6571 2145 -2314 -2046 -1546 -735 SS 20250227T125526.9Z 9189.538505 128 1 28.31 2 51.90 86.41 46.25 90.40 0.00 1 0.00 1 0 17 2.616e-02 1.480e-02 7.219e-03 3.415e-03 1.919533e-01 1.679105e-03 2.115501e-03 -6.000000e+00 1.451614e-02 225.86 -2.00 3.04 -2.00 316.30 0.00e+00 8.240149e-04 1.977394e-04 2.680445e-04 -6.000000e+00 6.690622e-04 291.74 -2.00 20.00 -2.00 315.47 0.00e+00 1.617 0.000 302.00 328.00 3 5.8828e+00 4.3487e-03 1.7497e-02 -6.0000e+00 3.5827e-02 2.8609e-02 4.8766e-03 8.5726e-03 -6.0000e+00 3.8857e-02 3.0894e-03 2.8258e-03 4.2173e-03 -6.0000e+00 2.3305e-02 -7.8604e-03 1.3627e-03 1.2013e-03 -6.0000e+00 1.0164e-02 2.5857e-04 2.6109e-05 9.0639e-05 1.3681e-05 -6.0000e+00 6.4940e-04 -1.0387e-02 0.0000e+00 12 8 8 10 0 0 99.96 25.47 0.36 -0.01039 -0.01019 8 8 1 5 0 3538.240 34.00 20.00 25.47 28.30 4.3 991.73 325 4727 1898 -1359 -1831 -3521 -690 -1647 3327 -1205 -1334 -1740 -807 -1682 883 1115 1912 2927 1061 1919 2531 -728 1792 -403 -80 2559 56 -649 -2310 2342 493 2886 2669 984 -3322 -2662 -2215 -26160 -1080 874 456 203 1350 -316 1126 -105 258 -211 -302 -434 390 231 1521 819 944 934 2385 374 283 314 760 2308 2304 2253 1655 -361 484 -1143 252 460 514 1335 323 958 331 -868 -1402 -2775 -1783 -1620 -1933 -1043 -1046 -1773 -557 -313 586 355 551 690 -129 -391 -844 -928 -797 -233 -206 873 935 178 -504 -1112 -1422 -47 -1239 -1280 -732 -716 621 986 1294 1088 725 522 -119 -1107 -234 -933 282 765 336 21 1235 247 244 -498 -259 268 180 62 -164 -243 -200 -437 145 245 -485 312 880 -163 189 -629 -668 60 929 399 -286 -338 -593 -115 -304 658 -270 -296 -373 -184 -438 253 355 631 971 371 684 926 -272 645 -155 -32 1040 24 -265 -873 795 174 1058 1048 420 -1400 -1020 -890 -13804 -582 501 293 137 926 -224 781 -74 178 -140 -195 -273 249 158 1082 616 735 735 1885 303 225 246 599 1901 2058 1982 1504 -338 402 -910 199 411 473 1288 320 919 331 -794 -1144 -2099 -1319 -1328 -1793 -1060 -1054 -1862 -613 -372 734 465 731 896 -158 -434 -925 -940 -822 -240 -234 1087 1267 244 -655 -1342 -1588 -52 -1524 -1687 -997 -1021 838 1399 1940 1673 1085 728 -164 -1416 -290 -1201 383 1126 481 30 1708 361 335 -658 -322 320 227 84 -234 -358 -295 -662 214 383 -787 514 1475 -271 303 -984 -1009 SS 20250227T130018.9Z 9189.541885 131 1 27.80 2 50.75 85.98 45.12 90.02 0.00 1 0.00 1 0 25 7.638e-02 5.861e-02 1.205e-02 5.527e-03 1.862385e-01 2.702483e-03 2.435860e-03 -6.000000e+00 4.211493e-02 225.86 -2.00 3.04 -2.00 316.43 0.00e+00 1.255245e-03 3.286365e-04 5.321439e-04 -6.000000e+00 1.949868e-03 291.74 -2.00 20.00 -2.00 315.58 0.00e+00 1.577 0.000 302.00 328.00 3 6.4903e+00 7.0078e-03 1.7361e-02 -6.0000e+00 1.0392e-01 6.8446e-02 7.8719e-03 9.1404e-03 -6.0000e+00 1.1300e-01 -9.0867e-03 4.5713e-03 4.4463e-03 -6.0000e+00 6.7760e-02 -1.4157e-02 2.2144e-03 1.3804e-03 -6.0000e+00 2.9313e-02 1.4613e-04 -3.3179e-03 1.4668e-04 2.0119e-05 -6.0000e+00 1.8989e-03 3.7960e-02 0.0000e+00 12 9 9 12 9 1 100.00 25.48 0.54 0.03796 0.01303 6 8 1 5 0 3969.910 34.00 20.00 25.48 28.57 4.3 993.70 22138 5916 10925 10876 -2047 8421 9457 10018 7991 4702 582 105 4561 1794 7018 12167 5042 4593 7478 7831 10270 3022 6105 7806 6792 2960 3914 2085 844 2950 989 6097 6571 4076 -403 1051 2067 -74408 5702 5161 4495 2294 1860 4276 4304 3191 1187 856 1610 1678 4260 2978 3565 3777 3689 3587 1901 2764 893 681 1041 3308 4619 5755 3442 122 -487 -2224 3244 3747 3085 2135 1328 1133 -598 -1561 -2069 -4337 260 945 -498 441 -1690 -1481 1420 1011 1955 659 1259 151 -879 -942 -2851 -980 -136 -220 2248 2619 937 -1076 -2517 -2899 -2856 -39 283 -1258 100 -479 724 1489 1399 257 -168 -880 -2616 -2778 -838 -751 1250 501 -677 -666 354 -1624 -830 -1796 -1974 213 1588 1130 1461 -405 -237 156 724 1318 868 704 1092 -24 17 -568 -858 3508 1218 2202 2087 -386 1307 1494 1739 1585 1026 129 23 1028 471 1975 3594 1650 1535 2507 2693 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