File name: Pandora86s1_SantaCruz_20250306_L2Fit_fwvt1c2d20240531p1-8.txt File generation date: 20260426T104150.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v1d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20250306_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20250306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1617 1767 Nominal wavelengths inside fitting window [nm]: 492.0187 492.1398 492.2608 492.3818 492.5028 492.6238 492.7448 492.8657 492.9866 493.1075 493.2284 493.3493 493.4702 493.5910 493.7119 493.8327 493.9535 494.0743 494.1951 494.3158 494.4365 494.5573 494.6780 494.7987 494.9193 495.0400 495.1606 495.2812 495.4019 495.5224 495.6430 495.7636 495.8841 496.0046 496.1252 496.2456 496.3661 496.4866 496.6070 496.7274 496.8479 496.9683 497.0886 497.2090 497.3293 497.4497 497.5700 497.6903 497.8106 497.9308 498.0511 498.1713 498.2915 498.4117 498.5319 498.6521 498.7722 498.8924 499.0125 499.1326 499.2527 499.3727 499.4928 499.6128 499.7328 499.8528 499.9728 500.0928 500.2127 500.3327 500.4526 500.5725 500.6924 500.8123 500.9321 501.0520 501.1718 501.2916 501.4114 501.5312 501.6509 501.7707 501.8904 502.0101 502.1298 502.2495 502.3691 502.4888 502.6084 502.7280 502.8476 502.9672 503.0867 503.2063 503.3258 503.4453 503.5648 503.6843 503.8038 503.9232 504.0427 504.1621 504.2815 504.4008 504.5202 504.6396 504.7589 504.8782 504.9975 505.1168 505.2361 505.3553 505.4746 505.5938 505.7130 505.8322 505.9513 506.0705 506.1896 506.3087 506.4278 506.5469 506.6660 506.7851 506.9041 507.0231 507.1421 507.2611 507.3801 507.4991 507.6180 507.7369 507.8558 507.9747 508.0936 508.2125 508.3313 508.4501 508.5689 508.6877 508.8065 508.9253 509.0440 509.1627 509.2814 509.4001 509.5188 509.6375 509.7561 509.8748 509.9934 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250306T102133.9Z 9196.431642 30 1 31.42 2 88.91 95.41 169.10 28.70 0.00 1 0.00 1 0 22 7.107e-03 6.850e-03 1.918e-03 1.904e-03 4.393088e+04 1.618256e+02 2.747823e+03 -6.000000e+00 3.875794e+02 291.71 -2.00 20.00 -2.00 505.45 0.00e+00 2.219881e-03 5.272455e-05 1.765856e-04 -6.000000e+00 1.999467e-04 291.71 -2.00 20.00 -2.00 500.59 0.00e+00 2.221738e+00 3.656774e-02 1.906578e-01 -6.000000e+00 1.357874e-01 226.00 -2.00 3.04 -2.00 502.15 0.00e+00 18.326 0.016 489.00 513.00 1 5.8147e+00 2.7969e-03 3.0325e-02 -6.0000e+00 1.0431e-02 -2.4107e-02 6.9954e-04 5.4686e-03 -6.0000e+00 2.7212e-03 3.7321e-04 2.3667e-03 1.1353e-04 1.9059e-04 -6.0000e+00 5.8670e-04 7.7999e-03 -1.8149e-04 12 8 8 10 0 0 73.46 26.17 2.04 0.00780 0.02422 8 8 1 4 0 3927.290 34.50 20.00 26.17 29.34 4.4 999.72 -414 -369 318 764 1091 1065 1459 1517 1254 649 703 543 -444 12 -598 -496 -512 -134 540 513 196 -88 28 84 527 430 654 375 -306 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-942 -1305 -1637 -1677 -1341 -1034 275 281 -317 -64 -437 -541 -584 -462 -665 -522 321 1303 1543 425 424 -649 -1173 -480 315 862 1539 1531 342 545 -114 -913 -364 -325 -861 -477 -8 -325 -180 945 155 116 386 238 454 935 960 701 392 285 -260 -477 SQ 20250306T102434.4Z 9196.433732 34 1 30.08 2 88.20 95.18 168.76 31.46 0.00 1 0.00 1 0 22 6.123e-03 5.963e-03 3.604e-04 3.588e-04 4.255195e+04 2.975571e+01 2.644329e+03 -6.000000e+00 3.338663e+02 291.71 -2.00 20.00 -2.00 505.42 0.00e+00 2.180805e-03 9.967447e-06 1.796104e-04 -6.000000e+00 1.722467e-04 291.71 -2.00 20.00 -2.00 500.59 0.00e+00 2.006104e+00 6.887800e-03 1.870393e-01 -6.000000e+00 1.169032e-01 226.00 -2.00 3.04 -2.00 502.16 0.00e+00 16.505 0.011 489.00 513.00 1 3.0209e+00 5.2760e-04 2.8123e-02 -6.0000e+00 8.9812e-03 -2.6877e-02 1.3195e-04 5.2515e-03 -6.0000e+00 2.3413e-03 7.9530e-03 1.4748e-03 2.1420e-05 2.0112e-04 -6.0000e+00 5.0533e-04 -5.3210e-03 -5.5295e-05 12 8 8 10 0 0 99.89 26.17 1.94 -0.00532 0.00491 125 125 1 4 0 240.620 34.50 20.00 26.17 29.42 4.3 999.71 -513 -312 292 689 920 1200 1261 1373 1214 861 750 478 32 -194 -334 -311 -194 84 231 135 258 110 -38 256 362 461 541 468 -245 -635 -898 -1014 -859 -125 -71 -46 -120 -397 -656 -749 -559 -481 -130 49 257 354 286 148 47 -512 -823 -1106 -1283 -1054 -643 -323 -107 58 91 -36 69 229 241 309 180 29 -126 -177 -389 -693 -644 -626 -455 -42 -73 -120 -198 -236 -209 -303 63 396 176 180 175 -99 -273 -389 -310 211 349 978 1241 895 840 673 446 639 -224 -1139 -1323 -1595 -1668 -1255 -923 -6 269 -80 -167 -131 -347 -627 -536 -373 -277 423 919 1084 374 1 -541 -1082 -507 344 520 951 1329 661 382 301 -633 -672 -230 -574 -451 244 -243 -4 560 432 250 373 336 643 867 921 660 104 -200 -295 -108 -472 -290 279 672 906 1179 1268 1404 1224 862 755 478 32 -189 -331 -303 -191 84 236 138 264 113 -39 263 377 483 565 487 -253 -642 -885 -1003 -861 -127 -74 -49 -126 -413 -677 -766 -582 -495 -135 52 269 373 302 154 49 -530 -843 -1101 -1283 -1052 -644 -329 -112 60 95 -37 71 238 254 325 188 30 -130 -181 -394 -695 -649 -631 -453 -42 -74 -123 -198 -234 -204 -296 60 381 172 178 172 -98 -271 -388 -302 205 338 955 1198 870 789 613 387 538 -188 -955 -1105 -1369 -1459 -1147 -879 -6 267 -79 -163 -128 -347 -624 -539 -369 -271 410 911 1102 387 1 -547 -1076 -494 336 504 928 1307 647 374 295 -625 -660 -221 -559 -444 239 -243 -4 570 444 259 394 359 683 912 960 684 107 -209 -303 -111 SQ 20250306T103034.2Z 9196.437895 43 1 29.34 2 86.78 94.73 168.00 36.43 0.00 1 0.00 1 0 22 4.585e-03 4.469e-03 1.066e-03 1.062e-03 2.785564e+04 8.239600e+01 1.779308e+03 -6.000000e+00 2.500372e+02 291.71 -2.00 20.00 -2.00 505.37 0.00e+00 1.391982e-03 2.939168e-05 1.169989e-04 -6.000000e+00 1.289922e-04 291.71 -2.00 20.00 -2.00 500.49 0.00e+00 1.465605e+00 2.039625e-02 1.325884e-01 -6.000000e+00 8.758002e-02 226.00 -2.00 3.04 -2.00 502.08 0.00e+00 12.995 0.006 489.00 513.00 1 5.6068e+00 1.5641e-03 2.1294e-02 -6.0000e+00 6.7279e-03 -2.7127e-03 3.9412e-04 3.6422e-03 -6.0000e+00 1.7547e-03 1.0380e-03 1.9472e-03 7.1894e-05 1.5079e-04 -6.0000e+00 3.7848e-04 -7.0292e-04 -1.1297e-04 11 8 0 10 0 0 83.83 26.17 1.50 -0.00070 0.01280 11 11 1 4 0 2667.100 34.50 20.00 26.17 29.52 4.3 999.86 -965 -672 -122 133 392 766 746 936 893 418 621 185 -215 -342 -604 -465 -305 64 139 225 358 149 -174 230 388 196 440 525 -293 -464 -606 -469 -506 86 140 -24 232 -37 -412 -368 -178 -34 -156 131 307 707 404 293 227 -103 -532 -764 -890 -792 -329 -257 62 -14 -20 -33 180 244 256 142 241 26 -23 84 -397 -529 -543 -520 -129 3 99 -376 -302 -180 -273 -409 -155 -252 -374 145 -32 -143 -331 -280 -174 307 312 591 887 613 954 823 224 331 -489 -1098 -1157 -1229 -894 -453 -632 3 -75 -235 -263 -285 -240 -234 -171 -49 258 470 740 1108 516 273 58 -642 -113 502 379 567 537 163 405 278 -527 -295 176 -545 -365 29 -198 -44 605 403 100 247 200 434 528 323 231 -268 -283 -549 -512 -897 -628 -117 129 391 778 775 954 914 426 642 190 -218 -342 -601 -463 -307 66 142 236 375 157 -184 243 412 202 468 557 -308 -467 -614 -475 -502 88 145 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