File name: Pandora86s1_SantaCruz_20250315_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260426T104156.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v1d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20250315_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20250315 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250315T112401.2Z 9205.475014 265 1 31.45 2 74.57 87.04 93.43 264.79 0.00 1 0.00 1 0 97 1.045e+00 1.472e-01 1.856e-01 1.551e-02 3.088240e-01 7.629048e-03 4.547214e-03 -6.000000e+00 5.767261e-01 226.19 -2.00 3.04 -2.00 319.40 0.00e+00 -8.091287e-02 2.205294e-03 3.368098e-03 -6.000000e+00 2.710044e-02 291.68 -2.00 20.00 -2.00 318.36 0.00e+00 3.689 0.000 302.00 328.00 3 6.4011e+00 2.2198e-02 8.0159e-02 -6.0000e+00 1.4279e+00 -2.5092e-01 2.7022e-02 1.2723e-01 -6.0000e+00 1.5561e+00 -5.5819e-01 1.9516e-02 6.0498e-02 -6.0000e+00 9.2845e-01 3.6189e-01 1.0109e-02 8.9904e-02 -6.0000e+00 4.0163e-01 3.2935e-05 -1.1474e-03 4.0865e-04 6.8846e-04 -6.0000e+00 2.6299e-02 2.0283e-01 0.0000e+00 12 8 8 10 0 0 99.97 26.06 0.90 0.20283 0.19421 8 8 1 5 0 3930.950 34.25 20.00 26.06 31.49 4.2 1012.10 230951 200452 185047 183235 184847 250666 266510 900000 316927 384558 288599 220808 300398 203785 157631 151911 142130 137384 94105 143945 126606 134507 178816 259004 243147 269884 180660 153854 113708 149822 100942 84353 74337 41563 31767 72599 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8075 10984 9163 8481 2897 2754 -2326 -2019 -4759 -216 1799 4295 2365 773 -2957 4074 4563 6104 7129 708 -9093 -11174 -11550 -8135 -6697 8142 10677 4546 6065 -2441 -17639 -31616 -27658 -24057 -1181 13031 11135 8987 10089 6722 14810 10985 4863 -3903 -14667 -19597 -17050 -5192 975 9315 14155 1366 -2372 -2642 -4291 -3246 -375 -3908 4844 17008 18548 12721 3815 2274 5608 12422 12887 4628 6525 2885 -9475 -15636 -13651 -10668 900000 SS 20250315T113328.6Z 9205.481581 268 1 30.02 2 72.32 86.27 95.60 264.04 0.00 1 0.00 1 0 17 1.885e-02 7.432e-03 1.644e-03 4.198e-04 3.433818e-01 2.074034e-04 3.561272e-03 -6.000000e+00 1.047977e-02 226.19 -2.00 3.04 -2.00 317.68 0.00e+00 7.770913e-04 3.439912e-05 3.675143e-04 -6.000000e+00 4.832924e-04 291.68 -2.00 20.00 -2.00 316.79 0.00e+00 3.247 0.000 302.00 328.00 3 5.2544e-01 5.5071e-04 3.4186e-02 -6.0000e+00 2.5886e-02 -1.2703e-03 6.2445e-04 1.5302e-02 -6.0000e+00 2.8077e-02 -1.2317e-02 3.8794e-04 7.4635e-03 -6.0000e+00 1.6826e-02 1.8926e-03 2.0125e-04 2.1144e-03 -6.0000e+00 7.3835e-03 9.8776e-03 -1.1659e-04 1.1101e-05 2.0812e-05 -6.0000e+00 4.7217e-04 -1.3866e-02 0.0000e+00 11 9 0 11 8 0 86.19 26.07 0.32 -0.01387 -0.01474 500 500 1 5 0 60.020 34.25 20.01 26.07 31.78 4.2 1015.52 900000 -3180 -1768 -4224 -7305 -7370 -6931 -5791 -3301 -3296 -5914 -6141 -4084 -2313 -118 -39 -389 1178 753 1822 1386 178 815 1283 264 232 20 -946 -2529 -2379 -437 -329 1257 -359 -3429 -4107 -3717 -1555 -833 28 139 -5 619 271 752 883 272 186 -376 -411 765 791 837 1406 995 1114 935 491 322 165 759 1509 1689 2754 1548 -73 -95 -1168 124 615 408 831 364 620 102 -664 -1090 -2484 -1846 -1582 -1733 -1239 -2181 -2004 -1156 -564 127 201 1003 919 518 460 -452 -392 -448 -524 -168 885 565 -111 -428 -925 -1085 -639 -532 -1193 -723 -517 107 543 921 961 763 479 101 -92 110 -137 347 297 109 266 769 400 407 133 -482 302 202 -139 -27 -373 -203 -374 -16 36 -75 567 406 -115 -110 -529 -657 900000 -262 -154 -375 -595 -547 -529 -488 -310 -341 -638 -661 -483 -290 -17 -7 -71 222 151 379 301 39 177 297 61 56 5 -232 -637 -577 -111 -85 355 -113 -1076 -1199 -1142 -537 -319 12 68 -3 310 140 386 456 141 95 -192 -211 407 461 490 874 655 750 611 326 223 112 519 1027 1265 2120 1271 -58 -74 -880 95 505 360 737 330 573 90 -558 -823 -1882 -1412 -1295 -1547 -1175 -2184 -2094 -1215 -638 145 239 1204 1084 600 487 -465 -400 -454 -566 -194 1093 742 -150 -546 -1135 -1266 -733 -642 -1555 -938 -706 147 770 1360 1483 1164 720 146 -129 150 -194 501 445 164 408 1143 578 579 190 -654 412 286 -208 -41 -582 -323 -595 -27 63 -130 998 732 -203 -193 -895 -1105 SS 20250315T113958.7Z 9205.486096 272 1 29.98 2 70.78 85.74 97.08 263.52 0.00 1 0.00 1 0 17 1.564e-02 7.523e-03 1.118e-03 3.520e-04 3.193955e-01 1.741907e-04 3.328117e-03 -6.000000e+00 8.693994e-03 226.19 -2.00 3.04 -2.00 317.29 0.00e+00 7.167135e-04 2.593495e-05 3.123101e-04 -6.000000e+00 4.009047e-04 291.68 -2.00 20.00 -2.00 316.41 0.00e+00 3.002 0.000 302.00 328.00 3 4.4224e-01 4.5886e-04 3.1629e-02 -6.0000e+00 2.1475e-02 -8.3343e-04 5.1802e-04 1.4181e-02 -6.0000e+00 2.3292e-02 -9.5994e-03 3.1367e-04 6.9248e-03 -6.0000e+00 1.3959e-02 6.0182e-04 1.5974e-04 1.9660e-03 -6.0000e+00 6.1258e-03 1.3865e-02 -7.9792e-05 9.2841e-06 1.9278e-05 -6.0000e+00 3.9169e-04 -1.4468e-02 0.0000e+00 11 8 0 10 0 0 45.14 26.11 0.34 -0.01447 -0.01507 584 584 1 5 0 51.320 34.25 20.01 26.11 32.22 4.3 1018.83 900000 -1446 -481 -2844 -5597 -6063 -5552 -3487 -3058 -2375 -4928 -4337 -2532 -1645 -443 500 371 1338 1116 1801 1388 369 1209 1260 816 709 298 -759 -1807 -1621 27 38 1276 -188 -3316 -3566 -3638 -3803 -802 44 -194 -14 402 153 683 619 147 187 -493 -359 689 828 710 1379 851 1134 935 494 399 180 677 1533 1733 2578 1388 -231 27 -1054 202 665 530 811 236 595 126 -562 -1087 -2416 -1706 -1517 -1689 -1345 -2125 -1888 -1116 -536 81 190 968 901 569 403 -461 -432 -504 -431 -212 851 592 -97 -336 -896 -1072 -637 -544 -1239 -713 -477 74 599 944 949 712 541 94 -104 159 -123 389 344 173 253 749 366 405 106 -481 382 203 -168 -22 -385 -221 -390 -52 95 -94 541 426 -138 -156 -531 -612 900000 -146 -51 -308 -609 -602 -564 -387 -386 -297 -641 -555 -354 -268 -84 108 79 296 261 436 351 94 304 337 234 215 93 -232 -517 -444 8 12 404 -66 -1159 -1153 -1243 -1492 -342 21 -106 -7 225 88 390 356 85 106 -278 -201 400 494 453 930 573 779 662 355 281 125 472 1128 1326 2144 1166 -187 21 -796 154 547 471 763 228 555 112 -475 -868 -1921 -1361 -1295 -1497 -1272 -2220 -1965 -1224 -606 93 227 1168 1069 658 446 -493 -434 -526 -479 -252 1039 769 -128 -439 -1125 -1282 -751 -676 -1598 -917 -645 100 873 1429 1446 1071 795 133 -141 209 -168 546 503 264 380 1094 538 564 146 -659 505 279 -244 -33 -582 -340 -618 -84 160 -163 923 745 -237 -266 -872 -999 SS 20250315T114514.5Z 9205.489751 275 1 30.01 2 69.53 85.30 98.28 263.09 0.00 1 0.00 1 0 17 1.424e-02 7.419e-03 9.385e-04 3.366e-04 3.019857e-01 1.666247e-04 3.150176e-03 -6.000000e+00 7.914624e-03 226.19 -2.00 3.04 -2.00 317.02 0.00e+00 6.491765e-04 2.322783e-05 2.489434e-04 -6.000000e+00 3.649621e-04 291.68 -2.00 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