File name: Pandora86s1_SantaCruz_20260228_L2Fit_fwvt1c2d20240531p1-8.txt File generation date: 20260301T043642.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260228_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1617 1767 Nominal wavelengths inside fitting window [nm]: 492.0187 492.1398 492.2608 492.3818 492.5028 492.6238 492.7448 492.8657 492.9866 493.1075 493.2284 493.3493 493.4702 493.5910 493.7119 493.8327 493.9535 494.0743 494.1951 494.3158 494.4365 494.5573 494.6780 494.7987 494.9193 495.0400 495.1606 495.2812 495.4019 495.5224 495.6430 495.7636 495.8841 496.0046 496.1252 496.2456 496.3661 496.4866 496.6070 496.7274 496.8479 496.9683 497.0886 497.2090 497.3293 497.4497 497.5700 497.6903 497.8106 497.9308 498.0511 498.1713 498.2915 498.4117 498.5319 498.6521 498.7722 498.8924 499.0125 499.1326 499.2527 499.3727 499.4928 499.6128 499.7328 499.8528 499.9728 500.0928 500.2127 500.3327 500.4526 500.5725 500.6924 500.8123 500.9321 501.0520 501.1718 501.2916 501.4114 501.5312 501.6509 501.7707 501.8904 502.0101 502.1298 502.2495 502.3691 502.4888 502.6084 502.7280 502.8476 502.9672 503.0867 503.2063 503.3258 503.4453 503.5648 503.6843 503.8038 503.9232 504.0427 504.1621 504.2815 504.4008 504.5202 504.6396 504.7589 504.8782 504.9975 505.1168 505.2361 505.3553 505.4746 505.5938 505.7130 505.8322 505.9513 506.0705 506.1896 506.3087 506.4278 506.5469 506.6660 506.7851 506.9041 507.0231 507.1421 507.2611 507.3801 507.4991 507.6180 507.7369 507.8558 507.9747 508.0936 508.2125 508.3313 508.4501 508.5689 508.6877 508.8065 508.9253 509.0440 509.1627 509.2814 509.4001 509.5188 509.6375 509.7561 509.8748 509.9934 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260228T102035.6Z 9555.430967 128 1 43.78 2 88.72 97.86 130.16 285.62 0.00 1 0.00 1 0 22 7.825e-03 7.616e-03 1.804e-04 1.797e-04 3.976312e+04 1.452191e+01 2.504598e+03 -6.000000e+00 4.266639e+02 291.74 -2.00 20.00 -2.00 505.45 0.00e+00 2.467645e-03 5.001414e-06 1.912462e-04 -6.000000e+00 2.201962e-04 291.74 -2.00 20.00 -2.00 500.81 0.00e+00 1.925459e+00 3.419946e-03 1.795264e-01 -6.000000e+00 1.499288e-01 225.88 -2.00 3.04 -2.00 502.35 0.00e+00 17.863 0.014 489.00 513.00 1 1.8667e+00 2.6181e-04 2.9328e-02 -6.0000e+00 1.1507e-02 -5.2943e-02 6.5820e-05 5.0951e-03 -6.0000e+00 3.0207e-03 2.1175e-02 1.4401e-03 1.1003e-05 2.0562e-04 -6.0000e+00 6.4757e-04 9.0923e-03 -2.4757e-04 12 9 9 12 1 1 74.17 25.80 3.13 0.00909 0.01908 326 39 1 4 0 133.880 34.00 20.00 25.80 29.99 4.8 995.26 900000 -329 326 1039 1336 1654 1802 1900 1746 1254 1085 735 232 -75 -256 -300 -203 125 405 380 323 232 102 299 478 559 597 571 -244 -924 -1296 -1388 -1227 -422 -66 -8 -145 -491 -743 -948 -786 -625 -287 -40 255 368 322 127 -49 -624 -1127 -1487 -1798 -1605 -1101 -492 -156 124 44 28 41 249 326 401 340 53 -95 -196 -480 -819 -823 -800 -628 -223 -72 -99 -314 -477 -544 -570 -293 148 44 -12 50 -96 -234 -422 -433 31 241 788 1316 1167 1109 906 563 485 -333 -1431 -1857 -2077 -2096 -1479 -906 -210 32 -310 -508 -387 -381 -562 -345 -165 -35 554 1176 1366 780 249 -425 -859 -559 355 708 1009 1433 885 534 602 -274 -500 -132 -499 -587 64 -138 56 582 633 363 516 472 737 1090 1119 837 221 -278 -489 -338 900000 -297 298 972 1274 1583 1764 1867 1730 1239 1056 711 227 -72 -244 -288 -197 121 402 381 326 234 103 299 483 569 607 581 -247 -916 -1268 -1360 -1218 -424 -67 -8 -149 -506 -761 -962 -795 -638 -292 -41 263 382 335 132 -51 -638 -1139 -1482 -1764 -1570 -1099 -501 -159 128 46 29 43 259 338 417 353 55 -97 -201 -487 -823 -827 -803 -627 -225 -72 -100 -317 -476 -532 -558 -283 143 43 -12 49 -96 -235 -420 -427 30 236 765 1289 1135 1058 832 499 421 -286 -1235 -1597 -1798 -1861 -1380 -877 -207 32 -312 -505 -385 -382 -572 -349 -165 -35 551 1171 1400 809 260 -441 -873 -555 351 705 1001 1431 886 536 603 -277 -503 -130 -495 -590 64 -141 58 604 664 388 553 506 799 1170 1193 887 234 -295 -520 -359 SQ 20260228T102335.2Z 9555.433046 132 1 54.75 2 88.02 97.64 130.81 285.54 0.00 1 0.00 1 0 22 6.290e-03 6.147e-03 1.114e-04 1.111e-04 3.414270e+04 8.726902e+00 2.169613e+03 -6.000000e+00 3.429465e+02 291.74 -2.00 20.00 -2.00 505.41 0.00e+00 1.950934e-03 3.088198e-06 1.556898e-04 -6.000000e+00 1.770261e-04 291.74 -2.00 20.00 -2.00 500.75 0.00e+00 1.663716e+00 2.115590e-03 1.576363e-01 -6.000000e+00 1.205623e-01 225.88 -2.00 3.04 -2.00 502.30 0.00e+00 16.026 0.010 489.00 513.00 1 1.4195e+00 1.6200e-04 2.6075e-02 -6.0000e+00 9.2527e-03 -3.8007e-02 4.0929e-05 4.4331e-03 -6.0000e+00 2.4298e-03 4.3980e-02 1.7929e-03 7.1135e-06 1.8792e-04 -6.0000e+00 5.2067e-04 1.0127e-02 -2.7303e-04 12 8 8 10 0 0 50.20 25.81 2.37 0.01013 0.02256 790 76 1 4 0 69.290 34.25 20.00 25.81 30.14 4.8 996.00 900000 -464 121 694 912 1243 1392 1454 1322 930 780 511 80 -187 -300 -298 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66 216 694 1121 1008 938 797 434 334 -305 -1093 -1317 -1467 -1464 -995 -741 -178 11 -334 -433 -334 -291 -439 -264 -93 -34 491 1032 1163 686 307 -221 -603 -367 353 523 752 1066 615 386 548 -206 -333 -41 -412 -503 78 -151 33 489 576 302 452 408 573 900 885 654 80 -328 -555 -388 SQ 20260228T102627.0Z 9555.435035 136 1 28.63 2 87.34 97.42 131.44 285.47 0.00 1 0.00 1 0 22 5.480e-03 5.367e-03 1.227e-04 1.224e-04 2.994271e+04 9.431474e+00 1.913971e+03 -6.000000e+00 2.988046e+02 291.74 -2.00 20.00 -2.00 505.39 0.00e+00 1.624639e-03 3.402315e-06 1.340840e-04 -6.000000e+00 1.542303e-04 291.74 -2.00 20.00 -2.00 500.70 0.00e+00 1.467869e+00 2.337515e-03 1.416107e-01 -6.000000e+00 1.050275e-01 225.88 -2.00 3.04 -2.00 502.25 0.00e+00 14.303 0.007 489.00 513.00 1 1.2266e+00 1.7906e-04 2.3275e-02 -6.0000e+00 8.0607e-03 -2.7941e-02 4.5366e-05 3.9341e-03 -6.0000e+00 2.1164e-03 6.9084e-02 1.5817e-03 8.1303e-06 1.6881e-04 -6.0000e+00 4.5360e-04 4.8144e-03 -2.3262e-04 12 8 8 10 0 0 46.64 25.81 1.95 0.00481 0.01579 612 59 1 4 0 46.770 34.25 20.00 25.81 30.26 4.8 996.50 900000 -597 -45 473 679 992 1161 1212 1126 749 653 430 -7 -221 -326 -303 -243 81 287 222 310 151 55 270 386 433 552 550 -174 -697 -863 -976 -851 -118 45 90 -1 -243 -485 -594 -466 -397 -101 114 326 394 357 239 141 -348 -777 -1072 -1332 -1158 -773 -333 -78 133 119 69 77 232 260 342 298 137 8 -73 -308 -632 -595 -561 -478 -122 -46 -137 -306 -382 -511 -610 -420 -143 -227 -141 -27 -108 -99 -250 -241 90 221 673 1037 908 899 778 433 299 -344 -1138 -1385 -1404 -1359 -849 -596 -152 -33 -361 -454 -294 -256 -354 -169 -29 53 495 954 1053 616 287 -147 -455 -260 352 369 575 869 473 323 509 -159 -254 37 -377 -462 89 -122 56 407 496 243 346 351 508 711 651 446 -17 -324 -551 -414 900000 -551 -42 455 666 980 1158 1217 1138 753 655 428 -7 -217 -317 -296 -237 80 288 225 316 155 56 276 394 446 566 563 -177 -699 -851 -962 -849 -118 46 93 -1 -251 -495 -608 -475 -407 -104 118 339 413 374 248 145 -356 -782 -1059 -1310 -1134 -764 -337 -79 137 123 71 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