File name: Pandora86s1_SantaCruz_20260305_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260306T043156.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260305_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260305 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260305T115908.5Z 9560.499404 269 1 17.07 2 65.64 88.52 91.44 263.44 0.00 1 0.00 1 0 17 1.388e-02 7.960e-03 3.798e-03 1.658e-03 2.647130e-01 8.222611e-04 2.769637e-03 -6.000000e+00 7.710911e-03 225.98 -2.00 3.04 -2.00 316.57 0.00e+00 4.405342e-04 1.017544e-04 1.901228e-04 -6.000000e+00 3.558246e-04 291.72 -2.00 20.00 -2.00 315.71 0.00e+00 2.407 0.000 302.00 328.00 3 3.5433e+00 2.1356e-03 2.5518e-02 -6.0000e+00 1.9037e-02 -4.1422e-03 2.3965e-03 1.1689e-02 -6.0000e+00 2.0649e-02 -3.2757e-04 1.4055e-03 5.7153e-03 -6.0000e+00 1.2377e-02 -3.9436e-03 6.8821e-04 1.6184e-03 -6.0000e+00 5.4360e-03 1.1669e-03 6.8439e-05 4.3925e-05 1.6888e-05 -6.0000e+00 3.4758e-04 -1.6113e-02 0.0000e+00 12 9 1 12 1 1 78.37 25.37 0.27 -0.01611 -0.01560 18 6 1 5 0 898.330 33.75 20.00 25.37 27.89 4.7 979.26 900000 -1184 -153 33 -4090 -1959 -2655 -2519 1243 -1801 -4542 -4661 -2951 -515 1889 1965 -1162 738 1852 1804 1819 -367 1515 1735 1711 303 -23 -433 -1850 -1993 -595 -1076 1611 -983 -3441 -4974 -3581 3469 -1278 32 196 133 62 -148 486 302 31 -585 -385 -1000 492 910 878 1170 1012 1112 889 387 511 -130 605 1308 1974 2042 868 48 133 -971 -127 630 188 757 112 596 149 -454 -1062 -2526 -1719 -1352 -2018 -827 -2305 -1668 -744 -502 449 316 913 898 543 508 -532 -498 -394 -571 -550 1004 434 -83 -309 -879 -1071 -666 -362 -1351 -681 -365 -4 398 1071 977 1045 607 282 -137 281 -240 114 97 154 218 438 347 635 298 -341 308 376 -368 45 -424 -224 -568 69 157 -174 451 451 -51 -250 -538 -557 900000 -199 -27 6 -648 -274 -383 -402 218 -356 -927 -931 -632 -114 472 557 -362 233 605 564 590 -121 487 588 617 116 -9 -165 -657 -673 -206 -407 645 -407 -1400 -2033 -1519 1455 -629 18 121 82 40 -97 315 197 20 -371 -254 -654 309 617 633 841 763 852 700 309 400 -100 469 1013 1660 1772 794 42 110 -773 -102 541 174 741 112 579 138 -402 -886 -2083 -1404 -1168 -1899 -817 -2405 -1801 -807 -564 532 375 1097 1104 626 558 -560 -512 -416 -638 -653 1258 554 -108 -396 -1085 -1267 -779 -445 -1728 -901 -486 -5 565 1559 1474 1543 876 388 -182 361 -321 156 139 229 322 631 485 868 407 -442 399 500 -512 64 -628 -336 -845 108 253 -282 740 757 -84 -399 -859 -858 SS 20260305T120759.6Z 9560.505551 274 1 54.65 2 63.53 87.81 93.46 262.75 0.00 1 0.00 1 0 17 2.350e-02 1.097e-02 2.150e-03 1.005e-03 2.456024e-01 4.989798e-04 2.565567e-03 -6.000000e+00 1.305510e-02 225.98 -2.00 3.04 -2.00 316.35 0.00e+00 2.900405e-04 5.915416e-05 1.269870e-04 -6.000000e+00 6.023779e-04 291.72 -2.00 20.00 -2.00 315.52 0.00e+00 2.231 0.000 302.00 328.00 3 3.9155e+00 1.2917e-03 2.3652e-02 -6.0000e+00 3.2232e-02 3.7514e-03 1.4478e-03 1.0842e-02 -6.0000e+00 3.4960e-02 1.8831e-03 8.4381e-04 5.2959e-03 -6.0000e+00 2.0955e-02 -3.1207e-03 4.0881e-04 1.4961e-03 -6.0000e+00 9.2045e-03 9.7106e-04 -5.6339e-06 2.6633e-05 1.5816e-05 -6.0000e+00 5.8840e-04 -1.6958e-02 0.0000e+00 12 9 8 11 8 0 99.91 25.39 0.33 -0.01696 -0.01700 73 7 1 5 0 748.570 33.75 20.00 25.39 28.52 4.8 984.42 900000 -2053 -292 -1370 -2896 -3904 -2138 105 855 -1242 -4162 -4610 -2231 24 515 467 -643 479 383 337 1206 -290 1195 1000 675 370 552 -245 -866 -1808 -669 -993 853 -1173 -3331 -4944 -3753 23234 -1220 -248 -548 -331 -226 -131 348 -600 -496 -68 -275 -764 287 323 518 1223 429 817 853 415 406 -32 163 1081 1551 2176 890 -190 345 -1072 31 455 63 639 46 749 227 -200 -1321 -2550 -1640 -1608 -1810 -1085 -2195 -1821 -1315 -561 294 182 981 885 634 440 -278 -197 -233 -457 -351 817 407 -36 -198 -651 -741 -645 -676 -1235 -587 -578 281 383 1140 1074 954 591 412 -127 83 -209 61 -46 176 -37 456 460 538 298 -305 269 123 -51 62 -391 -196 -443 -104 93 -99 458 455 -88 -130 -505 -685 900000 -384 -57 -263 -497 -610 -334 18 163 -265 -917 -992 -507 6 138 141 -208 157 132 120 441 -107 431 380 252 145 222 -96 -337 -670 -253 -376 343 -520 -1446 -2000 -1575 9199 -633 -143 -359 -213 -151 -89 234 -408 -334 -45 -187 -512 197 224 380 940 327 631 674 332 318 -24 127 887 1305 1972 804 -172 297 -888 26 402 60 639 48 744 215 -181 -1144 -2055 -1301 -1423 -1723 -1081 -2288 -1968 -1427 -654 346 223 1216 1079 758 505 -291 -201 -244 -502 -407 997 524 -47 -256 -780 -853 -736 -810 -1599 -751 -777 392 542 1641 1600 1391 844 563 -168 107 -277 83 -65 258 -54 649 634 729 405 -394 332 162 -70 89 -563 -285 -661 -158 145 -159 745 758 -144 -205 -808 -1057 SS 20260305T121351.7Z 9560.509626 277 1 54.82 2 62.14 87.33 94.80 262.28 0.00 1 0.00 1 0 17 1.192e-02 7.663e-03 1.667e-03 8.639e-04 2.360181e-01 4.282078e-04 2.483673e-03 -6.000000e+00 6.620112e-03 225.98 -2.00 3.04 -2.00 316.06 0.00e+00 4.862096e-04 4.799708e-05 1.278110e-04 -6.000000e+00 3.054713e-04 291.72 -2.00 20.00 -2.00 315.24 0.00e+00 2.129 0.000 302.00 328.00 3 3.7505e+00 1.1057e-03 2.2612e-02 -6.0000e+00 1.6344e-02 9.7170e-03 1.2381e-03 1.0428e-02 -6.0000e+00 1.7728e-02 -1.0727e-03 7.1660e-04 5.0973e-03 -6.0000e+00 1.0626e-02 -3.2541e-03 3.4293e-04 1.4460e-03 -6.0000e+00 4.6673e-03 1.2764e-03 8.9397e-05 2.2834e-05 1.5811e-05 -6.0000e+00 2.9839e-04 -1.6628e-02 0.0000e+00 11 8 0 10 0 0 99.84 25.41 0.22 -0.01663 -0.01596 84 8 1 5 0 652.540 33.75 20.01 25.41 28.88 4.7 986.18 900000 -1026 689 -628 -3805 -3715 -1699 -951 814 -521 -3487 -4347 -1152 -482 1133 1899 -155 1004 831 865 1621 210 1550 1478 1357 823 639 159 -811 -1803 477 -338 1775 -814 -3027 -4082 -3188 -369 -880 -214 -302 -314 -253 -305 423 -59 -293 -14 -119 -907 475 333 810 1391 665 1106 844 655 376 64 463 1167 1597 2411 1036 -332 316 -993 48 462 419 640 197 715 218 -429 -1054 -2388 -1633 -1502 -1773 -897 -2133 -1930 -1156 -596 274 225 898 878 668 194 -486 -389 -437 -274 -99 941 451 -33 -277 -806 -954 -718 -591 -1161 -599 -435 187 615 1026 948 939 610 205 -274 79 -238 177 218 63 14 506 208 457 321 -344 324 104 -150 -56 -305 -248 -417 -129 142 26 605 444 -182 -93 -451 -718 900000 -212 147 -133 -800 -702 -320 -196 187 -122 -839 -1023 -284 -135 358 620 -54 358 309 333 641 84 603 605 547 348 278 66 -338 -717 191 -147 758 -385 -1398 -1746 -1419 -182 -487 -133 -198 -217 -181 -223 305 -43 -211 -10 -81 -607 323 245 593 1067 537 902 669 525 296 53 382 960 1424 2193 991 -301 271 -816 40 407 397 641 202 711 206 -388 -900 -2004 -1350 -1310 -1671 -888 -2219 -2083 -1312 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