File name: Pandora86s1_SantaCruz_20260313_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260314T042836.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260313_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260313 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260313T111740.5Z 9568.470608 229 1 54.82 2 75.96 88.46 13.27 135.17 0.00 1 0.00 1 0 17 5.348e-02 7.762e-03 7.366e-03 8.814e-04 4.233422e-01 4.364177e-04 4.376733e-03 -6.000000e+00 2.972626e-02 226.15 -2.00 3.04 -2.00 318.76 0.00e+00 7.516738e-04 9.912740e-05 6.721852e-04 -6.000000e+00 1.370744e-03 291.69 -2.00 20.00 -2.00 317.88 0.00e+00 4.029 0.000 302.00 328.00 3 1.8008e+00 1.1999e-03 4.2447e-02 -6.0000e+00 7.3419e-02 -3.6179e-02 1.3887e-03 1.9209e-02 -6.0000e+00 7.9628e-02 -1.8699e-02 9.8207e-04 9.3649e-03 -6.0000e+00 4.7722e-02 5.1861e-03 5.2713e-04 2.6313e-03 -6.0000e+00 2.0950e-02 1.2568e-03 -8.2938e-05 2.3281e-05 2.5808e-05 -6.0000e+00 1.3392e-03 -1.5940e-02 0.0000e+00 11 8 0 10 0 0 96.56 25.59 0.36 -0.01594 -0.01656 215 21 1 5 0 254.950 34.00 20.00 25.59 31.29 4.7 1001.12 900000 -17432 -14151 -7573 -13381 -20495 -19519 -20557 -3429 -16999 -22468 -19957 -12871 -6408 -5734 1523 -3241 92 787 -757 -419 -994 1707 9 924 574 -461 -1333 -4560 -6043 -3169 -3692 446 -2263 -3989 -8265 -7222 11225 -1295 264 120 965 498 996 1186 251 191 566 564 -547 485 289 1426 1269 910 1757 973 407 369 153 342 1537 1909 2935 1603 503 550 -617 251 578 626 1004 64 629 -2 -699 -1254 -2795 -2033 -1911 -1606 -805 -2011 -1725 -1196 -639 366 308 1005 1106 721 362 -454 -574 -518 -638 -231 815 412 -40 -474 -1061 -1107 -789 -615 -1234 -645 -532 209 451 1059 981 835 544 -3 -189 120 -134 163 47 60 -85 642 480 551 210 -571 393 180 -70 77 -247 -116 -428 -177 124 -39 490 416 -115 -79 -472 -540 900000 -613 -524 -265 -446 -675 -663 -795 -129 -814 -1170 -1029 -710 -404 -433 127 -313 9 84 -86 -50 -119 200 1 128 77 -65 -185 -674 -887 -448 -600 79 -456 -798 -1605 -1471 2196 -349 79 41 353 177 364 434 94 72 212 213 -213 199 132 695 619 475 938 543 232 206 84 188 895 1150 1950 1081 330 359 -399 167 413 479 816 54 505 -1 -512 -886 -1897 -1412 -1430 -1309 -697 -1951 -1663 -1219 -666 402 337 1108 1258 770 376 -440 -562 -507 -671 -261 989 535 -53 -629 -1298 -1285 -896 -764 -1582 -858 -716 296 666 1633 1538 1308 847 -5 -267 165 -192 239 75 95 -136 993 721 820 302 -820 547 263 -109 124 -407 -197 -757 -321 231 -76 926 803 -219 -148 -879 -964 SS 20260313T112803.0Z 9568.477812 232 1 54.76 2 73.49 87.64 11.66 142.64 0.00 1 0.00 1 0 17 2.270e-02 7.321e-03 2.267e-03 5.034e-04 3.686463e-01 2.489308e-04 3.828143e-03 -6.000000e+00 1.262085e-02 226.15 -2.00 3.04 -2.00 317.92 0.00e+00 7.549470e-04 4.385480e-05 3.869247e-04 -6.000000e+00 5.819649e-04 291.69 -2.00 20.00 -2.00 317.03 0.00e+00 3.462 0.000 302.00 328.00 3 1.3105e+00 6.6465e-04 3.6512e-02 -6.0000e+00 3.1172e-02 -3.6815e-02 7.5532e-04 1.6462e-02 -6.0000e+00 3.3808e-02 -9.5646e-03 4.7895e-04 8.0380e-03 -6.0000e+00 2.0261e-02 2.3420e-03 2.5118e-04 2.2805e-03 -6.0000e+00 8.8951e-03 3.6522e-03 -1.7399e-05 1.3289e-05 2.1859e-05 -6.0000e+00 5.6857e-04 -1.6104e-02 0.0000e+00 11 8 0 10 0 0 99.09 25.60 0.34 -0.01610 -0.01623 419 40 1 5 0 130.670 34.00 20.00 25.60 31.51 4.7 1002.99 900000 -5310 -3286 -3423 -6467 -9258 -9421 -7324 -3303 -6620 -6735 -8962 -5473 -1606 -980 1563 -63 1641 1668 935 1137 544 1482 1541 943 550 -66 -1044 -2202 -3070 -760 -852 1110 -750 -3249 -5010 -4222 -1181 -1014 -179 10 251 315 353 802 443 94 97 -397 -632 588 839 864 1546 1056 1105 1024 622 320 32 617 1365 1939 2779 1553 63 462 -698 251 553 465 824 96 601 42 -462 -1221 -2445 -1807 -1533 -1829 -1138 -2146 -1904 -1142 -504 277 218 907 910 749 469 -247 -260 -366 -315 -195 825 446 -165 -470 -1016 -1053 -673 -524 -1246 -799 -489 99 482 890 895 728 437 146 -182 191 -138 261 180 76 143 656 367 418 211 -363 446 249 -163 94 -365 -78 -335 33 127 -73 539 381 -181 -169 -565 -585 900000 -368 -240 -251 -437 -588 -620 -529 -263 -603 -627 -855 -570 -175 -126 229 -10 278 301 178 226 108 293 299 198 123 -15 -239 -474 -646 -168 -211 301 -211 -911 -1434 -1268 -366 -352 -75 5 119 157 169 383 215 46 47 -192 -309 299 469 489 931 639 687 658 407 206 20 391 917 1356 2130 1213 48 339 -502 184 441 400 719 86 520 36 -378 -949 -1804 -1351 -1239 -1628 -1083 -2175 -1933 -1223 -558 311 255 1074 1060 849 510 -249 -259 -382 -340 -227 1035 579 -220 -616 -1275 -1248 -783 -643 -1596 -1063 -662 136 689 1335 1366 1138 649 209 -249 264 -192 372 268 117 217 1000 544 608 295 -500 617 349 -244 145 -581 -127 -547 56 222 -132 962 695 -326 -298 -988 -1011 SS 20260313T114715.6Z 9568.491152 242 1 3.93 2 68.92 86.09 9.53 162.59 0.00 1 0.00 1 0 17 3.626e-02 1.149e-02 2.446e-02 7.473e-03 3.038077e-01 3.693526e-03 3.137972e-03 -6.000000e+00 2.015885e-02 226.15 -2.00 3.04 -2.00 317.37 0.00e+00 7.725718e-04 5.560525e-04 2.754004e-04 -6.000000e+00 9.294164e-04 291.69 -2.00 20.00 -2.00 316.49 0.00e+00 2.754 0.000 302.00 328.00 3 3.9697e+00 9.7312e-03 2.9217e-02 -6.0000e+00 4.9790e-02 1.7618e-02 1.0994e-02 1.3419e-02 -6.0000e+00 5.3997e-02 -5.7757e-03 6.6819e-03 6.5663e-03 -6.0000e+00 3.2361e-02 -3.5226e-03 3.4077e-03 1.8794e-03 -6.0000e+00 1.4210e-02 5.1577e-04 -1.1949e-04 1.9814e-04 1.8155e-05 -6.0000e+00 9.0798e-04 -1.7379e-02 0.0000e+00 12 9 9 12 33 1 999.00 25.66 0.25 -0.01738 -0.01828 1 3 1 5 0 1961.130 34.00 20.00 25.66 33.04 4.7 1015.58 900000 -7402 -2362 4932 -17663 -15588 -3538 10974 6761 -2644 -10235 -12789 1262 796 2828 3661 -2444 900 -9458 830 3563 8540 4017 7540 4142 4545 -2306 -523 -1796 -596 3580 -2528 197 -1696 -2544 -8473 -7277 4475 -5494 1990 -762 2207 -4192 943 3414 646 -1484 -1258 1795 945 -103 69 1016 1000 1110 15 2504 75 -128 588 -460 2822 2705 3034 412 31 1519 -1735 -538 -44 534 1463 450 -148 707 -436 -1761 -2713 -76 -1678 -1150 -314 -3219 -975 -2075 -898 162 -190 863 1199 579 37 -466 -1656 -1700 -769 148 528 223 922 -900 -628 -121 -400 -174 -966 -520 -220 4 -281 2311 345 685 627 -47 -439 477 574 -284 181 291 -74 941 442 641 797 -1180 -580 476 -376 -679 -501 614 -639 227 226 -89 361 1144 -156 -417 -652 -807 900000 -820 -265 510 -2034 -1590 -327 976 714 -337 -1425 -1799 170 126 466 689 -526 195 -2394 197 857 1946 953 1828 1109 1274 -713 -154 -492 -154 934 -772 64 -564 -823 -2676 -2386 1492 -2432 913 -408 1216 -2376 521 1834 359 -839 -694 1020 538 -57 42 649 679 738 10 1721 53 -89 399 -319 2014 2119 2429 355 26 1193 -1347 -421 -37 469 1353 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