File name: Pandora86s1_SantaCruz_20260327_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260328T042335.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260327_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260327 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260327T124641.5Z 9582.532424 139 1 54.34 2 55.97 73.94 168.09 59.31 0.00 1 0.00 1 0 17 1.220e-02 8.459e-03 1.323e-03 8.358e-04 1.995084e-01 4.177933e-04 2.111183e-03 -6.000000e+00 6.787552e-03 226.33 -2.00 3.04 -2.00 315.34 0.00e+00 3.678419e-04 3.980226e-05 8.382637e-05 -6.000000e+00 3.123754e-04 291.45 -2.00 20.00 -2.00 314.59 0.00e+00 1.781 0.000 302.00 328.00 3 4.0549e+00 1.0694e-03 1.8981e-02 -6.0000e+00 1.6773e-02 1.3724e-02 1.1917e-03 8.8233e-03 -6.0000e+00 1.8188e-02 2.4166e-03 6.8639e-04 4.3120e-03 -6.0000e+00 1.0897e-02 -4.4956e-03 3.1767e-04 1.2205e-03 -6.0000e+00 4.7826e-03 1.3797e-03 -2.1892e-05 2.1973e-05 1.4087e-05 -6.0000e+00 3.0547e-04 -1.8340e-02 0.0000e+00 11 8 0 10 0 0 99.93 25.60 0.35 -0.01834 -0.01850 52 5 1 5 0 1044.890 34.00 20.00 25.60 31.05 4.7 1001.48 900000 -1221 -20 -1037 -2564 -2118 -1941 562 626 -713 -2688 -1935 -743 -574 246 1209 -274 984 886 1147 1117 -132 1537 1487 986 781 722 -521 -820 -678 536 -263 1645 -450 -2863 -4001 -3539 7469 -1265 -130 -604 -850 -234 -351 -20 -128 -540 -229 -575 -903 345 366 200 980 679 1061 826 365 455 131 553 1193 1608 2341 928 -100 484 -935 13 307 302 716 190 747 25 -219 -783 -2031 -1524 -1413 -1812 -1596 -2060 -1830 -1113 -617 284 193 780 761 665 360 -526 -247 -279 -452 -230 859 659 10 -202 -677 -778 -943 -530 -1266 -633 -590 252 428 1115 964 957 587 462 -115 55 -324 59 158 72 44 538 342 599 267 -330 454 172 -164 83 -327 -168 -510 -18 136 24 398 384 -231 -122 -589 -646 900000 -355 -6 -306 -730 -537 -497 154 194 -225 -864 -593 -240 -209 93 509 -123 443 385 513 516 -61 693 701 493 407 385 -269 -388 -322 255 -126 824 -247 -1537 -1983 -1825 3920 -762 -88 -436 -645 -182 -279 -16 -100 -420 -171 -417 -675 261 281 162 787 569 897 714 320 390 111 470 1068 1480 2199 913 -92 439 -810 11 283 300 718 196 746 25 -209 -700 -1766 -1296 -1261 -1747 -1624 -2186 -2010 -1231 -707 344 234 959 920 782 403 -559 -252 -288 -490 -263 1036 837 12 -257 -798 -881 -1063 -629 -1563 -807 -788 334 597 1585 1411 1363 812 606 -144 66 -408 76 213 103 62 742 457 782 348 -408 556 214 -211 112 -441 -228 -709 -26 204 36 609 601 -358 -182 -889 -941 SS 20260327T130233.0Z 9582.543437 149 1 21.74 2 52.36 71.93 164.94 65.25 0.00 1 0.00 1 0 17 9.704e-03 7.580e-03 1.163e-03 8.206e-04 1.847315e-01 4.124089e-04 1.970072e-03 -6.000000e+00 5.399387e-03 226.33 -2.00 3.04 -2.00 314.85 0.00e+00 3.557213e-04 3.569494e-05 5.811643e-05 -6.000000e+00 2.484957e-04 291.45 -2.00 20.00 -2.00 314.15 0.00e+00 1.633 0.000 302.00 328.00 3 3.2867e+00 1.0501e-03 1.7457e-02 -6.0000e+00 1.3343e-02 2.2402e-02 1.1664e-03 8.1991e-03 -6.0000e+00 1.4468e-02 -8.8928e-04 6.7144e-04 4.0071e-03 -6.0000e+00 8.6684e-03 -3.2282e-03 3.0584e-04 1.1326e-03 -6.0000e+00 3.8044e-03 3.5008e-03 -6.2819e-05 2.1435e-05 1.3807e-05 -6.0000e+00 2.4301e-04 -1.8134e-02 0.0000e+00 12 9 1 12 1 1 99.99 25.64 0.37 -0.01813 -0.01861 54 13 1 5 0 395.100 34.00 20.00 25.64 32.89 4.8 1015.93 900000 -441 546 -972 -2595 -2351 -1448 197 388 -29 -2169 -1517 -647 -436 385 721 393 932 1116 1431 1579 313 1352 1633 1367 955 437 -224 -913 -397 690 166 1226 -256 -2757 -3181 -3008 -1625 -1151 -18 -501 -561 -13 -154 42 -121 -447 -279 -531 -531 629 596 482 1106 718 928 842 418 412 279 464 1317 1429 2290 1180 -255 161 -1047 92 370 386 628 137 601 155 -334 -769 -1964 -1431 -1237 -1707 -1173 -2197 -1759 -1036 -649 140 47 852 888 568 363 -304 -279 -292 -284 -116 981 512 58 -149 -700 -842 -712 -437 -1180 -680 -666 25 448 918 943 739 660 163 -108 9 -317 282 322 129 -49 601 397 565 203 -392 400 255 -2 0 -347 -213 -278 23 125 -73 478 314 -152 -168 -649 -608 900000 -159 202 -356 -905 -729 -449 66 137 -11 -847 -563 -253 -179 177 346 198 472 550 723 822 164 690 866 764 528 248 -129 -482 -206 360 87 677 -146 -1615 -1705 -1682 -963 -767 -13 -387 -455 -10 -125 34 -97 -355 -222 -408 -413 494 479 392 936 634 794 734 369 357 247 415 1186 1339 2200 1181 -250 147 -939 81 341 386 640 143 611 157 -319 -708 -1666 -1234 -1126 -1626 -1183 -2340 -1933 -1155 -755 166 58 1036 1096 678 409 -321 -281 -297 -305 -132 1183 635 73 -183 -826 -948 -797 -519 -1469 -847 -869 33 613 1286 1317 1035 887 207 -133 10 -395 360 433 177 -67 806 532 736 253 -479 481 312 -2 0 -465 -287 -382 32 181 -106 709 464 -229 -245 -948 -856 SS 20260327T132443.0Z 9582.558831 167 1 14.19 2 47.39 68.73 160.32 69.90 0.00 1 0.00 1 0 33 9.656e-02 1.024e-01 3.791e-03 2.632e-03 1.563148e-01 1.310061e-03 2.578646e-03 -6.000000e+00 5.370531e-02 226.33 -2.00 3.04 -2.00 314.83 0.00e+00 1.123489e-03 1.161108e-04 3.497246e-04 -6.000000e+00 2.472880e-03 291.45 -2.00 20.00 -2.00 314.14 0.00e+00 1.475 0.000 302.00 328.00 3 5.0748e+00 3.3422e-03 1.6370e-02 -6.0000e+00 1.3271e-01 6.0446e-02 3.7292e-03 9.2422e-03 -6.0000e+00 1.4393e-01 1.1402e-02 2.1420e-03 4.1857e-03 -6.0000e+00 8.6235e-02 -3.8067e-02 9.6588e-04 1.6571e-03 -6.0000e+00 3.7823e-02 7.1149e-04 6.9451e-03 6.7967e-05 1.9727e-05 -6.0000e+00 2.4184e-03 -1.4248e-02 0.0000e+00 12 9 9 12 1 1 -151.84 25.77 0.07 -0.01425 0.03794 4 2 1 5 0 2836.740 34.00 20.00 25.77 33.92 4.7 1019.71 900000 5367 3960 982 -2558 -4 5149 10322 9807 4026 -1874 3234 9058 8635 10100 10211 5648 7162 7124 7659 6534 4809 8557 9272 7215 5930 2658 -136 416 4674 7476 6512 9577 4622 -1434 1887 5677 -98755 10749 10660 6229 4326 4324 3556 3800 3720 2514 2716 2068 2348 6961 5754 5271 6475 4555 5140 4922 2639 2299 3124 5257 7840 7499 6891 1644 -2690 -477 -592 5199 7196 4242 3357 1250 148 -2082 -3674 -3639 -3829 2236 4384 2680 3197 -163 9 2820 2444 2510 1459 281 -1128 -3080 -4021 -5516 -1975 2234 3050 3018 4161 1297 -3075 -4094 -5511 -3694 1427 2253 -868 198 -290 735 1719 1401 -795 -2997 -4933 -5103 -4295 -884 166 2309 1845 -37 -1696 -975 -2901 -2115 -2405 -3092 1200 2509 1892 1232 -484 -205 1061 3134 2054 913 1694 804 -358 -113 -733 648 900000 1925 1465 348 -810 -1 1608 3128 3332 1521 -721 1162 3374 3632 4338 4766 2807 3567 3655 3740 3296 2412 4472 4677 3863 3323 1537 -75 225 2323 3747 3465 5295 2572 -771 1007 3179 -112219 6860 7462 4937 3392 3484 2905 3070 3005 1996 2191 1612 1785 5265 4689 4237 5380 3939 4452 4347 2370 2024 2710 4595 7158 6995 6854 1612 -2607 -433 -511 4439 6903 4337 3418 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