File name: Pandora86s1_SantaCruz_20260517_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260518T041447.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260517_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260517T174215.4Z 9633.737678 268 1 9.22 2 43.66 327.37 46.51 346.80 0.00 1 0.00 1 0 17 1.047e-02 8.313e-03 2.989e-03 2.203e-03 1.558787e-01 1.106255e-03 1.665765e-03 -6.000000e+00 5.824596e-03 226.29 -2.00 3.04 -2.00 314.58 0.00e+00 3.374752e-04 9.050722e-05 6.287375e-05 -6.000000e+00 2.664678e-04 290.03 -2.00 20.00 -2.00 313.93 0.00e+00 1.380 0.000 302.00 328.00 3 4.4972e+00 2.8124e-03 1.4758e-02 -6.0000e+00 1.4399e-02 7.6830e-03 3.1213e-03 6.9039e-03 -6.0000e+00 1.5618e-02 -1.8009e-03 1.7968e-03 3.3729e-03 -6.0000e+00 9.3493e-03 -4.5245e-03 8.1035e-04 9.5147e-04 -6.0000e+00 4.0983e-03 1.4070e-03 1.5007e-04 5.7441e-05 1.1993e-05 -6.0000e+00 2.6216e-04 -1.8785e-02 0.0000e+00 12 9 1 12 1 1 99.80 24.80 0.36 -0.01878 -0.01766 6 4 1 5 0 1317.120 33.50 20.00 24.80 24.47 4.9 953.22 900000 -788 129 -397 -2426 -1059 -659 2452 943 1431 -1992 -2549 -644 90 385 1255 -853 -72 507 1263 1783 106 1033 1676 1226 792 391 -250 -879 -745 -3 409 1807 -253 -2923 -4208 -1855 -2158 -433 -146 -618 -859 -235 -427 76 -273 -622 -130 -633 -897 653 648 366 954 1261 1875 628 193 496 223 1048 985 1806 2033 1329 -211 252 -1245 -1 390 433 996 9 770 438 -291 -723 -2407 -1892 -1382 -1615 -925 -2131 -1504 -1026 -441 122 339 949 541 447 530 -572 -401 -276 -534 -394 1001 426 305 -54 -947 -1071 -606 -620 -1511 -485 -561 -31 406 991 1133 978 714 428 -345 -142 -540 268 165 243 -198 593 236 812 210 -128 556 13 -43 168 -235 47 -444 2 47 -271 546 412 -84 -206 -624 -711 900000 -309 52 -156 -910 -349 -217 858 377 573 -817 -1078 -261 41 179 642 -462 -39 280 710 963 58 585 918 707 475 240 -147 -505 -397 -1 227 1049 -150 -1686 -2386 -1073 -1330 -293 -111 -501 -728 -193 -358 63 -225 -533 -107 -500 -723 526 527 314 807 1102 1642 566 177 442 197 926 920 1720 1973 1333 -208 232 -1083 -1 374 425 1032 9 798 434 -276 -642 -2076 -1583 -1264 -1582 -946 -2275 -1652 -1135 -504 148 410 1163 656 527 592 -607 -406 -281 -567 -440 1167 523 377 -66 -1126 -1232 -692 -748 -1892 -599 -727 -42 544 1344 1569 1365 965 549 -425 -169 -667 336 217 324 -266 806 312 1043 258 -156 643 16 -54 219 -304 61 -588 3 67 -387 790 612 -124 -294 -903 -995 SS 20260517T180844.4Z 9633.756070 281 1 13.89 2 47.39 320.34 48.32 339.43 0.00 1 0.00 1 0 17 9.065e-03 7.295e-03 1.124e-03 8.461e-04 1.648418e-01 4.255023e-04 1.759733e-03 -6.000000e+00 5.043498e-03 226.29 -2.00 3.04 -2.00 314.50 0.00e+00 3.393364e-04 3.437612e-05 4.054762e-05 -6.000000e+00 2.307082e-04 290.03 -2.00 20.00 -2.00 313.87 0.00e+00 1.475 0.000 302.00 328.00 3 3.0753e+00 1.0806e-03 1.5734e-02 -6.0000e+00 1.2469e-02 4.0596e-03 1.1992e-03 7.3148e-03 -6.0000e+00 1.3523e-02 1.0449e-03 6.9054e-04 3.5709e-03 -6.0000e+00 8.0952e-03 -4.3553e-03 3.1060e-04 1.0111e-03 -6.0000e+00 3.5491e-03 5.2431e-03 -3.0696e-05 2.2042e-05 1.2458e-05 -6.0000e+00 2.2697e-04 -1.9678e-02 0.0000e+00 12 9 1 12 1 1 99.27 24.88 0.36 -0.01968 -0.01991 36 14 1 5 0 375.230 33.50 20.00 24.88 25.50 4.8 959.76 900000 -176 369 -1104 -2295 -2181 -1378 245 618 223 -1609 -1755 -392 -294 1097 827 55 1276 966 1466 1377 206 1179 1310 952 651 547 -151 -835 -506 804 66 1420 -114 -2599 -2729 -2480 -1572 -990 -280 -365 -704 -93 -370 -224 -76 -313 -517 -722 -549 370 574 424 1256 766 862 754 644 309 124 737 1158 1372 2198 1087 -277 -160 -957 115 398 341 554 3 668 205 -245 -564 -1668 -1309 -1418 -1714 -1050 -2051 -1633 -1163 -571 65 183 821 801 568 485 -426 -138 -377 -222 -74 875 549 172 -268 -634 -811 -568 -330 -1190 -605 -583 -143 478 906 937 784 593 92 -96 62 -266 331 187 -53 187 538 325 571 200 -377 266 205 -193 12 -336 -36 -379 38 178 -97 327 267 -96 -116 -490 -582 900000 -72 156 -459 -896 -806 -508 91 243 96 -699 -727 -169 -134 522 438 29 670 524 812 787 118 659 761 555 395 339 -90 -479 -283 447 37 832 -69 -1535 -1542 -1457 -987 -671 -207 -292 -568 -77 -311 -186 -63 -256 -423 -569 -434 294 468 351 1077 685 750 669 576 272 111 666 1062 1310 2156 1109 -265 -146 -855 102 380 343 570 3 686 208 -235 -517 -1458 -1112 -1276 -1680 -1054 -2179 -1790 -1300 -667 78 223 1011 972 665 549 -452 -143 -380 -235 -83 1050 680 216 -329 -744 -907 -631 -391 -1483 -757 -742 -188 637 1240 1314 1068 795 116 -118 74 -326 417 243 -71 250 724 423 719 247 -456 316 248 -243 16 -446 -48 -500 51 250 -140 471 394 -141 -168 -694 -819 SS 20260517T181336.5Z 9633.759450 284 1 15.54 2 48.14 319.17 48.74 338.15 0.00 1 0.00 1 0 17 1.002e-02 7.909e-03 1.806e-03 1.306e-03 1.670932e-01 6.565660e-04 1.778735e-03 -6.000000e+00 5.573144e-03 226.29 -2.00 3.04 -2.00 314.71 0.00e+00 4.412345e-04 5.507030e-05 5.085107e-05 -6.000000e+00 2.549473e-04 290.03 -2.00 20.00 -2.00 314.05 0.00e+00 1.496 0.000 302.00 328.00 3 3.9723e+00 1.6707e-03 1.5954e-02 -6.0000e+00 1.3778e-02 6.3851e-03 1.8547e-03 7.4078e-03 -6.0000e+00 1.4944e-02 1.0360e-03 1.0677e-03 3.6103e-03 -6.0000e+00 8.9455e-03 -4.3387e-03 4.8329e-04 1.0295e-03 -6.0000e+00 3.9216e-03 2.0840e-03 5.5102e-05 3.4139e-05 1.2367e-05 -6.0000e+00 2.5082e-04 -1.9299e-02 0.0000e+00 12 9 1 12 1 1 99.99 24.90 0.32 -0.01930 -0.01888 22 8 1 5 0 675.480 33.50 19.99 24.90 25.63 4.9 960.70 900000 -112 808 -1557 -2283 -2202 -2226 567 797 -73 -2017 -1718 -508 -343 1015 880 327 1073 585 1330 1449 779 1165 1518 982 548 445 -339 -907 -480 427 205 1504 59 -2961 -3103 -2715 -2468 -953 -351 -280 -304 187 -749 -216 -124 -464 -240 -603 -588 554 787 440 1119 1008 1108 917 341 687 317 384 1315 1534 2092 905 -473 163 -1314 428 520 473 795 -47 866 400 -162 -685 -2148 -1567 -1375 -1572 -1058 -2048 -1925 -1110 -468 131 -4 963 860 442 470 -493 -456 -372 -323 -34 816 518 -84 -106 -772 -1035 -859 -372 -1079 -877 -594 99 535 799 1123 882 516 176 -64 53 -423 384 141 32 190 537 425 530 536 -175 341 242 -290 -29 -275 -209 -558 16 173 -41 505 472 -205 -149 -684 -672 900000 -43 317 -606 -783 -723 -735 200 293 -29 -821 -665 -205 -144 473 427 166 546 308 714 801 430 631 852 547 318 264 -194 -503 -247 220 111 856 34 -1684 -1709 -1555 -1503 -642 -253 -226 -244 154 -633 -180 -103 -381 -188 -480 -453 429 649 365 964 861 954 806 304 597 273 334 1195 1439 2093 903 -463 148 -1185 379 493 464 825 -50 896 397 -153 -632 -1826 -1358 -1246 -1534 -1086 -2201 -2055 -1244 -544 155 -5 1202 1058 530 533 -528 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