File name: Pandora86s1_SantaCruz_20260522_L2Fit_fwvt1c2d20240531p1-8.txt File generation date: 20260523T041759.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260522_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260522 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1617 1767 Nominal wavelengths inside fitting window [nm]: 492.0187 492.1398 492.2608 492.3818 492.5028 492.6238 492.7448 492.8657 492.9866 493.1075 493.2284 493.3493 493.4702 493.5910 493.7119 493.8327 493.9535 494.0743 494.1951 494.3158 494.4365 494.5573 494.6780 494.7987 494.9193 495.0400 495.1606 495.2812 495.4019 495.5224 495.6430 495.7636 495.8841 496.0046 496.1252 496.2456 496.3661 496.4866 496.6070 496.7274 496.8479 496.9683 497.0886 497.2090 497.3293 497.4497 497.5700 497.6903 497.8106 497.9308 498.0511 498.1713 498.2915 498.4117 498.5319 498.6521 498.7722 498.8924 499.0125 499.1326 499.2527 499.3727 499.4928 499.6128 499.7328 499.8528 499.9728 500.0928 500.2127 500.3327 500.4526 500.5725 500.6924 500.8123 500.9321 501.0520 501.1718 501.2916 501.4114 501.5312 501.6509 501.7707 501.8904 502.0101 502.1298 502.2495 502.3691 502.4888 502.6084 502.7280 502.8476 502.9672 503.0867 503.2063 503.3258 503.4453 503.5648 503.6843 503.8038 503.9232 504.0427 504.1621 504.2815 504.4008 504.5202 504.6396 504.7589 504.8782 504.9975 505.1168 505.2361 505.3553 505.4746 505.5938 505.7130 505.8322 505.9513 506.0705 506.1896 506.3087 506.4278 506.5469 506.6660 506.7851 506.9041 507.0231 507.1421 507.2611 507.3801 507.4991 507.6180 507.7369 507.8558 507.9747 508.0936 508.2125 508.3313 508.4501 508.5689 508.6877 508.8065 508.9253 509.0440 509.1627 509.2814 509.4001 509.5188 509.6375 509.7561 509.8748 509.9934 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260522T114847.9Z 9638.492221 66 1 13.13 2 74.45 61.98 149.87 87.76 0.00 1 0.00 1 0 15 3.868e-03 3.836e-03 1.545e-04 1.544e-04 5.397145e+03 9.529483e+00 3.717841e+02 -6.000000e+00 2.094343e+02 289.89 -2.00 20.00 -2.00 505.29 0.00e+00 7.552472e-04 4.241206e-06 4.920639e-05 -6.000000e+00 1.083365e-04 289.89 -2.00 20.00 -2.00 500.56 0.00e+00 3.033069e-01 2.947542e-03 3.475520e-02 -6.000000e+00 7.427567e-02 226.27 -2.00 3.04 -2.00 502.13 0.00e+00 3.663 0.000 489.00 513.00 1 2.4449e+00 2.2581e-04 5.9201e-03 -6.0000e+00 5.6952e-03 -6.0813e-03 5.8827e-05 8.7682e-04 -6.0000e+00 1.4975e-03 9.9178e-02 3.5004e-04 1.2297e-05 4.2158e-05 -6.0000e+00 3.2019e-04 -7.9445e-03 -1.9287e-04 12 9 1 12 1 1 96.74 24.16 1.33 -0.00794 -0.00552 270 57 1 4 0 48.440 33.00 20.00 24.16 21.07 4.8 927.57 900000 -1021 -633 -145 123 404 537 662 656 394 376 244 -33 -167 -246 -208 -205 26 204 167 281 171 97 266 352 327 438 516 10 -427 -678 -811 -779 -183 79 243 289 105 -87 -211 -140 -161 20 198 364 446 456 384 339 6 -393 -664 -1030 -939 -697 -331 -112 145 168 63 93 235 345 437 424 357 209 63 -122 -369 -357 -379 -367 -105 9 -27 -101 -181 -406 -559 -543 -510 -589 -427 -206 -108 -50 -114 -123 -128 -69 175 428 388 401 404 208 -8 -325 -628 -782 -755 -567 -101 -159 9 -20 -306 -400 -297 -245 -147 116 272 410 569 733 713 495 437 218 55 110 353 204 282 411 172 229 464 58 -29 54 -206 -434 -160 -123 -67 232 317 158 240 241 273 331 261 39 -329 -489 -663 -611 900000 -981 -615 -144 124 410 551 684 681 407 386 250 -34 -168 -245 -207 -205 26 210 172 291 177 101 276 366 339 457 536 10 -433 -672 -810 -777 -185 82 254 301 108 -89 -214 -143 -163 21 205 376 465 475 397 348 6 -395 -654 -1006 -911 -680 -331 -114 147 171 64 95 238 352 447 432 360 209 63 -120 -365 -351 -371 -359 -104 9 -27 -99 -177 -395 -540 -524 -496 -574 -417 -201 -107 -49 -112 -121 -126 -68 173 428 389 403 401 204 -8 -310 -593 -737 -707 -539 -98 -158 9 -20 -304 -395 -291 -241 -146 117 273 413 574 743 723 504 440 218 54 108 347 201 279 406 171 225 456 57 -29 53 -199 -416 -153 -119 -66 230 315 159 240 242 276 336 264 39 -325 -481 -644 -596 SQ 20260522T120013.3Z 9638.500154 70 1 5.94 2 72.07 60.71 147.28 87.18 0.00 1 0.00 1 0 15 3.521e-03 3.495e-03 7.142e-05 7.134e-05 4.795010e+03 4.366538e+00 3.339783e+02 -6.000000e+00 1.907009e+02 289.89 -2.00 20.00 -2.00 505.28 0.00e+00 6.912074e-04 1.959495e-06 4.452082e-05 -6.000000e+00 9.864214e-05 289.89 -2.00 20.00 -2.00 500.54 0.00e+00 2.253078e-01 1.362505e-03 3.077722e-02 -6.000000e+00 6.764638e-02 226.27 -2.00 3.04 -2.00 502.12 0.00e+00 3.203 0.000 489.00 513.00 1 1.8284e-01 1.0440e-04 5.2033e-03 -6.0000e+00 5.1866e-03 -3.3284e-03 2.7220e-05 7.7786e-04 -6.0000e+00 1.3641e-03 1.0216e+00 7.7693e-04 5.7089e-06 3.8008e-05 -6.0000e+00 2.9156e-04 -9.8847e-03 -1.9761e-04 10 0 0 10 0 0 4.27 24.17 1.31 -0.00988 -0.00450 1480 143 1 4 0 4.010 33.00 20.00 24.17 21.31 4.9 931.06 900000 -833 -511 -114 66 349 482 616 646 428 400 260 -15 -200 -299 -323 -291 -52 151 109 262 188 108 272 329 351 450 526 9 -343 -488 -657 -585 -84 63 183 222 32 -146 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670 464 488 244 85 131 305 90 270 390 201 308 502 136 31 83 -214 -410 -170 -143 -103 146 262 111 180 225 259 313 232 52 -302 -425 -574 -534 SQ 20260522T120019.3Z 9638.500223 70 2 5.94 2 72.05 60.70 147.26 87.18 0.00 1 0.00 1 0 15 3.514e-03 3.487e-03 7.193e-05 7.184e-05 4.800287e+03 4.389587e+00 3.347196e+02 -6.000000e+00 1.902936e+02 289.89 -2.00 20.00 -2.00 505.28 0.00e+00 6.897387e-04 1.973246e-06 4.435328e-05 -6.000000e+00 9.843179e-05 289.89 -2.00 20.00 -2.00 500.54 0.00e+00 2.285871e-01 1.372072e-03 3.059163e-02 -6.000000e+00 6.750048e-02 226.27 -2.00 3.04 -2.00 502.11 0.00e+00 3.200 0.000 489.00 513.00 1 1.9694e-01 1.0514e-04 5.1922e-03 -6.0000e+00 5.1754e-03 -3.3698e-03 2.7407e-05 7.7511e-04 -6.0000e+00 1.3612e-03 1.0075e+00 7.5786e-04 5.7416e-06 3.8351e-05 -6.0000e+00 2.9094e-04 -1.0041e-02 -1.9513e-04 10 0 0 10 0 0 15.50 24.17 1.31 -0.01004 -0.00478 1480 143 1 4 0 4.010 33.00 20.00 24.17 21.31 4.9 931.06 900000 -837 -508 -110 68 350 489 619 638 419 416 261 -18 -199 -294 -311 -268 -53 138 104 234 183 87 257 334 353 452 527 6 -333 -480 -644 -595 -59 66 167 222 31 -168 -286 -201 -195 36 190 367 405 413 322 279 -46 -368 -599 -901 -808 -592 -254 -87 127 140 64 79 194 247 324 345 274 186 89 -101 -384 -335 -326 -319 -83 1 -71 -158 -196 -403 -583 -437 -386 -478 -298 -149 -154 -103 -154 -148 -166 -114 156 398 366 395 411 215 6 -334 -611 -753 -740 -560 -105 -149 -20 -8 -292 -360 -259 -203 -114 139 258 348 527 677 672 457 469 224 63 112 313 143 278 386 196 289 501 141 40 64 -219 -432 -175 -172 -108 171 265 109 182 220 262 321 246 37 -293 -409 -588 -543 900000 -809 -496 -109 70 358 505 643 666 435 428 266 -19 -199 -294 -311 -270 -54 141 108 244 191 91 267 349 367 468 549 6 -338 -477 -637 -594 -59 69 175 232 31 -173 -291 -205 -199 37 197 380 418 431 333 287 -47 -370 -590 -880 -783 -578 -254 -88 129 143 65 80 196 252 332 352 276 186 88 -100 -380 -329 -319 -312 -82 1 -70 -156 -191 -391 -563 -421 -375 -465 -291 -146 -153 -101 -152 -145 -164 -113 155 398 367 397 408 212 6 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