File name: Pandora86s1_SantaCruz_20260606_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260607T041537.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260606_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260606T122139.3Z 9653.515038 292 1 54.22 2 69.22 56.31 49.61 266.07 0.00 1 0.00 1 0 17 4.340e-02 1.117e-02 1.529e-02 3.265e-03 2.743125e-01 1.611469e-03 2.943365e-03 -6.000000e+00 2.414974e-02 226.24 -2.00 3.04 -2.00 318.13 0.00e+00 1.223993e-04 2.946982e-04 6.563578e-04 -6.000000e+00 1.103321e-03 289.45 -2.00 20.00 -2.00 317.27 0.00e+00 2.790 0.000 302.00 328.00 3 5.2518e+00 4.3250e-03 2.9153e-02 -6.0000e+00 5.9699e-02 -4.6016e-02 4.9310e-03 1.2807e-02 -6.0000e+00 6.4754e-02 3.2431e-03 3.1494e-03 6.0634e-03 -6.0000e+00 3.8757e-02 5.2869e-04 1.6422e-03 1.7412e-03 -6.0000e+00 1.7033e-02 1.4903e-04 4.9641e-04 8.9267e-05 1.6510e-05 -6.0000e+00 1.1028e-03 -2.0990e-02 0.0000e+00 12 8 8 10 0 0 99.99 25.59 0.07 -0.02099 -0.01726 44 4 2 5 0 1232.170 34.00 19.99 25.59 30.96 4.9 999.72 900000 2249 3012 1008 -510 3287 -5119 20913 31234 790 -13867 -13899 -3261 2508 -3552 3188 4936 -1190 -1638 -4572 1319 -7599 3310 -4916 6419 -4435 108 -196 -5925 -3668 -6074 597 10182 -3236 -2192 -1943 -6037 900000 -1366 1416 1308 1270 -339 -1219 1243 243 423 565 324 -2686 -1905 1806 1093 959 1308 2485 1844 1141 -671 -1336 -443 1331 4291 4033 -221 423 3040 -2732 -878 -246 493 666 -1422 611 499 528 -17 -4914 -1850 -1852 -1824 901 -1586 -1261 -1289 -158 1913 858 920 156 558 297 -1957 -1656 -571 136 -1591 757 729 -169 -1264 -1604 -646 -1055 -263 -2109 136 -925 152 254 2044 1120 1309 674 1023 -38 473 -338 -150 -746 426 -607 590 -112 381 597 244 270 549 -244 8 -563 -520 -1070 -185 233 672 518 373 -2 -548 -312 -371 900000 164 231 78 -35 199 -345 1210 1862 70 -1441 -1416 -326 275 -478 458 744 -197 -286 -856 242 -1519 591 -1010 1258 -1019 24 -43 -1262 -726 -1283 129 2174 -860 -555 -451 -1539 900000 -458 558 537 552 -156 -578 573 114 196 256 144 -1218 -890 884 574 535 764 1465 1124 709 -417 -820 -273 855 2930 3010 -180 322 2053 -1867 -599 -190 394 566 -1259 517 434 416 -12 -3373 -1231 -1384 -1556 772 -1524 -1260 -1368 -180 2109 1000 1090 183 658 321 -1971 -1552 -545 143 -1894 916 971 -230 -1649 -1936 -763 -1240 -313 -2753 181 -1308 223 370 3147 1807 2069 1008 1501 -52 627 -467 -222 -1120 660 -944 887 -165 563 844 328 350 760 -369 12 -885 -830 -1763 -321 403 1195 943 695 -3 -975 -570 -654 SS 20260606T130843.3Z 9653.547723 325 1 2.36 2 60.27 49.51 60.57 263.49 0.00 1 0.00 1 0 17 1.106e-02 7.884e-03 7.289e-03 4.395e-03 2.111791e-01 2.194141e-03 2.223806e-03 -6.000000e+00 6.148910e-03 226.24 -2.00 3.04 -2.00 315.57 0.00e+00 4.451177e-04 2.177840e-04 4.311193e-05 -6.000000e+00 2.806543e-04 289.45 -2.00 20.00 -2.00 314.84 0.00e+00 2.008 0.000 302.00 328.00 3 3.5809e+00 5.6300e-03 2.1153e-02 -6.0000e+00 1.5203e-02 1.0124e-02 6.2788e-03 9.3739e-03 -6.0000e+00 1.6492e-02 -1.6557e-03 3.6217e-03 4.5643e-03 -6.0000e+00 9.8691e-03 -2.8515e-03 1.6872e-03 1.3084e-03 -6.0000e+00 4.3241e-03 1.7613e-03 -4.7456e-05 1.1527e-04 1.4582e-05 -6.0000e+00 2.7681e-04 -1.8779e-02 0.0000e+00 12 9 1 12 1 1 999.00 25.76 0.45 -0.01878 -0.01914 2 7 1 5 0 784.180 34.00 20.00 25.76 33.93 4.8 1020.05 900000 -722 1293 793 -2843 -4565 -2338 -2110 726 -1856 187 -3077 -1431 -62 2100 906 -51 1646 1428 27 1313 647 1383 1468 2216 719 -979 -1221 -1199 -7 1250 723 330 -218 -1352 -2916 -1669 -285 -1077 -106 -417 -845 61 -417 -270 -786 -411 -805 -307 -938 915 469 -89 968 668 1359 808 473 -95 719 879 1341 1261 2651 841 161 -49 -1627 213 664 -51 218 486 980 990 -282 -353 -1612 -662 -1456 -1531 -1594 -2760 -1776 -1086 -10 -438 -6 490 996 187 1548 -614 -175 185 18 28 466 570 317 -303 -1466 -1038 -786 -651 -275 -695 286 -58 633 193 419 1021 304 182 129 817 -116 -252 285 -384 -235 233 599 126 265 -480 303 566 -291 234 -115 -188 -281 300 -53 43 752 750 -63 -364 -854 -842 900000 -193 355 214 -757 -1107 -561 -556 210 -555 55 -898 -439 -21 746 366 -21 660 595 12 584 288 604 670 1060 341 -484 -580 -555 -3 541 337 165 -111 -664 -1418 -838 -150 -643 -71 -300 -608 45 -315 -202 -592 -305 -609 -224 -672 659 347 -70 791 544 1113 679 403 -80 588 725 1167 1138 2437 815 154 -44 -1399 181 604 -50 219 497 973 976 -267 -311 -1382 -554 -1296 -1474 -1630 -2974 -1889 -1214 -12 -520 -7 613 1221 224 1734 -662 -181 193 20 33 558 719 406 -382 -1795 -1210 -908 -794 -346 -881 376 -78 882 279 600 1466 425 241 162 1029 -147 -328 387 -534 -337 326 807 167 347 -596 373 707 -380 321 -158 -260 -399 434 -80 67 1179 1166 -97 -561 -1282 -1261 SS 20260606T132226.0Z 9653.557245 331 1 54.71 2 57.83 47.16 63.75 262.74 0.00 1 0.00 1 0 17 1.067e-02 7.300e-03 8.645e-04 5.024e-04 1.961627e-01 2.502834e-04 2.071766e-03 -6.000000e+00 5.935596e-03 226.24 -2.00 3.04 -2.00 315.69 0.00e+00 2.956911e-04 2.530781e-05 8.309062e-05 -6.000000e+00 2.708731e-04 289.45 -2.00 20.00 -2.00 314.94 0.00e+00 1.871 0.000 302.00 328.00 3 2.8719e+00 6.4356e-04 1.9707e-02 -6.0000e+00 1.4676e-02 -6.6877e-03 7.1744e-04 8.7095e-03 -6.0000e+00 1.5919e-02 1.8359e-03 4.1391e-04 4.2499e-03 -6.0000e+00 9.5261e-03 -4.4782e-03 1.9393e-04 1.2026e-03 -6.0000e+00 4.1748e-03 4.2035e-03 3.1138e-05 1.3302e-05 1.3721e-05 -6.0000e+00 2.6714e-04 -2.0148e-02 0.0000e+00 11 8 0 10 0 0 100.00 25.83 0.43 -0.02015 -0.01991 930 90 1 5 0 58.820 34.00 20.00 25.83 34.92 4.8 1025.65 900000 -753 717 -1733 -3149 -2279 -2068 -111 868 119 -2220 -2059 -641 -320 -63 625 -218 950 957 1338 982 185 1263 1051 1093 382 403 -162 -555 -859 662 239 1681 46 -2871 -3117 -2863 5263 -1137 -348 -684 -657 -153 -359 -207 14 -530 -620 -889 -841 132 326 324 920 549 675 792 382 237 116 424 1252 1215 2196 1070 -205 148 -950 371 476 277 657 319 607 273 -380 -681 -1867 -1325 -1121 -1676 -1099 -2182 -1894 -1100 -514 98 119 903 862 534 599 -108 -32 -199 -171 -193 782 520 -60 -190 -752 -873 -657 -471 -1223 -757 -605 -62 467 837 860 690 521 313 -64 87 -216 221 147 40 22 387 229 470 293 -256 478 259 -89 8 -348 -88 -395 55 83 -15 427 301 -108 -147 -482 -611 900000 -200 197 -475 -769 -493 -451 -26 229 34 -656 -584 -191 -99 -22 240 -89 389 405 581 409 77 557 448 492 180 195 -75 -237 -373 288 111 757 23 -1391 -1381 -1322 2545 -649 -221 -490 -494 -110 -265 -151 11 -384 -462 -643 -591 94 249 244 725 452 563 673 329 200 97 355 1101 1092 2105 1013 -194 133 -811 313 426 265 665 331 614 264 -356 -602 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