File name: Pandora86s1_SantaCruz_20260630_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260701T042238.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260630_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260630T140206.0Z 9677.584791 349 1 54.74 2 52.46 39.94 121.43 223.23 0.00 1 0.00 1 0 17 9.934e-03 7.561e-03 9.150e-04 5.820e-04 1.801568e-01 2.906804e-04 1.917504e-03 -6.000000e+00 5.524045e-03 226.27 -2.00 3.04 -2.00 315.32 0.00e+00 4.640959e-04 2.727244e-05 8.160535e-05 -6.000000e+00 2.515499e-04 288.85 -2.00 20.00 -2.00 314.61 0.00e+00 1.637 0.000 302.00 328.00 3 3.3830e+00 7.4490e-04 1.7431e-02 -6.0000e+00 1.3661e-02 1.8519e-02 8.2927e-04 8.0015e-03 -6.0000e+00 1.4823e-02 -1.7423e-04 4.7726e-04 3.9087e-03 -6.0000e+00 8.8669e-03 -5.1898e-03 2.2023e-04 1.1138e-03 -6.0000e+00 3.8809e-03 3.1915e-03 7.2042e-05 1.5359e-05 1.2917e-05 -6.0000e+00 2.4876e-04 -1.6263e-02 0.0000e+00 11 8 0 10 0 0 100.00 24.72 0.30 -0.01626 -0.01572 738 71 1 5 0 74.160 33.50 20.01 24.72 26.42 4.9 966.99 900000 -71 880 -1370 -2159 -1572 -1361 142 750 135 -2248 -1682 -605 -206 709 700 36 1064 951 1446 1263 244 1301 1297 831 675 466 -333 -576 -922 492 474 1848 -155 -2791 -3497 -2571 -3446 -754 -149 -518 -284 -154 -340 144 -80 -478 -399 -731 -673 386 477 741 1241 791 1022 785 517 228 297 472 1261 1507 2183 1199 -221 -40 -1085 168 474 446 843 243 757 257 -202 -985 -2080 -1512 -1277 -1561 -1216 -2144 -1796 -1005 -474 140 328 885 789 581 275 -466 -403 -293 -142 -91 921 548 -12 -257 -819 -1002 -712 -482 -1228 -743 -620 62 521 949 961 795 502 135 -151 39 -214 299 115 -11 97 516 370 572 243 -347 375 216 -125 40 -402 -154 -508 -30 164 -72 498 302 -65 -151 -489 -593 900000 -22 261 -439 -609 -394 -344 39 230 45 -764 -544 -205 -72 276 304 17 485 413 643 581 112 584 608 411 347 245 -169 -266 -433 231 235 889 -81 -1428 -1782 -1254 -1926 -453 -99 -388 -222 -124 -261 116 -64 -383 -306 -544 -485 281 371 606 991 659 857 672 447 194 248 398 1119 1359 2098 1196 -207 -35 -915 140 445 444 886 247 793 257 -196 -853 -1771 -1256 -1095 -1514 -1223 -2226 -1925 -1132 -545 170 416 1079 995 686 312 -508 -404 -297 -157 -105 1100 681 -15 -322 -954 -1138 -805 -567 -1564 -979 -812 84 702 1349 1399 1126 696 180 -185 49 -262 390 155 -16 138 716 496 761 310 -442 455 262 -163 55 -540 -207 -702 -44 242 -110 772 459 -98 -230 -725 -849 SS 20260630T140625.1Z 9677.587790 352 1 54.71 2 51.80 39.00 122.11 222.48 0.00 1 0.00 1 0 17 9.540e-03 7.468e-03 2.905e-04 2.044e-04 1.780704e-01 1.026538e-04 1.897954e-03 -6.000000e+00 5.304931e-03 226.27 -2.00 3.04 -2.00 314.88 0.00e+00 4.394747e-04 8.825695e-06 5.778801e-05 -6.000000e+00 2.415647e-04 288.85 -2.00 20.00 -2.00 314.21 0.00e+00 1.613 0.000 302.00 328.00 3 1.4362e+00 2.6145e-04 1.7188e-02 -6.0000e+00 1.3120e-02 7.3038e-03 2.9035e-04 7.9043e-03 -6.0000e+00 1.4235e-02 -1.1543e-03 1.6719e-04 3.8569e-03 -6.0000e+00 8.5151e-03 -4.0176e-03 7.6011e-05 1.0984e-03 -6.0000e+00 3.7271e-03 2.3055e-02 1.8094e-05 5.3510e-06 1.3079e-05 -6.0000e+00 2.3889e-04 -1.6538e-02 0.0000e+00 11 8 0 10 0 0 99.98 24.74 0.38 -0.01654 -0.01640 2174 210 1 5 0 25.160 33.50 20.00 24.74 26.74 4.9 969.48 900000 -299 801 -1438 -2644 -2084 -1343 95 424 53 -1964 -1635 -566 -464 672 702 167 1087 836 1553 1184 454 1352 1382 944 645 401 -212 -739 -649 841 303 1535 -164 -2898 -3026 -2717 -1817 -863 -206 -445 -452 -137 -264 84 -32 -394 -378 -723 -512 487 550 701 1146 714 881 837 469 387 227 573 1274 1342 2184 1125 -285 -20 -985 212 535 332 701 247 708 213 -420 -783 -2014 -1437 -1370 -1676 -1191 -2161 -1804 -976 -567 90 196 920 832 525 387 -324 -230 -307 -289 -118 871 561 -49 -226 -740 -950 -638 -518 -1166 -717 -577 15 497 868 944 769 593 204 -48 92 -140 293 291 66 68 576 342 541 269 -252 443 261 -32 9 -382 -174 -382 -31 70 -122 454 308 -139 -131 -538 -656 900000 -108 297 -530 -862 -650 -419 32 150 21 -764 -606 -220 -190 305 332 83 540 430 815 606 232 717 719 518 369 235 -119 -380 -331 428 164 822 -96 -1648 -1669 -1472 -1107 -555 -149 -345 -350 -109 -214 67 -26 -312 -301 -557 -382 367 442 565 965 627 746 722 409 331 200 510 1139 1244 2156 1108 -275 -18 -875 186 506 327 727 262 732 210 -394 -715 -1696 -1236 -1240 -1642 -1181 -2253 -1941 -1103 -667 108 236 1122 999 612 442 -349 -237 -320 -316 -137 1025 698 -62 -279 -881 -1086 -725 -624 -1466 -901 -758 20 681 1217 1313 1074 798 259 -58 111 -169 378 381 92 93 777 462 688 338 -311 523 325 -41 12 -516 -236 -512 -43 102 -177 675 469 -209 -190 -788 -930 SS 20260630T141051.8Z 9677.590877 355 1 54.72 2 51.14 38.00 122.79 221.69 0.00 1 0.00 1 0 25 9.552e-03 7.569e-03 1.730e-04 1.267e-04 1.753350e-01 6.373718e-05 1.869140e-03 -6.000000e+00 5.311485e-03 226.27 -2.00 3.04 -2.00 314.66 0.00e+00 4.363847e-04 5.267991e-06 4.623522e-05 -6.000000e+00 2.418607e-04 288.85 -2.00 20.00 -2.00 314.02 0.00e+00 1.590 0.000 302.00 328.00 3 5.4150e-01 1.6202e-04 1.6940e-02 -6.0000e+00 1.3136e-02 2.1405e-03 1.7980e-04 7.7882e-03 -6.0000e+00 1.4252e-02 -9.8666e-04 1.0364e-04 3.7954e-03 -6.0000e+00 8.5256e-03 -3.9502e-03 4.6793e-05 1.0808e-03 -6.0000e+00 3.7317e-03 5.8054e-02 5.9374e-06 3.3112e-06 1.3063e-05 -6.0000e+00 2.3918e-04 -1.6623e-02 0.0000e+00 11 8 0 10 0 0 99.99 24.76 0.35 -0.01662 -0.01658 2526 244 1 5 0 21.660 33.50 20.00 24.76 27.02 4.9 971.51 900000 -173 768 -1399 -2698 -2137 -1374 93 375 142 -2038 -1629 -631 -390 567 760 202 1124 860 1640 1269 489 1359 1365 933 767 515 -165 -693 -597 875 430 1562 -56 -2834 -2879 -2697 -1765 -801 -230 -494 -448 -163 -363 56 -33 -353 -359 -687 -528 542 616 604 1175 706 873 778 528 382 261 609 1251 1345 2131 1125 -279 -99 -1030 183 491 304 652 241 714 158 -425 -804 -1979 -1417 -1456 -1700 -1274 -2125 -1828 -1016 -533 108 167 919 830 557 408 -328 -235 -318 -292 -64 867 574 -14 -219 -724 -925 -643 -571 -1187 -708 -577 5 519 915 973 791 576 191 -62 78 -210 298 294 103 133 590 364 525 292 -295 436 222 -49 15 -351 -165 -385 -33 47 -136 424 305 -125 -135 -538 -665 900000 -66 303 -548 -990 -739 -476 33 149 58 -842 -641 -260 -171 263 391 104 578 457 889 680 262 745 744 537 459 302 -97 -391 -314 459 240 873 -34 -1682 -1633 -1525 -1074 -529 -167 -388 -356 -133 -301 46 -27 -286 -289 -535 -412 427 500 498 1010 612 763 694 476 338 227 535 1118 1260 2060 1130 -272 -92 -902 164 463 304 668 253 729 160 -403 -724 -1700 -1228 -1300 -1659 -1286 -2273 -1962 -1146 -614 128 201 1120 1022 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