File name: Pandora86s1_SantaCruz_20260715_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260716T042242.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260715_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260715T115044.2Z 9692.493568 62 1 24.87 2 76.45 61.80 91.03 68.80 0.00 1 0.00 1 0 17 4.061e-02 7.501e-03 8.071e-03 1.129e-03 4.131275e-01 5.604201e-04 4.281305e-03 -6.000000e+00 2.259384e-02 226.32 -2.00 3.04 -2.00 318.51 0.00e+00 1.436657e-03 1.164142e-04 6.535222e-04 -6.000000e+00 1.026734e-03 288.53 -2.00 20.00 -2.00 317.68 0.00e+00 4.167 0.000 302.00 328.00 3 1.3396e+00 1.5222e-03 4.3522e-02 -6.0000e+00 5.5891e-02 -8.0069e-03 1.7446e-03 1.8664e-02 -6.0000e+00 6.0631e-02 -2.6573e-02 1.2056e-03 9.2255e-03 -6.0000e+00 3.6260e-02 9.5565e-03 6.4562e-04 2.7477e-03 -6.0000e+00 1.5875e-02 1.7331e-03 -1.6585e-04 2.9651e-05 2.6145e-05 -6.0000e+00 1.0165e-03 -2.0558e-02 0.0000e+00 12 9 1 12 1 1 99.86 25.22 0.31 -0.02056 -0.02180 103 22 1 5 0 239.120 33.75 20.00 25.22 26.06 4.9 963.23 900000 -9528 -7773 -12357 -5785 -12252 -20683 -11002 -5674 -15113 -16273 -16408 -12137 -2044 -3477 578 -4284 228 614 -913 1673 -1660 390 448 1270 -1103 -1070 -2200 -4088 -4028 -1508 -2248 2715 -1507 -2831 -6236 -3667 -1302 -1357 301 423 325 751 765 767 1062 421 666 61 -761 318 942 846 1964 1085 1548 993 903 260 96 374 1822 2044 2776 1598 239 604 -745 246 478 474 1010 263 678 101 -820 -1259 -2879 -1910 -1330 -1731 -926 -2102 -1736 -1290 -613 218 218 883 1022 484 364 -467 -520 -607 -494 -194 923 475 -239 -354 -1234 -802 -589 -712 -1507 -781 -497 108 582 1072 929 911 553 143 -238 51 -66 312 143 77 313 748 387 434 188 -379 322 221 -93 -98 -402 -150 -568 -74 136 -46 544 350 -154 -260 -348 -452 900000 -384 -335 -564 -223 -460 -872 -471 -264 -858 -962 -981 -794 -147 -306 58 -500 27 71 -113 211 -217 50 61 187 -176 -178 -361 -640 -615 -244 -418 542 -350 -652 -1376 -831 -304 -384 102 153 126 304 321 323 451 182 285 27 -338 137 448 436 1004 595 871 581 537 153 55 217 1111 1294 1829 1140 167 415 -506 171 358 381 817 218 574 81 -634 -878 -2044 -1377 -1028 -1474 -839 -2030 -1673 -1314 -641 240 241 985 1172 524 380 -476 -506 -621 -542 -219 1122 621 -323 -454 -1528 -934 -669 -885 -1948 -1005 -674 149 833 1612 1479 1447 841 210 -339 70 -95 460 219 121 487 1128 590 628 272 -525 450 322 -145 -159 -669 -249 -977 -132 248 -88 1011 666 -288 -479 -635 -790 SS 20260715T120016.7Z 9692.500193 65 1 54.72 2 74.46 60.79 88.99 68.12 0.00 1 0.00 1 0 25 2.364e-02 7.306e-03 1.674e-03 3.931e-04 3.685652e-01 1.945031e-04 3.822273e-03 -6.000000e+00 1.315093e-02 226.32 -2.00 3.04 -2.00 317.85 0.00e+00 8.055605e-04 3.323787e-05 3.477580e-04 -6.000000e+00 5.976518e-04 288.53 -2.00 20.00 -2.00 317.02 0.00e+00 3.665 0.000 302.00 328.00 3 5.8024e-01 5.1821e-04 3.8334e-02 -6.0000e+00 3.2532e-02 -1.4140e-02 5.8734e-04 1.6484e-02 -6.0000e+00 3.5291e-02 -1.3421e-02 3.7230e-04 8.0569e-03 -6.0000e+00 2.1106e-02 3.8360e-03 1.9413e-04 2.3176e-03 -6.0000e+00 9.2395e-03 6.1761e-03 -1.2010e-04 1.0345e-05 2.2899e-05 -6.0000e+00 5.9173e-04 -2.0022e-02 0.0000e+00 11 8 0 10 0 0 94.65 25.24 0.33 -0.02002 -0.02092 649 63 1 5 0 84.300 33.75 20.00 25.24 26.70 5.0 968.66 900000 -6858 -3200 -6522 -7378 -9024 -10511 -6985 -3988 -5874 -8067 -6984 -4172 -2158 -243 1234 105 1763 1829 2213 1774 967 1729 1893 1279 335 -35 -850 -1905 -2399 -265 -25 1190 -188 -3331 -4539 -3883 -4381 -1084 265 130 84 435 231 591 567 159 231 -337 -513 660 998 873 1510 1088 1205 1016 706 204 87 605 1461 1822 2687 1615 111 278 -889 131 542 381 703 221 541 54 -538 -1082 -2322 -1805 -1503 -1712 -1265 -2023 -1952 -1164 -529 150 209 875 885 633 488 -399 -369 -355 -356 -146 799 541 -142 -420 -860 -1019 -668 -543 -1266 -737 -554 46 558 924 959 725 510 109 -161 92 -118 287 117 31 93 616 421 494 212 -347 418 252 -65 34 -343 -47 -336 -25 66 -95 495 356 -176 -180 -494 -575 900000 -513 -249 -528 -539 -610 -744 -534 -339 -564 -810 -694 -453 -250 -33 192 18 316 320 405 341 187 332 388 284 80 -9 -206 -434 -531 -62 -6 315 -56 -994 -1267 -1133 -1476 -397 109 58 40 214 118 300 291 82 118 -173 -265 355 553 493 907 695 749 653 462 131 55 384 980 1278 2066 1270 85 205 -644 96 433 331 620 200 474 47 -445 -846 -1720 -1352 -1216 -1530 -1164 -1986 -2010 -1213 -572 172 241 1018 1013 706 519 -409 -373 -360 -389 -173 983 717 -187 -543 -1064 -1188 -790 -678 -1598 -965 -740 64 790 1374 1457 1128 756 160 -225 126 -167 418 178 48 140 933 620 712 304 -474 569 359 -97 52 -543 -77 -546 -43 115 -171 885 651 -317 -319 -864 -966 SS 20260715T121055.4Z 9692.507586 68 1 54.70 2 72.26 59.60 86.72 67.32 0.00 1 0.00 1 0 17 1.520e-02 7.193e-03 9.305e-04 2.985e-04 3.289187e-01 1.477979e-04 3.426894e-03 -6.000000e+00 8.458143e-03 226.32 -2.00 3.04 -2.00 317.27 0.00e+00 7.178381e-04 2.158592e-05 2.516131e-04 -6.000000e+00 3.843727e-04 288.53 -2.00 20.00 -2.00 316.44 0.00e+00 3.237 0.000 302.00 328.00 3 4.8075e-01 3.8866e-04 3.3909e-02 -6.0000e+00 2.0923e-02 -1.3341e-02 4.3751e-04 1.4648e-02 -6.0000e+00 2.2698e-02 -7.2691e-03 2.6485e-04 7.1523e-03 -6.0000e+00 1.3574e-02 1.2799e-03 1.3442e-04 2.0515e-03 -6.0000e+00 5.9427e-03 1.0598e-02 -1.5298e-04 7.8647e-06 2.0719e-05 -6.0000e+00 3.8056e-04 -2.0286e-02 0.0000e+00 11 8 0 10 0 0 90.99 25.27 0.34 -0.02029 -0.02144 895 86 1 5 0 61.110 33.75 20.00 25.27 27.23 5.0 972.52 900000 -2372 -515 -2445 -4702 -6639 -5683 -3780 -1826 -2912 -4761 -4509 -2448 -1655 392 1161 130 1424 1251 1681 1292 340 1049 1193 831 637 213 -838 -1747 -2041 -89 -181 1150 -214 -3299 -3939 -3320 -289 -1090 71 -137 -24 154 208 612 451 129 -82 -447 -467 597 863 744 1420 847 945 844 576 231 166 600 1400 1631 2599 1496 -69 189 -944 211 528 442 654 186 615 92 -555 -874 -2043 -1539 -1390 -1729 -1240 -2125 -1942 -1185 -660 85 186 903 912 600 391 -331 -337 -399 -374 -130 811 535 -126 -388 -859 -966 -667 -553 -1255 -754 -556 18 553 907 925 769 510 139 -73 154 -127 323 179 32 132 601 393 514 302 -383 394 247 -84 5 -319 -102 -345 -24 63 -110 504 355 -121 -177 -524 -627 900000 -255 -58 -282 -495 -645 -561 -408 -221 -393 -666 -623 -368 -292 73 249 31 319 297 415 334 89 271 327 245 184 64 -247 -518 -583 -26 -55 382 -79 -1225 -1355 -1192 -107 -462 34 -71 -13 88 116 340 253 73 -46 -260 -271 340 536 471 952 574 655 603 419 165 116 423 1041 1271 2108 1242 -58 145 -736 166 432 394 597 174 557 82 -472 -695 -1599 -1208 -1177 -1554 -1197 -2192 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