File name: Pandora86s1_SantaCruz_20260718_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20260719T042323.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 86 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora86_OF_v3d20231204.txt Instrument calibration file used: Pandora86s1_CF_v2d20240531.txt Level 1 file used: Pandora86s1_SantaCruz_20260718_L1_smca1c2d20240531p1-8.txt Full location name: Santa Cruz de la Sierra Short location name: SantaCruz Country of location: Bolivia Location latitude [deg]: -17.7604 Location longitude [deg]: -63.1994 Location altitude [m]: 408 Local noon date: 20260718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0112 305.1522 305.2931 305.4340 305.5750 305.7159 305.8568 305.9977 306.1386 306.2794 306.4203 306.5611 306.7020 306.8428 306.9836 307.1244 307.2652 307.4060 307.5468 307.6875 307.8283 307.9690 308.1098 308.2505 308.3912 308.5319 308.6726 308.8133 308.9539 309.0946 309.2352 309.3759 309.5165 309.6571 309.7977 309.9383 310.0789 310.2194 310.3600 310.5005 310.6411 310.7816 310.9221 311.0626 311.2031 311.3436 311.4840 311.6245 311.7650 311.9054 312.0458 312.1862 312.3266 312.4670 312.6074 312.7478 312.8881 313.0285 313.1688 313.3091 313.4495 313.5898 313.7301 313.8703 314.0106 314.1509 314.2911 314.4314 314.5716 314.7118 314.8520 314.9922 315.1324 315.2726 315.4127 315.5529 315.6930 315.8331 315.9732 316.1133 316.2534 316.3935 316.5336 316.6736 316.8137 316.9537 317.0938 317.2338 317.3738 317.5138 317.6537 317.7937 317.9337 318.0736 318.2136 318.3535 318.4934 318.6333 318.7732 318.9131 319.0529 319.1928 319.3326 319.4725 319.6123 319.7521 319.8919 320.0317 320.1715 320.3112 320.4510 320.5907 320.7305 320.8702 321.0099 321.1496 321.2893 321.4290 321.5686 321.7083 321.8479 321.9876 322.1272 322.2668 322.4064 322.5460 322.6855 322.8251 322.9647 323.1042 323.2437 323.3832 323.5228 323.6622 323.8017 323.9412 324.0807 324.2201 324.3595 324.4990 324.6384 324.7778 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260718T135153.6Z 9695.577704 136 1 5.66 2 52.91 44.54 91.83 88.64 0.00 1 0.00 1 0 17 9.138e-03 7.255e-03 6.683e-04 4.917e-04 1.753584e-01 2.470947e-04 1.875339e-03 -6.000000e+00 5.085590e-03 226.36 -2.00 3.04 -2.00 314.64 0.00e+00 3.927554e-04 2.035557e-05 4.273831e-05 -6.000000e+00 2.310414e-04 288.51 -2.00 20.00 -2.00 314.01 0.00e+00 1.654 0.000 302.00 328.00 3 9.2525e-01 6.2861e-04 1.7486e-02 -6.0000e+00 1.2582e-02 1.0061e-02 6.9750e-04 7.8165e-03 -6.0000e+00 1.3648e-02 -1.7149e-03 4.0155e-04 3.8094e-03 -6.0000e+00 8.1617e-03 -3.2619e-03 1.8114e-04 1.0834e-03 -6.0000e+00 3.5732e-03 3.7191e-02 -1.0125e-04 1.2827e-05 1.3172e-05 -6.0000e+00 2.2876e-04 -2.0953e-02 0.0000e+00 12 9 1 12 1 1 99.98 25.88 0.36 -0.02095 -0.02171 154 145 1 5 0 36.520 34.25 20.00 25.88 31.91 4.9 1004.76 900000 -302 617 -1407 -2480 -2069 -1214 197 387 67 -1674 -1704 -486 -101 645 879 141 1148 766 1653 1362 285 1326 1331 972 662 658 -105 -676 -677 763 438 1496 21 -2895 -2805 -2557 -1352 -844 -332 -564 -547 -74 -372 46 -59 -479 -357 -825 -570 472 533 535 1184 664 821 695 411 293 194 513 1224 1239 2186 1136 -248 -34 -794 220 391 312 643 205 648 152 -387 -614 -1803 -1212 -1215 -1601 -1201 -2066 -1800 -997 -589 44 147 879 836 530 428 -201 -173 -241 -298 -109 818 549 -97 -224 -626 -879 -661 -550 -1160 -713 -544 -2 471 851 969 748 583 219 -18 38 -211 213 220 -1 34 502 359 533 289 -239 421 233 -40 9 -259 -90 -428 -22 135 -134 445 352 -134 -211 -554 -637 900000 -118 248 -563 -930 -730 -427 70 147 28 -704 -684 -203 -45 303 437 74 600 414 869 741 156 706 737 568 385 392 -60 -371 -363 407 248 849 12 -1678 -1544 -1462 -828 -562 -244 -450 -441 -61 -303 38 -49 -395 -282 -654 -437 364 424 448 997 584 729 609 364 255 172 457 1108 1176 2139 1124 -238 -31 -706 193 361 316 668 212 673 151 -374 -563 -1572 -1025 -1093 -1528 -1225 -2173 -1957 -1105 -687 53 180 1086 1019 622 482 -218 -177 -248 -324 -123 962 689 -121 -270 -741 -989 -738 -656 -1422 -904 -703 -3 626 1168 1363 1025 782 282 -22 46 -255 267 293 -1 46 674 479 687 365 -294 506 287 -50 12 -345 -120 -569 -31 192 -193 652 529 -200 -304 -796 -906 SS 20260718T135538.9Z 9695.580312 139 1 54.69 2 52.29 43.76 90.96 88.38 0.00 1 0.00 1 0 17 9.184e-03 7.189e-03 5.253e-04 3.665e-04 1.731033e-01 1.835208e-04 1.840961e-03 -6.000000e+00 5.111138e-03 226.36 -2.00 3.04 -2.00 314.89 0.00e+00 3.794206e-04 1.584015e-05 5.155552e-05 -6.000000e+00 2.321983e-04 288.51 -2.00 20.00 -2.00 314.22 0.00e+00 1.631 0.000 302.00 328.00 3 2.5869e+00 4.6809e-04 1.7236e-02 -6.0000e+00 1.2645e-02 1.4613e-03 5.1985e-04 7.6946e-03 -6.0000e+00 1.3716e-02 -1.8225e-03 2.9916e-04 3.7522e-03 -6.0000e+00 8.2027e-03 -2.8678e-03 1.3624e-04 1.0657e-03 -6.0000e+00 3.5912e-03 7.2709e-03 -1.2933e-04 9.5918e-06 1.2822e-05 -6.0000e+00 2.2990e-04 -2.1127e-02 0.0000e+00 11 8 0 10 0 0 100.00 25.91 0.35 -0.02113 -0.02210 708 68 2 5 0 77.240 34.25 20.00 25.91 32.10 4.9 1006.67 900000 -418 771 -1273 -2495 -2177 -1305 -33 500 113 -1830 -1684 -450 -337 637 659 -67 1042 768 1470 1345 418 1246 1385 996 722 474 -226 -617 -555 833 412 1502 -32 -2755 -2961 -2843 -287 -1083 -248 -495 -506 -220 -508 -86 -105 -485 -475 -809 -649 356 589 529 1137 643 755 763 528 360 198 563 1229 1338 2073 1140 -266 77 -882 231 521 293 642 163 645 223 -262 -637 -1806 -1248 -1269 -1562 -1201 -2088 -1878 -1034 -658 93 132 913 799 566 504 -305 -197 -310 -314 -26 866 565 17 -227 -682 -804 -618 -451 -1188 -688 -563 -93 427 845 918 771 602 190 -71 59 -226 201 156 74 40 548 369 479 266 -269 409 222 -52 -13 -308 -105 -373 7 87 -74 453 276 -99 -149 -503 -655 900000 -146 276 -454 -848 -656 -391 -11 182 42 -686 -648 -167 -140 276 317 -34 527 376 734 694 216 629 727 551 417 263 -129 -321 -287 428 210 805 -19 -1577 -1544 -1541 -172 -690 -178 -380 -407 -182 -407 -68 -87 -399 -375 -617 -504 278 466 441 940 555 658 677 473 317 172 493 1127 1267 2000 1146 -252 71 -769 199 479 292 648 169 652 225 -253 -573 -1569 -1051 -1119 -1487 -1205 -2197 -2045 -1133 -749 112 160 1119 966 666 561 -322 -198 -314 -332 -29 1021 703 21 -283 -821 -931 -711 -546 -1502 -866 -742 -122 585 1181 1316 1076 812 243 -86 72 -274 260 204 102 55 742 484 614 338 -338 488 278 -68 -17 -417 -143 -500 10 127 -107 669 419 -148 -217 -738 -930 SS 20260718T140251.1Z 9695.585313 145 1 0.51 2 51.12 42.22 89.29 87.88 0.00 1 0.00 1 0 17 9.348e-03 7.380e-03 1.880e-03 1.421e-03 1.699054e-01 7.163136e-04 1.820428e-03 -6.000000e+00 5.202461e-03 226.36 -2.00 3.04 -2.00 314.48 0.00e+00 2.721247e-04 5.715560e-05 4.013712e-05 -6.000000e+00 2.363472e-04 288.51 -2.00 20.00 -2.00 313.87 0.00e+00 1.590 0.000 302.00 328.00 3 6.4415e-01 1.8192e-03 1.6834e-02 -6.0000e+00 1.2871e-02 1.1231e-02 2.0155e-03 7.5687e-03 -6.0000e+00 1.3962e-02 -3.1899e-03 1.1623e-03 3.6950e-03 -6.0000e+00 8.3492e-03 -2.8106e-03 5.2275e-04 1.0447e-03 -6.0000e+00 3.6553e-03 5.2912e-02 -1.3054e-04 3.7009e-05 1.2939e-05 -6.0000e+00 2.3401e-04 -2.1120e-02 0.0000e+00 12 9 1 12 1 1 98.91 25.94 0.39 -0.02112 -0.02210 14 157 1 5 0 33.600 34.25 20.01 25.94 32.48 4.9 1008.71 900000 96 1141 -1792 -3206 -2592 -374 -36 640 931 -1116 -2064 78 -263 1080 915 -34 837 637 1206 1463 539 1385 1165 1018 549 268 -209 -399 -441 573 378 1420 299 -2441 -2623 -2597 -1709 -961 -96 -697 -794 -299 -529 -77 -115 -472 -182 -802 -359 443 575 388 1040 622 1083 877 251 510 42 343 1395 1170 1900 1131 -75 239 -961 158 608 441 742 298 614 211 -292 -807 -1758 -1217 -1280 -1513 -1373 -2089 -2062 -946 -445 41 239 833 769 659 425 -164 126 -310 -351 -144 918 562 -77 25 -777 -629 -595 -491 -1177 -873 -722 6 554 766 775 805 384 50 -70 86 -252 378 147 107 -10 555 30 631 264 -143 599 101 23 -68 -79 -5 -412 20 162 -206 435 300 -255 -155 -453 -650 900000 40 485 -764 -1277 -962 -136 -14 257 405 -493 -878 34 -123 535 482 -18 445 349 675 809 299 780 657 604 327 163 -128 -231 -237 321 214 810 185 -1478 -1507 -1552 -1058 -651 -72 -554 -642 -247 -446 -64 -96 -388 -147 -650 -280 348 467 322 898 544 952 787 228 454 37 304 1255 1109 1866 1123 -72 222 -844 141 572 444 769 309 638 216 -280 -730 -1549 -1039 -1165 -1467 -1390 -2190 -2241 -1047 -506 48 287 1014 945 776 479 -176 130 -315 -378 -162 1078 691 -96 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