File name: Pandora196s1_Sapporo_20220312_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T092845.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220312_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220311T233719.8Z 8105.984257 230 1 47.55 2 62.71 125.04 107.05 24.41 0.00 1 0.00 1 0 17 3.573e-02 5.842e-03 4.650e-03 4.286e-04 3.932056e-01 2.181034e-04 4.714027e-03 -6.000000e+00 2.058756e-02 225.76 -2.00 3.56 -2.00 319.16 0.00e+00 1.705445e-03 5.292081e-05 5.767752e-04 -6.000000e+00 8.835995e-04 274.99 -2.00 20.00 -2.00 318.61 0.00e+00 2.170 0.000 302.00 328.00 3 1.3043e+00 5.9927e-04 2.9837e-02 -6.0000e+00 5.1080e-02 -1.9410e-02 6.9332e-04 2.0417e-02 -6.0000e+00 5.5409e-02 4.4895e-03 5.3935e-04 1.0639e-02 -6.0000e+00 3.2896e-02 -1.0706e-02 2.8772e-04 3.5390e-03 -6.0000e+00 1.4132e-02 9.9365e-03 -3.8253e-04 1.2296e-05 3.5103e-05 -6.0000e+00 9.4717e-04 1.8537e-03 -4.6004e-05 10 0 0 10 0 0 95.06 17.06 0.28 0.00185 -0.00102 914 236 1 5 0 51.950 20.67 15.07 17.06 6.39 12.3 960.47 -8430 -11019 -9000 -12179 -14360 -14677 -12222 -8901 -9971 -8966 -12600 -9699 -6201 -3356 -2891 -1409 -1771 -560 -355 144 342 -436 570 -419 -1136 -2476 -3044 -3720 -2088 -2229 481 156 120 -1563 -4680 -3522 -3112 -1626 -751 -948 -1556 -1212 -680 -449 -103 542 -123 259 -148 336 867 1376 1046 1304 657 729 719 -57 -69 520 1211 2015 2168 2053 1136 138 404 73 1171 1549 457 673 -34 232 -168 -765 -1070 -1761 -1283 -1247 -1658 -1621 -1995 -1573 -552 -311 543 403 695 609 675 403 -339 66 240 140 196 205 -140 -369 -664 -1100 -577 -196 -889 -1255 -558 -578 390 551 616 206 334 59 62 221 532 95 273 -93 41 181 564 302 651 228 -72 463 -52 -116 -307 -527 -217 128 132 8 289 123 68 -101 -78 -687 -200 -299 -253 -341 -403 -402 -347 -277 -352 -336 -493 -390 -287 -181 -184 -102 -137 -46 -31 13 32 -40 54 -43 -125 -287 -359 -419 -222 -241 57 21 18 -248 -708 -525 -510 -308 -171 -255 -463 -378 -220 -147 -34 179 -41 85 -49 114 318 549 444 592 310 354 358 -28 -34 250 599 1081 1275 1312 740 84 236 43 740 1121 327 499 -25 178 -119 -489 -636 -1034 -819 -920 -1257 -1372 -1811 -1488 -557 -333 607 460 787 659 672 373 -294 58 230 151 236 275 -182 -509 -854 -1292 -641 -228 -1131 -1664 -778 -847 556 851 1011 343 536 89 95 320 786 136 416 -149 66 279 843 470 969 326 -99 664 -82 -181 -513 -905 -384 239 263 16 558 243 133 -205 -152 -1289 SS 20220311T234239.8Z 8105.987961 233 1 48.02 2 61.92 126.25 106.65 25.53 0.00 1 0.00 1 0 25 3.354e-01 2.927e-02 2.323e-01 2.339e-02 3.953208e-01 1.215947e-02 5.104089e-03 -6.000000e+00 1.935637e-01 225.76 -2.00 3.56 -2.00 319.30 0.00e+00 1.614467e-03 2.972208e-03 2.197641e-03 -6.000000e+00 8.497790e-03 274.99 -2.00 20.00 -2.00 318.75 0.00e+00 2.114 0.000 302.00 328.00 3 7.3700e+00 3.3412e-02 3.0398e-02 -6.0000e+00 4.7990e-01 1.2583e-01 3.8732e-02 2.2670e-02 -6.0000e+00 5.2090e-01 -5.4937e-02 2.9261e-02 1.1961e-02 -6.0000e+00 3.0886e-01 1.7940e-02 1.5431e-02 3.7238e-03 -6.0000e+00 1.3373e-01 2.2613e-05 4.9159e-04 6.8681e-04 4.4397e-05 -6.0000e+00 9.0296e-03 1.2680e-03 -8.2631e-05 12 8 8 10 0 0 98.17 17.06 1.82 0.00127 0.00496 13 3 1 5 0 3692.700 20.67 14.94 17.06 7.08 12.5 967.79 900000 -27564 91457 -50849 900000 6828 87261 318915 -29374 3222 -60816 -11505 -30905 55959 -53444 2352 -27569 31240 41757 13570 -28753 18902 52418 -17578 42962 -36024 -7113 -14423 17163 -23239 34739 -13277 12674 11136 8407 13183 -7612 -4213 -3296 21693 -4060 24449 -1608 8375 -6683 7903 -447 3469 -4509 -6903 6394 -1486 8105 -9324 13067 -4402 8517 -4793 7952 1943 9684 6703 3502 4328 3701 6506 -4743 504 165 5151 -1440 6520 836 5143 611 23 -7071 -7165 -3350 -6650 -578 -2546 -436 -6176 7782 -3598 3349 -3490 1896 -464 -1287 -705 -4374 -3532 -5565 1747 -1429 2138 -1807 1288 -827 -1095 -2724 -633 1566 -2597 1884 -3640 3023 -989 2893 284 2538 -1752 1084 -2902 581 -225 589 1547 929 3135 -995 2422 -1021 1788 -814 2321 -1016 -768 902 -2573 841 866 1832 -422 231 -1190 890 -2161 269 -874 900000 -1147 2085 -2656 900000 178 1990 7272 -1443 123 -4291 -537 -2055 1898 -6093 179 -2958 2034 2601 1148 -3770 1540 3187 -2245 3241 -6067 -908 -1869 1570 -3186 3060 -2042 1687 1577 1124 1698 -1316 -826 -773 4623 -1222 5795 -513 2440 -2257 2365 -143 1069 -1508 -2426 2127 -582 3052 -4462 5136 -2113 3710 -2323 3339 863 4123 3210 1893 2508 2189 3454 -2712 273 98 3331 -1064 4599 611 3417 389 13 -4079 -4061 -2003 -4740 -435 -2175 -387 -6083 7174 -3939 3587 -4068 2074 -493 -1269 -646 -3879 -3151 -5569 1823 -1693 2721 -2502 1667 -1028 -1237 -2977 -715 1872 -3350 2458 -5260 4381 -1614 4810 487 4089 -2748 1552 -4139 817 -333 925 2502 1503 4794 -1542 3442 -1439 2372 -1059 3087 -1512 -1227 1498 -4528 1480 1600 3570 -869 479 -2549 1846 -4408 519 -1627 SS 20220312T001029.9Z 8106.007291 248 1 47.62 2 57.99 132.87 104.33 31.25 0.00 1 0.00 1 0 17 2.088e-02 5.923e-03 3.340e-03 4.482e-04 3.418662e-01 2.289164e-04 4.159192e-03 -6.000000e+00 1.203565e-02 225.76 -2.00 3.56 -2.00 318.69 0.00e+00 1.325785e-03 4.768526e-05 4.330435e-04 -6.000000e+00 5.163934e-04 275.00 -2.00 20.00 -2.00 318.13 0.00e+00 1.880 0.000 302.00 328.00 3 1.6218e+00 6.1789e-04 2.5929e-02 -6.0000e+00 2.9862e-02 -1.4204e-02 7.0455e-04 1.7760e-02 -6.0000e+00 3.2388e-02 6.0292e-03 5.0290e-04 9.0770e-03 -6.0000e+00 1.9229e-02 -1.1063e-02 2.6692e-04 2.9128e-03 -6.0000e+00 8.2648e-03 1.0267e-02 6.8525e-05 1.2967e-05 3.0011e-05 -6.0000e+00 5.5314e-04 7.4648e-04 3.3338e-05 10 0 0 10 0 0 99.99 17.10 0.26 0.00075 0.00126 1084 280 1 5 0 43.720 20.67 14.95 17.10 8.37 12.3 977.39 -3279 -5781 -4274 -7418 -7398 -7823 -5989 -5206 -4716 -6605 -7574 -6015 -3757 -1922 -1302 -51 -1100 618 409 495 659 -250 1011 -42 -237 -1494 -1615 -2916 -1568 -993 461 610 684 -1286 -3625 -2804 -2875 -1269 -701 -786 -1395 -983 -600 -250 -36 468 -295 188 -228 173 715 1314 953 1168 598 785 643 -124 115 595 1242 1857 1919 1920 891 -28 232 -108 1162 1459 355 597 15 314 -105 -733 -912 -1624 -1240 -1334 -1670 -1679 -2063 -1547 -511 -344 519 416 663 587 603 355 -231 80 253 205 188 215 -96 -405 -694 -1090 -598 -188 -936 -1246 -528 -584 358 582 616 185 372 25 123 224 539 87 284 -62 9 107 567 295 615 244 -28 476 -24 -120 -286 -547 -151 157 201 11 306 116 39 -146 -123 -787 -122 -243 -186 -319 -282 -289 -253 -246 -248 -379 -437 -356 -255 -150 -119 -5 -120 70 49 61 85 -32 131 -6 -35 -233 -254 -439 -221 -139 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