File name: Pandora196s1_Sapporo_20220317_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T093139.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220317_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220317 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220316T222135.4Z 8110.931659 271 1 47.72 2 73.34 108.44 108.00 306.82 0.00 1 0.00 1 0 17 2.346e-01 6.605e-03 1.385e-01 2.962e-03 5.781713e-01 1.591860e-03 6.740118e-03 -6.000000e+00 1.352456e-01 226.00 -2.00 3.56 -2.00 320.75 0.00e+00 3.977688e-03 6.306754e-04 1.043142e-03 -6.000000e+00 5.808978e-03 275.38 -2.00 20.00 -2.00 320.27 0.00e+00 3.435 0.001 302.00 328.00 3 2.9697e+00 4.8885e-03 4.6060e-02 -6.0000e+00 3.3570e-01 2.8179e-02 6.4001e-03 3.1195e-02 -6.0000e+00 3.6409e-01 -1.3247e-02 6.5651e-03 1.8118e-02 -6.0000e+00 2.1616e-01 -5.8118e-03 3.2715e-03 7.7093e-03 -6.0000e+00 9.2827e-02 4.3670e-04 -4.4368e-04 8.5200e-05 8.1082e-05 -6.0000e+00 6.2189e-03 3.1870e-03 -3.8195e-05 11 8 0 10 0 0 99.96 16.98 0.23 0.00319 -0.00015 133 34 1 5 0 358.720 20.56 15.00 16.98 10.70 12.5 1010.00 -111772 -42266 -140867 -22835 -82978 -5077 -20259 -71556 -46351 -87019 -29659 -78461 -1984 -63682 36902 -29945 6106 -12776 15960 -7870 -10386 -9707 -27662 -35 -27058 2358 -29663 -2319 -22897 313 -7319 1062 408 -1589 -1737 -8955 4146 -6015 3879 -5452 2210 -5818 4129 -1910 3922 172 2483 2493 -842 2673 2137 3662 489 5100 559 2818 -1920 503 -1639 337 1211 2250 2927 3438 3064 -92 1376 -709 2701 616 1907 244 350 120 -383 -516 -1611 -1282 -2121 -1031 -2567 -1018 -2358 -1019 -879 -354 143 992 961 773 909 261 -313 -656 566 -619 453 159 528 -284 -557 -1130 -476 -192 -1051 -1034 -846 -274 166 924 319 222 175 -6 -62 121 470 -213 376 -344 209 49 949 -173 665 -8 -280 228 23 27 -287 -582 -396 13 46 91 195 390 90 -81 10 -531 -1082 -244 -2259 -117 -706 -20 -100 -654 -372 -1145 -235 -1102 -17 -1223 344 -622 101 -285 289 -191 -270 -248 -883 -1 -1003 69 -1216 -70 -849 10 -297 46 21 -89 -92 -509 230 -439 314 -576 242 -737 501 -253 495 23 334 347 -126 409 366 689 103 1113 133 682 -501 127 -411 82 306 625 909 1185 1099 -33 474 -255 1043 281 927 125 175 57 -166 -207 -617 -496 -934 -518 -1499 -664 -1682 -753 -698 -297 125 876 841 647 703 191 -220 -481 463 -589 485 188 660 -349 -635 -1196 -467 -196 -1172 -1196 -1040 -347 228 1401 528 378 293 -9 -93 173 689 -329 615 -582 345 78 1448 -262 963 -11 -381 331 36 48 -549 -1162 -804 29 105 216 469 951 216 -185 23 -1124 SS 20220316T223341.3Z 8110.940062 278 1 13.89 2 71.26 110.74 109.71 309.22 0.00 1 0.00 1 0 17 1.282e-01 7.956e-03 1.401e-01 5.688e-03 5.193238e-01 2.961887e-03 6.190632e-03 -6.000000e+00 7.391867e-02 226.00 -2.00 3.56 -2.00 319.86 0.00e+00 2.911104e-03 9.171491e-04 1.266047e-03 -6.000000e+00 3.174341e-03 275.38 -2.00 20.00 -2.00 319.36 0.00e+00 3.075 0.001 302.00 328.00 3 4.2143e+00 8.4353e-03 4.1139e-02 -6.0000e+00 1.8348e-01 3.7479e-02 1.0207e-02 2.7526e-02 -6.0000e+00 1.9897e-01 -1.1218e-02 9.2827e-03 1.5247e-02 -6.0000e+00 1.1813e-01 -5.5904e-03 4.8520e-03 5.7669e-03 -6.0000e+00 5.0747e-02 1.8843e-04 -4.7383e-05 1.5866e-04 6.0325e-05 -6.0000e+00 3.3967e-03 2.0364e-03 -4.3040e-06 12 9 1 12 1 1 97.26 17.00 0.33 0.00204 0.00168 5 5 1 5 0 2279.330 20.56 14.93 17.00 11.18 12.4 1013.44 -33397 6050 -27076 -70177 -13989 -41927 -11927 -71355 -49642 -12150 -26443 -43279 -20883 -23031 -14261 -21489 4403 -10315 -12867 14960 -11291 9272 3903 -7537 -6403 -10410 -8488 -5367 -4961 -5326 -6595 -3368 296 -641 809 -2198 618 -655 -3766 1202 -1194 239 1256 -2816 1884 -348 -4083 568 -1241 -363 3856 3897 2348 1978 1465 1771 1258 -567 395 616 1265 1221 2960 2752 1659 633 1389 945 2168 1049 236 179 -597 -557 -1194 -1137 -3616 -2387 -2883 -1647 -2584 -1683 -1582 -1493 -745 772 1022 671 860 1137 906 369 67 -418 24 -84 241 415 433 -333 -408 -1469 -1504 24 -1085 -1631 -561 -401 716 1170 733 441 554 -271 298 -583 454 9 821 -290 -72 464 746 -210 27 687 -299 286 -423 -43 -754 -913 -54 120 194 143 -82 62 451 -233 208 -416 -358 51 -337 -1317 -139 -533 -122 -1464 -937 -174 -448 -940 -458 -635 -444 -852 148 -442 -607 570 -574 384 178 -418 -376 -668 -544 -326 -294 -332 -488 -278 27 -63 73 -206 62 -79 -567 204 -227 48 261 -622 406 -79 -951 131 -300 -91 1010 1132 744 672 521 649 476 -216 145 228 484 509 1335 1375 861 313 670 465 1162 639 154 121 -400 -357 -714 -615 -1913 -1252 -1674 -1080 -1922 -1364 -1361 -1346 -709 758 1051 697 894 1124 850 329 58 -368 23 -89 282 533 582 -439 -510 -1712 -1667 27 -1326 -2054 -734 -549 1042 1803 1198 737 912 -430 449 -862 679 14 1320 -481 -119 740 1167 -320 40 981 -414 417 -671 -72 -1350 -1679 -101 234 395 300 -174 133 959 -478 414 -805 SS 20220316T225155.9Z 8110.952730 287 1 7.43 2 68.18 114.32 112.18 312.98 0.00 1 0.00 1 0 17 6.399e-02 6.595e-03 4.922e-02 3.852e-03 4.534091e-01 1.978191e-03 5.422295e-03 -6.000000e+00 3.690316e-02 226.00 -2.00 3.56 -2.00 319.12 0.00e+00 2.281450e-03 4.827276e-04 5.538776e-04 -6.000000e+00 1.584882e-03 275.38 -2.00 20.00 -2.00 318.58 0.00e+00 2.667 0.000 302.00 328.00 3 3.5656e+00 5.4260e-03 3.5611e-02 -6.0000e+00 9.1600e-02 2.1047e-02 6.2898e-03 2.3593e-02 -6.0000e+00 9.9339e-02 -1.0452e-02 4.9905e-03 1.2317e-02 -6.0000e+00 5.8979e-02 -2.8264e-03 2.6687e-03 4.3633e-03 -6.0000e+00 2.5332e-02 5.8284e-04 -2.1050e-04 1.0758e-04 4.2287e-05 -6.0000e+00 1.6961e-03 3.0721e-03 4.0612e-06 12 9 1 12 1 1 20.34 17.03 0.22 0.00307 0.00149 7 14 1 5 0 905.650 20.67 14.93 17.03 11.05 12.5 1012.31 -22969 -7042 -6337 -25717 -25871 -11309 2148 -18014 -15703 -31264 -15706 -31515 -8328 -15862 5666 -620 2578 -1574 3592 -2147 -843 -1747 -385 3816 -8401 -3570 -1411 -3764 -2979 -1483 -333 220 -1546 54 -3738 -6443 -2872 -1087 2021 -1948 -132 -2386 383 549 1025 1029 -20 679 -265 1470 -838 1427 913 1579 909 883 541 -656 478 1114 1236 1094 2674 1379 1344 97 468 -948 1625 1675 505 7 37 231 -469 -241 -1732 -1831 -1568 -1182 -1274 -1267 -1942 -1597 27 144 212 737 561 274 842 -349 -249 -589 790 -185 254 207 34 -644 -471 -1013 -644 457 -695 -1452 -775 -521 158 864 661 413 695 -97 392 -304 327 -350 71 239 480 65 490 80 608 192 -68 340 -174 -303 53 -497 -295 -46 -49 67 531 201 115 -346 74 -727 -511 -151 -144 -689 -638 -235 42 -485 -464 -1134 -509 -1286 -328 -799 286 -38 165 -114 263 -174 -70 -148 -33 342 -906 -384 -151 -393 -299 -151 -38 29 -230 8 -563 -995 -474 -202 443 -511 -38 -735 120 175 326 334 -6 224 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