File name: Pandora196s1_Sapporo_20220515_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T103026.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220515_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220514T202136.2Z 8169.848335 219 1 47.54 2 78.96 74.54 110.26 271.38 0.00 1 0.00 1 0 17 6.098e-01 1.147e-02 2.213e-01 3.919e-03 7.732055e-01 2.216106e-03 9.154692e-03 -6.000000e+00 3.581755e-01 230.93 -2.00 3.56 -2.00 321.61 0.00e+00 6.182516e-03 1.176182e-03 4.819817e-03 -6.000000e+00 1.551910e-02 281.95 -2.00 20.00 -2.00 321.14 0.00e+00 5.036 0.002 302.00 328.00 3 1.5537e+00 7.9921e-03 6.8848e-02 -6.0000e+00 8.9751e-01 2.2737e-01 1.1915e-02 5.0250e-02 -6.0000e+00 9.6884e-01 -3.0380e-01 1.2683e-02 3.0714e-02 -6.0000e+00 5.7515e-01 1.1418e-01 5.8327e-03 1.1565e-02 -6.0000e+00 2.4587e-01 3.1321e-04 -5.5729e-04 1.0667e-04 1.6232e-04 -6.0000e+00 1.6193e-02 2.8270e-03 -7.5954e-05 12 8 8 10 0 0 99.80 17.88 0.34 0.00283 -0.00136 143 37 1 5 0 332.340 21.48 15.00 17.88 15.54 13.2 971.59 -109555 -231720 -139308 -194561 -204653 -188284 -232146 -135099 -226900 -46678 -242110 -115440 -188002 -57561 -130925 -44240 -68613 -44020 -28743 -65193 -9322 -70611 -21378 -96113 -21913 -83625 -12289 -64112 -3196 -58629 -4204 -1192 -893 -5691 -22586 3872 -26146 9418 -14567 19821 -10149 17626 1691 15733 10947 10320 4087 11815 12526 2059 14680 660 13717 4913 14320 2484 9340 6471 4197 5079 4341 8987 6009 8417 2070 7661 331 6695 2635 7272 3197 4317 3502 617 1528 -2928 -1170 -5944 865 -2249 568 -1735 -1107 -2779 32 -184 930 1112 606 728 -783 983 -3035 -1147 -2623 -148 -872 600 -579 -280 -1172 -1682 -540 -743 -961 -2340 -85 -1689 409 198 909 -212 365 -410 -492 238 507 729 131 612 159 1028 750 1015 435 293 -509 344 127 -6 40 -915 -182 -44 137 -266 544 117 297 -380 95 -881 -419 -2576 -677 -1622 -1706 -1308 -2661 -657 -3074 -178 -4373 -750 -3069 -374 -2092 -406 -918 -521 -318 -1096 -93 -1268 -245 -2534 -293 -2173 -160 -1372 -38 -1344 -71 -24 -21 -152 -673 89 -899 270 -651 750 -582 822 98 818 606 599 261 740 833 165 1178 69 1378 593 1658 337 1217 856 548 652 586 1301 1029 1608 447 1525 72 1440 664 2037 1008 1392 1105 187 414 -744 -282 -1576 250 -811 232 -835 -579 -1557 19 -114 598 726 394 451 -458 538 -1698 -676 -1819 -118 -810 631 -664 -313 -1225 -1567 -458 -653 -915 -2349 -89 -1948 518 286 1314 -325 557 -608 -765 358 782 1176 225 967 269 1634 1160 1505 628 410 -701 519 222 -11 80 -1930 -404 -106 348 -704 1441 315 785 -950 221 -1941 SS 20220514T202717.5Z 8169.852285 222 1 47.71 2 77.96 75.46 111.27 272.31 0.00 1 0.00 1 0 17 5.274e-01 9.355e-03 2.578e-01 4.807e-03 7.226745e-01 2.758155e-03 8.623519e-03 -6.000000e+00 3.115702e-01 230.93 -2.00 3.56 -2.00 321.58 0.00e+00 7.952194e-03 1.418569e-03 3.781700e-03 -6.000000e+00 1.360909e-02 281.95 -2.00 20.00 -2.00 321.08 0.00e+00 4.648 0.002 302.00 328.00 3 2.0850e+00 9.8306e-03 6.2729e-02 -6.0000e+00 7.7997e-01 1.5180e-01 1.4226e-02 4.3737e-02 -6.0000e+00 8.4212e-01 -1.8412e-01 1.5022e-02 2.8196e-02 -6.0000e+00 4.9878e-01 6.5184e-02 6.9939e-03 1.2403e-02 -6.0000e+00 2.1269e-01 2.7806e-04 -7.6331e-04 1.3679e-04 1.6987e-04 -6.0000e+00 1.4011e-02 2.6445e-03 -8.9741e-05 12 8 8 10 0 0 99.95 17.89 0.20 0.00264 -0.00309 179 46 1 5 0 266.490 21.58 15.00 17.89 15.82 13.2 973.59 -240938 -110199 -205818 -129022 -230228 900000 -232860 -131915 -84722 -76566 -115970 -187139 -102587 -92514 -41497 -83221 -6047 -56986 -13107 -39225 36966 -58971 -9485 -47325 -41547 -41647 -65647 -7775 -68130 8362 -42900 12515 -23313 15510 -25353 11677 -10657 -8432 -4172 -8653 -299 288 7474 750 11713 -4834 11927 646 13125 1141 4041 5439 5763 6961 1924 9005 2108 6475 816 5364 2782 5453 3148 9600 6094 3081 4358 2484 5024 2782 3289 1353 1881 -444 373 -2936 -1852 -2267 -1866 -1162 -1822 -806 -2098 -1114 -1097 -255 -731 1692 1051 1651 224 -159 -1389 -1800 -731 -857 -165 130 544 -643 -314 -2213 -400 -982 -997 -1866 -940 -878 475 691 145 139 -54 -215 -486 239 177 485 686 283 368 724 1159 258 745 41 -147 68 318 -365 -243 -756 -214 153 69 -57 327 385 -70 -133 -10 -662 -2874 -516 -2280 -660 -2943 900000 -3175 -731 -397 -359 -761 -2631 -830 -907 -350 -1205 -51 -825 -134 -551 277 -1030 -116 -827 -726 -763 -1566 -113 -1684 118 -1151 258 -735 400 -843 296 -341 -313 -181 -468 -17 17 443 49 704 -358 772 50 945 100 389 584 673 881 269 1216 313 910 118 738 411 883 597 1943 1350 683 965 584 1291 850 1080 469 632 -143 108 -787 -472 -604 -572 -427 -783 -393 -1130 -625 -662 -162 -488 1123 696 1038 133 -90 -772 -1070 -495 -680 -150 135 605 -708 -319 -2041 -335 -855 -939 -1842 -983 -987 586 962 224 225 -87 -333 -716 340 259 740 1108 468 591 1102 1702 368 1020 54 -192 96 517 -671 -489 -1610 -481 365 177 -150 875 1042 -189 -335 -23 -1482 SS 20220514T203700.4Z 8169.859033 228 1 47.49 2 76.23 77.02 113.00 273.91 0.00 1 0.00 1 0 17 3.884e-01 1.182e-02 3.133e-01 9.175e-03 6.427465e-01 5.122444e-03 7.601514e-03 -6.000000e+00 2.295983e-01 230.93 -2.00 3.56 -2.00 321.08 0.00e+00 3.786178e-03 2.289462e-03 2.692059e-03 -6.000000e+00 1.003098e-02 281.95 -2.00 20.00 -2.00 320.54 0.00e+00 4.105 0.001 302.00 328.00 3 4.2420e+00 1.6783e-02 5.5030e-02 -6.0000e+00 5.7547e-01 1.4499e-01 2.2680e-02 3.7832e-02 -6.0000e+00 6.2144e-01 -1.3306e-01 2.2739e-02 2.1281e-02 -6.0000e+00 3.6773e-01 4.6414e-02 1.0966e-02 7.4092e-03 -6.0000e+00 1.5681e-01 5.7666e-05 -6.0535e-04 2.6128e-04 9.8199e-05 -6.0000e+00 1.0424e-02 2.3805e-03 -8.5740e-05 12 8 8 10 0 0 99.87 17.91 0.15 0.00238 -0.00217 18 5 1 5 0 2637.570 21.58 15.00 17.91 16.18 13.1 976.02 -38881 -3029 -133814 -163450 -84294 -85736 900000 -156438 -23500 -139344 -82344 -151274 900000 -124200 171087 -53964 14442 -2197 8043 -8056 17964 -32446 -21714 73524 -56379 -10568 -27234 -13790 -31644 28811 31471 -11888 -3168 -2280 -10373 -20631 9196 -13873 25431 -10699 19184 -2841 10943 16717 11042 -3093 9255 377 547 10787 -2209 11253 -4938 11701 2188 16547 -69 933 -3097 3101 965 163 5520 6525 2689 494 6180 -3739 4260 -787 2116 -453 1915 -36 604 -1208 -688 -3013 -4712 -954 -4449 404 -2213 -55 -2139 1418 547 1417 1026 173 1719 -818 -937 -3211 -397 -2764 801 446 289 -647 -1463 -1548 580 -89 -779 -1349 -1063 366 -624 2026 349 575 -228 478 -322 497 602 284 155 -414 530 14 1802 -1227 1091 -657 -473 -100 397 212 -497 -232 -518 270 218 -59 -555 545 -380 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