File name: Pandora196s1_Sapporo_20220525_L2Fit_fout2c10d20220307p1-8.txt File generation date: 20250121T103257.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v10d20220307.txt Level 1 file used: Pandora196s1_Sapporo_20220525_L1_smca1c10d20220307p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20220525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0528 305.1941 305.3353 305.4766 305.6178 305.7590 305.9003 306.0415 306.1826 306.3238 306.4650 306.6062 306.7473 306.8884 307.0296 307.1707 307.3118 307.4529 307.5940 307.7350 307.8761 308.0172 308.1582 308.2992 308.4402 308.5813 308.7223 308.8632 309.0042 309.1452 309.2861 309.4271 309.5680 309.7089 309.8498 309.9907 310.1316 310.2725 310.4134 310.5542 310.6951 310.8359 310.9767 311.1176 311.2584 311.3992 311.5399 311.6807 311.8215 311.9622 312.1030 312.2437 312.3844 312.5251 312.6658 312.8065 312.9472 313.0878 313.2285 313.3691 313.5097 313.6504 313.7910 313.9316 314.0721 314.2127 314.3533 314.4938 314.6344 314.7749 314.9154 315.0559 315.1964 315.3369 315.4774 315.6179 315.7583 315.8987 316.0392 316.1796 316.3200 316.4604 316.6008 316.7412 316.8815 317.0219 317.1622 317.3026 317.4429 317.5832 317.7235 317.8638 318.0040 318.1443 318.2846 318.4248 318.5650 318.7053 318.8455 318.9857 319.1258 319.2660 319.4062 319.5463 319.6865 319.8266 319.9667 320.1068 320.2469 320.3870 320.5271 320.6672 320.8072 320.9472 321.0873 321.2273 321.3673 321.5073 321.6473 321.7873 321.9272 322.0672 322.2071 322.3470 322.4870 322.6269 322.7667 322.9066 323.0465 323.1864 323.3262 323.4660 323.6059 323.7457 323.8855 324.0253 324.1651 324.3048 324.4446 324.5843 324.7241 324.8638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220524T201402.6Z 8179.843085 137 1 47.34 2 78.97 71.65 57.03 138.23 0.00 1 0.00 1 0 17 5.057e-01 1.938e-02 3.798e-01 1.190e-02 7.447718e-01 6.895773e-03 9.236509e-03 -6.000000e+00 2.984409e-01 231.59 -2.00 3.56 -2.00 321.62 0.00e+00 5.309719e-04 3.544868e-03 8.065949e-03 -6.000000e+00 1.373369e-02 282.98 -2.00 20.00 -2.00 321.11 0.00e+00 5.038 0.002 302.00 328.00 3 3.6117e+00 2.4773e-02 7.7968e-02 -6.0000e+00 7.4831e-01 3.3726e-01 3.4876e-02 7.2137e-02 -6.0000e+00 8.0746e-01 -4.6818e-01 3.4027e-02 3.1039e-02 -6.0000e+00 4.7885e-01 1.8089e-01 1.5768e-02 6.8403e-03 -6.0000e+00 2.0540e-01 4.1246e-05 -6.4717e-04 3.3868e-04 1.2719e-04 -6.0000e+00 1.3559e-02 3.0027e-03 -5.9164e-05 12 8 8 10 0 0 58.32 18.11 0.68 0.00300 -0.00186 18 5 1 5 0 2629.480 21.79 15.00 18.11 21.43 13.4 1002.47 -40508 -175075 36746 73627 900000 -75032 -143522 -138733 -164612 7539 -213300 900000 -172001 202794 -129198 48598 -20396 28519 95471 -94700 900000 -97931 900000 -42006 -1063 -68864 -29989 -94945 32778 -78453 45625 3443 17000 15708 -19355 93145 -20857 91909 -9818 34419 2634 49150 -9036 38924 17270 37919 31064 14658 28039 15515 27043 -3881 42474 -5799 22350 5942 15723 9485 10610 15132 2769 17811 9600 17975 4388 17536 -1453 17449 -1926 9876 2544 4865 1456 1958 5283 -1918 7522 -10287 -923 -4617 1747 -3436 2107 -3614 -864 502 0 2536 -143 1276 -763 1511 -6677 48 -6092 1342 -2631 366 632 -1614 -4163 -2287 -2420 -3003 8 -2770 -40 -1285 934 702 2245 -1731 1040 -81 289 561 57 1177 -143 1587 -908 2105 1145 1960 -135 681 -852 -118 496 -431 458 -457 -283 -573 510 -215 410 231 -74 198 181 -1616 -470 -2538 426 854 900000 -870 -1664 -1609 -2722 87 -6386 900000 -4860 2352 -3829 564 -277 331 1107 -3315 900000 -3536 900000 -1021 -18 -2473 -736 -4256 410 -3132 667 89 445 450 -735 1167 -887 1535 -547 1471 173 2200 -742 2040 1100 2049 1823 1057 1866 1259 2202 -476 3635 -865 2653 867 2188 1357 1469 1962 418 2570 1706 3323 977 3311 -336 3489 -524 2776 831 1608 484 604 1426 -497 1734 -2939 -271 -1691 697 -1658 1050 -2012 -503 305 0 1608 -92 773 -439 824 -3865 28 -4225 1010 -2375 368 679 -1738 -4264 -2048 -2007 -2597 7 -2693 -40 -1418 1125 960 3282 -2758 1610 -122 421 793 84 1782 -232 2587 -1474 3155 1682 2746 -186 907 -1144 -169 813 -800 908 -967 -635 -1376 1277 -562 1076 617 -194 499 426 -3637 SS 20220524T201956.2Z 8179.847178 140 1 47.11 2 77.94 72.59 56.31 139.72 0.00 1 0.00 1 0 17 5.039e-01 1.608e-02 3.208e-01 1.024e-02 6.882368e-01 5.876178e-03 8.611447e-03 -6.000000e+00 2.989512e-01 231.59 -2.00 3.56 -2.00 321.43 0.00e+00 3.650306e-03 2.916077e-03 6.374694e-03 -6.000000e+00 1.411844e-02 282.99 -2.00 20.00 -2.00 320.90 0.00e+00 4.643 0.002 302.00 328.00 3 3.9285e+00 2.0529e-02 6.7085e-02 -6.0000e+00 7.5181e-01 1.9211e-01 2.8510e-02 5.5117e-02 -6.0000e+00 8.1210e-01 -3.0753e-01 2.8244e-02 2.7156e-02 -6.0000e+00 4.7909e-01 1.2713e-01 1.3257e-02 6.9885e-03 -6.0000e+00 2.0543e-01 4.7237e-05 -5.0052e-04 2.9551e-04 1.3741e-04 -6.0000e+00 1.3529e-02 2.5250e-03 -4.2089e-05 12 8 8 10 0 0 94.39 18.12 0.55 0.00252 -0.00124 15 4 1 5 0 3140.140 21.79 15.00 18.12 21.48 13.4 1002.99 -204099 -229688 900000 -129385 -1789 -142846 900000 -213673 -162879 900000 -205052 900000 -143333 900000 -77856 30549 -68183 -14817 29309 -29515 -41729 136753 67056 -985 91327 -30045 -36440 -49965 -8304 -34861 50027 -26922 -6655 -467 -12645 16895 -5993 5578 -9148 24614 -7648 43878 3594 28397 -899 15753 1576 27333 10864 13691 17075 7991 20508 1486 20337 -521 11276 -2283 10173 2589 10589 7781 6353 13027 3263 13840 2495 5415 1056 8254 -3004 3317 111 4588 -3015 -4251 119 -254 -3758 -1661 3096 -3837 -2438 -2508 -1071 1110 -601 1322 2113 -1799 2558 -41 -3498 -1437 -2973 792 -3627 1832 -951 -162 -2308 -2278 -197 -547 -2037 -2201 3 -1371 1168 -240 1172 -512 1478 -1655 749 -95 1067 913 819 -103 572 1485 461 1098 455 722 -48 113 -643 270 -60 -950 -561 -16 370 133 982 -315 -192 -332 396 -1108 -3308 -5463 900000 -1291 -18 -1425 900000 -4939 -2568 900000 -5454 900000 -3021 900000 -1400 305 -1505 -217 302 -564 -930 1364 669 -16 911 -752 -986 -1495 -166 -961 744 -992 -232 -17 -483 479 -237 233 -534 1240 -584 2173 281 1768 -76 1157 136 1899 936 1229 1662 958 2356 226 2689 -88 1747 -400 1522 414 1649 1389 1281 2822 817 3003 610 1335 304 2570 -1112 1195 41 1516 -977 -1249 32 -71 -1241 -644 1325 -2013 -1373 -1490 -675 726 -420 906 1450 -1227 1551 -24 -2072 -883 -2124 635 -3431 1875 -1073 -177 -2396 -2150 -169 -490 -2006 -2258 3 -1573 1449 -340 1770 -819 2300 -2553 1087 -135 1539 1382 1319 -171 922 2262 690 1593 642 983 -64 164 -1057 489 -118 -1972 -1227 -37 899 335 2491 -821 -492 -804 911 -2434 SS 20220524T202520.2Z 8179.850928 143 1 47.77 2 77.00 73.45 55.68 141.12 0.00 1 0.00 1 0 17 6.051e-01 1.234e-02 2.585e-01 5.178e-03 6.592117e-01 2.913141e-03 8.042232e-03 -6.000000e+00 3.583910e-01 231.59 -2.00 3.56 -2.00 321.27 0.00e+00 5.282149e-03 1.391515e-03 4.429488e-03 -6.000000e+00 1.584425e-02 282.99 -2.00 20.00 -2.00 320.73 0.00e+00 4.329 0.001 302.00 328.00 3 3.0864e+00 9.9375e-03 5.9381e-02 -6.0000e+00 8.9831e-01 1.1539e-01 1.3724e-02 4.3624e-02 -6.0000e+00 9.6914e-01 -1.7840e-01 1.3816e-02 2.4879e-02 -6.0000e+00 5.7448e-01 6.6588e-02 6.5555e-03 8.4407e-03 -6.0000e+00 2.4637e-01 1.5180e-04 -5.4949e-04 1.4791e-04 1.3196e-04 -6.0000e+00 1.6069e-02 2.3035e-03 -3.0748e-05 12 8 8 10 0 0 77.57 18.13 0.42 0.00230 -0.00183 46 12 1 5 0 1038.350 21.79 15.00 18.13 21.65 13.4 1004.53 -199383 900000 -205874 74959 -207965 900000 -133738 116521 -82080 -151532 -31918 -133805 178050 -131689 422639 -103063 28057 -46250 47518 -31503 38628 2423 -11069 -2860 -39555 47148 -72660 43604 -66311 90445 -42848 35228 -12893 10314 4784 3081 16096 -4564 8956 -7313 19344 -8912 15626 -7533 20369 610 15017 2954 8452 6286 7102 9281 4405 14670 -869 10501 -2363 6221 -2403 4637 -2956 5913 6411 5141 6782 1320 6827 -990 5705 897 4433 98 3275 -734 1376 -618 -2712 -1665 -4050 -413 -3933 120 -3745 -686 -1979 1024 122 1718 502 1275 546 -166 -1179 -1798 114 -1341 -533 -744 613 -1299 160 -2638 -44 -914 -1330 -1465 -829 -613 235 1164 -242 553 -372 236 -805 565 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