File name: Pandora196s1_Sapporo_20221023_L2Fit_fout2c1d20220907p1-8.txt File generation date: 20250121T125912.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 196 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora196_OF_v3d20210122.txt Instrument calibration file used: Pandora196s1_CF_v1d20220907.txt Level 1 file used: Pandora196s1_Sapporo_20221023_L1_smca1c1d20220907p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20221023 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 207 348 Nominal wavelengths inside fitting window [nm]: 305.0502 305.1915 305.3327 305.4740 305.6153 305.7565 305.8977 306.0389 306.1802 306.3214 306.4625 306.6037 306.7449 306.8860 307.0272 307.1683 307.3094 307.4506 307.5917 307.7327 307.8738 308.0149 308.1560 308.2970 308.4380 308.5791 308.7201 308.8611 309.0021 309.1431 309.2840 309.4250 309.5659 309.7069 309.8478 309.9887 310.1296 310.2705 310.4114 310.5523 310.6932 310.8340 310.9748 311.1157 311.2565 311.3973 311.5381 311.6789 311.8197 311.9604 312.1012 312.2419 312.3827 312.5234 312.6641 312.8048 312.9455 313.0861 313.2268 313.3675 313.5081 313.6487 313.7894 313.9300 314.0706 314.2112 314.3517 314.4923 314.6329 314.7734 314.9139 315.0545 315.1950 315.3355 315.4760 315.6164 315.7569 315.8974 316.0378 316.1782 316.3187 316.4591 316.5995 316.7399 316.8802 317.0206 317.1610 317.3013 317.4416 317.5820 317.7223 317.8626 318.0029 318.1431 318.2834 318.4237 318.5639 318.7041 318.8444 318.9846 319.1248 319.2649 319.4051 319.5453 319.6854 319.8256 319.9657 320.1058 320.2459 320.3860 320.5261 320.6662 320.8063 320.9463 321.0864 321.2264 321.3664 321.5064 321.6464 321.7864 321.9264 322.0663 322.2063 322.3462 322.4861 322.6261 322.7660 322.9059 323.0457 323.1856 323.3255 323.4653 323.6052 323.7450 323.8848 324.0246 324.1644 324.3042 324.4439 324.5837 324.7234 324.8632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221023T031859.3Z 8331.138186 367 1 48.55 2 56.14 197.78 54.54 233.14 0.00 1 0.00 1 0 17 1.239e-02 6.322e-03 7.582e-04 2.083e-04 2.628353e-01 1.059066e-04 3.258668e-03 -6.000000e+00 7.122796e-03 224.91 -2.00 3.56 -2.00 317.60 0.00e+00 7.173529e-04 1.652440e-05 2.436344e-04 -6.000000e+00 3.146206e-04 281.49 -2.00 20.00 -2.00 316.92 0.00e+00 1.789 0.000 302.00 328.00 3 6.1070e-01 2.7867e-04 2.2424e-02 -6.0000e+00 1.7600e-02 6.6175e-03 3.1359e-04 1.3616e-02 -6.0000e+00 1.9074e-02 4.3680e-03 1.9415e-04 6.7966e-03 -6.0000e+00 1.1376e-02 -9.6227e-03 9.9022e-05 1.9950e-03 -6.0000e+00 4.9305e-03 3.5028e-02 1.1676e-04 5.9868e-06 2.1282e-05 -6.0000e+00 3.2787e-04 -2.9869e-03 1.5382e-05 10 0 0 10 0 0 99.87 17.22 0.29 -0.00299 -0.00211 1975 509 1 5 0 23.860 21.48 15.00 17.22 17.96 17.2 932.24 -679 -2735 -2308 -4796 -4461 -3849 -2250 -1541 -989 -2938 -3941 -3299 -1000 -721 259 316 -342 940 697 1245 898 297 1102 1057 401 115 -800 -1337 -450 -22 1282 740 916 -1099 -3583 -2450 -2113 -1161 -254 -595 -1029 -708 -287 -211 -25 371 -458 8 -523 217 638 1127 740 1130 464 809 779 147 189 630 1144 1658 1779 1563 700 -265 149 -187 1180 1341 214 607 10 329 -104 -646 -885 -1442 -1156 -1193 -1805 -1688 -2165 -1562 -527 -399 434 274 630 420 555 290 -161 213 453 136 185 261 -107 -397 -659 -942 -602 -10 -906 -1261 -562 -542 372 673 713 289 447 107 154 295 591 127 311 -77 -107 45 520 269 690 301 -2 658 37 -60 -282 -516 -202 221 192 13 254 104 -13 -248 -155 -804 -58 -259 -225 -457 -409 -335 -202 -154 -110 -353 -471 -397 -134 -110 45 61 -69 195 151 277 207 68 253 258 104 31 -217 -343 -107 -5 314 197 263 -338 -1035 -688 -648 -410 -107 -293 -504 -361 -150 -112 -13 195 -237 4 -287 119 368 634 438 706 299 530 521 98 123 409 762 1188 1376 1291 581 -202 106 -131 873 1135 197 579 9 299 -89 -492 -679 -1064 -904 -966 -1634 -1687 -2310 -1727 -571 -460 524 339 772 494 654 314 -160 208 476 159 218 340 -147 -529 -821 -1081 -719 -12 -1146 -1663 -777 -781 560 996 1106 450 717 159 211 384 779 176 464 -122 -170 70 786 388 947 396 -2 845 52 -90 -440 -820 -328 375 320 23 449 188 -23 -435 -262 -1318 SS 20221023T040349.7Z 8331.169325 395 1 23.60 2 59.49 210.17 61.50 243.14 0.00 1 0.00 1 0 17 2.406e-02 7.826e-03 1.613e-02 3.585e-03 2.881112e-01 1.821738e-03 3.521955e-03 -6.000000e+00 1.384569e-02 224.91 -2.00 3.56 -2.00 317.92 0.00e+00 1.267623e-03 3.130297e-04 3.034283e-04 -6.000000e+00 6.112374e-04 281.48 -2.00 20.00 -2.00 317.24 0.00e+00 1.961 0.000 302.00 328.00 3 5.1880e+00 4.8310e-03 2.4538e-02 -6.0000e+00 3.4213e-02 3.8931e-02 5.4614e-03 1.4851e-02 -6.0000e+00 3.7068e-02 3.8993e-03 3.4932e-03 7.4826e-03 -6.0000e+00 2.2110e-02 -9.3422e-03 1.8077e-03 2.3769e-03 -6.0000e+00 9.5890e-03 2.8700e-04 8.0150e-04 1.0318e-04 2.3513e-05 -6.0000e+00 6.3640e-04 -4.2030e-03 1.3824e-04 12 9 1 12 1 1 99.98 17.22 0.28 -0.00420 0.00182 12 7 1 5 0 1801.660 21.48 15.00 17.22 16.73 17.3 923.03 6334 -5370 778 -11009 -4402 -10251 8288 -8188 606 -4864 -7738 1800 -3502 3720 -1248 -970 -2849 3844 -1826 1174 608 2547 1307 642 975 -1487 669 -2588 1174 -3608 5649 -1294 1896 -3148 -3062 -1838 -984 -64 -1394 -17 -2000 -1401 -1121 1491 -776 223 -946 67 -1815 1048 74 1732 1686 1536 1516 666 1611 -572 871 778 1234 836 2343 1121 1073 -541 -361 -131 645 1838 -130 1092 -383 672 -384 78 -1575 -2050 -1778 -2001 -1866 -1465 -1819 -1358 -350 -607 741 60 739 492 737 236 -429 213 -562 602 77 798 83 88 -1107 -1223 -1075 261 -1230 -1297 -620 -451 277 609 1176 395 628 -276 174 -302 345 260 261 -250 -460 446 723 593 927 394 -243 633 -272 139 -252 -574 -372 194 186 76 449 -192 228 -386 92 -931 411 -430 61 -929 -310 -730 520 -669 51 -463 -750 162 -381 435 -177 -154 -483 638 -336 216 117 468 251 132 210 -341 151 -567 236 -751 1156 -308 476 -875 -781 -455 -265 -20 -520 -7 -931 -677 -560 734 -388 113 -475 33 -892 504 38 950 959 929 941 425 1041 -374 549 490 799 581 1738 888 850 -403 -257 -91 478 1502 -115 991 -349 589 -319 59 -1112 -1416 -1289 -1638 -1655 -1414 -1851 -1433 -390 -714 893 75 906 586 815 247 -420 206 -582 675 94 1040 113 117 -1410 -1464 -1243 311 -1577 -1728 -855 -640 407 947 1886 638 979 -413 241 -404 467 364 388 -389 -724 686 1081 855 1287 533 -317 848 -389 208 -394 -905 -600 323 326 136 812 -357 421 -698 162 -1606 SS 20221023T040819.9Z 8331.172452 398 1 9.16 2 59.91 211.35 62.24 244.07 0.00 1 0.00 1 0 17 1.539e-02 6.625e-03 1.020e-02 2.735e-03 2.917503e-01 1.390586e-03 3.594387e-03 -6.000000e+00 8.851416e-03 224.91 -2.00 3.56 -2.00 317.48 0.00e+00 7.399269e-04 2.135106e-04 2.363851e-04 -6.000000e+00 3.910014e-04 281.48 -2.00 20.00 -2.00 316.80 0.00e+00 1.986 0.000 302.00 328.00 3 4.0798e+00 3.6535e-03 2.4862e-02 -6.0000e+00 2.1872e-02 1.3635e-02 4.1103e-03 1.5065e-02 -6.0000e+00 2.3703e-02 5.6970e-03 2.5560e-03 7.5218e-03 -6.0000e+00 1.4137e-02 -8.4280e-03 1.3061e-03 2.2078e-03 -6.0000e+00 6.1267e-03 8.5551e-04 6.7169e-05 7.7418e-05 2.3215e-05 -6.0000e+00 4.0750e-04 -2.8024e-03 4.3283e-06 12 9 1 12 1 1 99.76 17.22 0.25 -0.00280 -0.00230 9 14 1 5 0 897.730 21.48 15.00 17.22 16.99 17.3 925.64 3279 -1023 518 -6289 -4186 -6501 -3121 -2855 -1225 -5481 -3304 -4873 -1111 -1789 619 1275 98 1719 2359 733 458 634 -67 1285 1335 713 -1946 -797 -571 695 1257 301 1712 -393 -4081 -3820 -2247 -1776 -108 -632 -992 -570 -187 -276 -283 227 13 -401 -144 210 16 1263 256 1230 565 969 782 107 200 1310 1219 1469 1873 1689 754 -650 24 -559 926 929 169 210 144 212 -327 -431 -1118 -1698 -1577 -1266 -1851 -1506 -2007 -1468 -143 218 560 228 885 394 400 111 -226 -75 232 586 212 231 339 -501 -580 -1133 -751 -309 -1232 -1044 -734 -379 390 887 781 385 402 154 215 113 587 -48 63 -109 107 -77 444 289 823 181 170 31 -82 270 -39 -137 -432 365 179 -158 -48 13 23 -463 68 -522 266 -95 49 -612 -359 -546 -267 -274 -129 -629 -376 -576 -145 -266 104 238 19 350 488 159 103 143 -16 313 336 188 -528 -206 -138 167 318 84 510 -123 -1246 -1147 -729 -654 -45 -304 -513 -307 -104 -155 -158 127 7 -218 -79 115 9 759 164 810 384 672 555 76 139 895 860 1100 1486 1410 635 -516 19 -419 736 817 155 200 136 196 -287 -350 -854 -1278 -1242 -1094 -1730 -1500 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