File name: Pandora276s1_Sapporo_20250612_L2Fit_fout2c2d20231212p1-8.txt File generation date: 20250825T105930.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora276_OF_v2d20230804.txt Instrument calibration file used: Pandora276s1_CF_v2d20231212.txt Level 1 file used: Pandora276s1_Sapporo_20250612_L1_smca1c2d20231212p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20250612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0410 305.1817 305.3223 305.4630 305.6036 305.7443 305.8849 306.0255 306.1661 306.3067 306.4473 306.5878 306.7284 306.8689 307.0095 307.1500 307.2905 307.4310 307.5715 307.7120 307.8524 307.9929 308.1333 308.2738 308.4142 308.5546 308.6950 308.8354 308.9757 309.1161 309.2565 309.3968 309.5371 309.6775 309.8178 309.9581 310.0983 310.2386 310.3789 310.5191 310.6594 310.7996 310.9398 311.0800 311.2202 311.3604 311.5006 311.6407 311.7809 311.9210 312.0611 312.2013 312.3414 312.4815 312.6215 312.7616 312.9017 313.0417 313.1817 313.3218 313.4618 313.6018 313.7418 313.8817 314.0217 314.1617 314.3016 314.4415 314.5815 314.7214 314.8613 315.0012 315.1410 315.2809 315.4207 315.5606 315.7004 315.8402 315.9800 316.1198 316.2596 316.3994 316.5392 316.6789 316.8186 316.9584 317.0981 317.2378 317.3775 317.5172 317.6568 317.7965 317.9361 318.0758 318.2154 318.3550 318.4946 318.6342 318.7738 318.9133 319.0529 319.1924 319.3320 319.4715 319.6110 319.7505 319.8900 320.0294 320.1689 320.3083 320.4478 320.5872 320.7266 320.8660 321.0054 321.1448 321.2842 321.4235 321.5629 321.7022 321.8415 321.9808 322.1201 322.2594 322.3987 322.5380 322.6772 322.8165 322.9557 323.0949 323.2341 323.3733 323.5125 323.6517 323.7908 323.9300 324.0691 324.2082 324.3473 324.4864 324.6255 324.7646 324.9037 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250612T022347.9Z 9294.099860 452 1 54.60 2 20.04 172.81 162.56 321.95 0.00 1 0.00 1 0 17 1.072e-02 8.158e-03 2.052e-03 1.430e-03 1.768674e-01 7.881924e-04 2.148025e-03 -6.000000e+00 6.653161e-03 232.74 -2.00 3.56 -2.00 314.82 0.00e+00 2.606452e-04 6.543603e-05 2.339882e-05 -6.000000e+00 2.916260e-04 284.85 -2.00 20.00 -2.00 314.20 0.00e+00 1.064 0.000 302.00 328.00 3 6.1971e+00 2.0358e-03 1.4264e-02 -6.0000e+00 1.6698e-02 5.3713e-02 2.2465e-03 9.3047e-03 -6.0000e+00 1.7991e-02 -6.1210e-03 1.2819e-03 4.5102e-03 -6.0000e+00 1.0694e-02 -4.3652e-04 5.4835e-04 1.2353e-03 -6.0000e+00 4.4534e-03 3.0504e-04 -2.7757e-04 4.6106e-05 1.9494e-05 -6.0000e+00 3.4247e-04 4.1428e-03 0.0000e+00 11 9 0 11 40 0 99.99 27.84 0.57 0.00414 0.00206 30 3 1 5 0 1819.600 36.25 20.00 27.84 22.26 3.4 1100.00 406 -453 -1890 -1778 -2558 -762 1155 -653 679 -1512 -1488 -2886 871 -594 3520 -221 -103 868 -51 873 2359 -306 -626 181 3506 -340 -368 -134 -1255 2712 1830 594 -718 9 -3166 -1721 -688 110 -117 -221 -806 -1324 -358 -237 -1055 -837 -939 -269 -539 1979 114 1122 605 1470 433 1051 860 -102 680 1229 890 1216 1573 1554 731 -664 -1661 -790 -299 801 613 689 719 453 262 -1286 -522 -1249 -1552 -1013 -1157 -1144 -2021 -2366 -1102 -585 157 141 467 699 368 222 -309 598 147 2 158 413 785 -136 41 -287 -1191 -599 -221 -1281 -1334 -202 -257 490 675 676 588 211 -256 -151 189 -121 237 264 -20 483 279 499 702 688 280 373 787 676 227 -390 -418 -189 380 185 -10 -226 275 -266 -452 -304 -1024 131 -158 -674 -600 -866 -239 364 -227 233 -553 -545 -1086 337 -257 1617 -104 -50 432 -27 456 1232 -164 -340 101 1960 -188 -217 -75 -665 1326 912 314 -403 5 -1786 -939 -394 66 -83 -167 -628 -1088 -299 -199 -891 -698 -765 -210 -437 1546 93 890 506 1269 388 953 789 -95 617 1106 823 1111 1525 1572 742 -643 -1596 -720 -279 761 635 708 746 460 266 -1209 -469 -1056 -1321 -926 -1100 -1189 -2143 -2656 -1228 -692 194 172 572 874 433 253 -322 621 155 3 185 498 998 -175 51 -330 -1391 -703 -259 -1615 -1676 -262 -348 655 937 947 799 282 -334 -184 223 -148 305 343 -28 655 372 639 899 836 344 449 972 833 293 -520 -540 -250 524 268 -14 -332 407 -390 -648 -443 -1471 SS 20250612T023438.0Z 9294.107385 461 1 28.50 2 19.92 180.09 163.62 328.81 0.00 1 0.00 1 0 17 7.967e-03 6.490e-03 1.719e-04 1.313e-04 1.694197e-01 7.280417e-05 2.079656e-03 -6.000000e+00 4.945352e-03 232.74 -2.00 3.56 -2.00 314.36 0.00e+00 3.205602e-04 5.521853e-06 1.661533e-05 -6.000000e+00 2.167803e-04 284.85 -2.00 20.00 -2.00 313.79 0.00e+00 1.063 0.000 302.00 328.00 3 9.5369e-01 1.8737e-04 1.4004e-02 -6.0000e+00 1.2412e-02 1.5300e-02 2.0609e-04 8.9564e-03 -6.0000e+00 1.3374e-02 -1.7219e-03 1.1787e-04 4.3464e-03 -6.0000e+00 7.9489e-03 -3.0083e-03 4.9824e-05 1.1994e-03 -6.0000e+00 3.3100e-03 5.9528e-02 -3.5391e-04 4.2244e-06 1.9483e-05 -6.0000e+00 2.5458e-04 4.6966e-03 0.0000e+00 11 8 0 10 0 0 99.96 27.85 0.42 0.00470 0.00204 2796 280 1 5 0 10.190 36.50 20.00 27.85 23.14 3.4 1100.00 680 -597 -1134 -2002 -2636 -805 48 1039 764 -267 -1455 -1052 347 323 467 411 -151 528 880 881 1186 574 1029 1219 822 502 -29 -743 -267 439 1266 1209 798 -211 -2594 -2125 -1176 -888 -197 -326 -946 -1006 -625 -602 -638 -210 -616 -725 -409 -121 671 1030 709 1088 691 651 793 457 324 558 922 1424 1356 1122 592 -613 -446 -117 249 1215 385 217 216 63 177 -413 -599 -797 -906 -474 -1197 -1483 -1667 -1805 -1037 -592 -306 164 163 394 291 429 102 126 601 610 366 484 449 -206 -444 -671 -742 -377 -179 -1015 -871 -440 -446 246 473 467 241 216 61 -36 248 257 144 212 32 -20 252 486 483 943 509 479 830 375 189 -74 -319 -12 55 5 -87 -4 104 -246 -273 -437 -858 280 -252 -485 -818 -1047 -297 18 418 316 -117 -645 -470 163 159 240 216 -83 295 503 515 669 326 588 717 505 317 -18 -447 -157 247 711 711 471 -128 -1555 -1304 -723 -593 -141 -257 -763 -854 -524 -508 -537 -181 -519 -591 -334 -97 548 849 615 945 619 593 730 422 296 508 856 1341 1317 1105 583 -594 -411 -107 232 1187 387 223 224 66 181 -400 -544 -702 -802 -435 -1181 -1505 -1760 -1954 -1184 -697 -370 200 199 480 343 475 110 133 619 653 417 567 556 -250 -533 -777 -845 -433 -211 -1248 -1091 -558 -589 329 640 638 328 283 76 -45 296 315 182 278 43 -27 330 629 613 1162 600 572 987 458 242 -94 -418 -16 75 6 -123 -6 148 -357 -387 -618 -1193 SS 20250612T023506.6Z 9294.107716 461 2 28.50 2 19.92 180.41 163.67 329.13 0.00 1 0.00 1 0 17 7.974e-03 6.498e-03 1.632e-04 1.251e-04 1.695948e-01 6.938971e-05 2.081953e-03 -6.000000e+00 4.949763e-03 232.74 -2.00 3.56 -2.00 314.33 0.00e+00 3.098282e-04 5.258800e-06 1.703966e-05 -6.000000e+00 2.169707e-04 284.85 -2.00 20.00 -2.00 313.77 0.00e+00 1.063 0.000 302.00 328.00 3 8.5617e-01 1.7853e-04 1.4011e-02 -6.0000e+00 1.2423e-02 1.5467e-02 1.9640e-04 8.9641e-03 -6.0000e+00 1.3385e-02 -2.0539e-03 1.1233e-04 4.3478e-03 -6.0000e+00 7.9560e-03 -2.8033e-03 4.7487e-05 1.1972e-03 -6.0000e+00 3.3130e-03 6.5606e-02 -3.5142e-04 4.0243e-06 1.9341e-05 -6.0000e+00 2.5480e-04 4.5556e-03 0.0000e+00 11 8 0 10 0 0 99.99 27.85 0.41 0.00456 0.00191 2796 280 1 5 0 10.190 36.25 20.00 27.85 23.14 3.4 1100.00 688 -490 -1161 -2065 -2596 -819 3 1055 757 -328 -1565 -1095 297 329 501 371 -172 518 880 889 1153 602 1019 1217 847 516 -25 -702 -226 449 1188 1175 816 -219 -2608 -2097 -1174 -891 -200 -368 -943 -999 -580 -617 -616 -191 -663 -743 -423 -119 690 1023 684 1072 710 652 824 459 341 578 895 1410 1345 1094 634 -609 -433 -110 231 1232 390 212 242 78 186 -407 -600 -789 -904 -500 -1195 -1490 -1665 -1799 -1051 -612 -293 131 183 393 299 423 114 131 599 601 363 462 413 -201 -434 -675 -764 -346 -174 -998 -898 -426 -440 246 444 450 253 221 69 5 256 274 148 228 52 -26 259 479 483 934 521 487 850 377 173 -80 -312 -10 55 26 -100 -2 70 -258 -271 -451 -869 279 -204 -490 -880 -1015 -315 1 417 327 -141 -685 -483 138 160 255 204 -94 288 500 517 679 357 607 714 518 325 -16 -421 -133 250 665 687 501 -132 -1558 -1280 -719 -594 -143 -291 -766 -853 -489 -525 -522 -165 -563 -609 -347 -96 566 848 597 937 640 599 739 412 314 530 810 1340 1319 1089 631 -595 -403 -101 217 1174 396 221 254 81 186 -397 -548 -699 -804 -462 -1152 -1528 -1777 -1972 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