File name: Pandora276s1_Sapporo_20250706_L2Fit_fout2c2d20231212p1-8.txt File generation date: 20250825T110608.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 276 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora276_OF_v2d20230804.txt Instrument calibration file used: Pandora276s1_CF_v2d20231212.txt Level 1 file used: Pandora276s1_Sapporo_20250706_L1_smca1c2d20231212p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20250706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 195 337 Nominal wavelengths inside fitting window [nm]: 305.0410 305.1817 305.3223 305.4630 305.6036 305.7443 305.8849 306.0255 306.1661 306.3067 306.4473 306.5878 306.7284 306.8689 307.0095 307.1500 307.2905 307.4310 307.5715 307.7120 307.8524 307.9929 308.1333 308.2738 308.4142 308.5546 308.6950 308.8354 308.9757 309.1161 309.2565 309.3968 309.5371 309.6775 309.8178 309.9581 310.0983 310.2386 310.3789 310.5191 310.6594 310.7996 310.9398 311.0800 311.2202 311.3604 311.5006 311.6407 311.7809 311.9210 312.0611 312.2013 312.3414 312.4815 312.6215 312.7616 312.9017 313.0417 313.1817 313.3218 313.4618 313.6018 313.7418 313.8817 314.0217 314.1617 314.3016 314.4415 314.5815 314.7214 314.8613 315.0012 315.1410 315.2809 315.4207 315.5606 315.7004 315.8402 315.9800 316.1198 316.2596 316.3994 316.5392 316.6789 316.8186 316.9584 317.0981 317.2378 317.3775 317.5172 317.6568 317.7965 317.9361 318.0758 318.2154 318.3550 318.4946 318.6342 318.7738 318.9133 319.0529 319.1924 319.3320 319.4715 319.6110 319.7505 319.8900 320.0294 320.1689 320.3083 320.4478 320.5872 320.7266 320.8660 321.0054 321.1448 321.2842 321.4235 321.5629 321.7022 321.8415 321.9808 322.1201 322.2594 322.3987 322.5380 322.6772 322.8165 322.9557 323.0949 323.2341 323.3733 323.5125 323.6517 323.7908 323.9300 324.0691 324.2082 324.3473 324.4864 324.6255 324.7646 324.9037 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250705T203300.9Z 9317.856260 106 1 3.38 2 75.83 72.02 147.25 302.10 0.00 1 0.00 1 0 17 1.294e-01 9.858e-03 6.049e-02 4.628e-03 4.957553e-01 2.513146e-03 5.836781e-03 -6.000000e+00 8.040954e-02 233.04 -2.00 3.56 -2.00 319.17 0.00e+00 1.957230e-03 6.459528e-04 7.087473e-04 -6.000000e+00 3.553481e-03 287.06 -2.00 20.00 -2.00 318.39 0.00e+00 3.995 0.001 302.00 328.00 3 2.4265e+00 7.0662e-03 4.8036e-02 -6.0000e+00 2.0181e-01 1.7497e-02 8.1831e-03 2.6804e-02 -6.0000e+00 2.1731e-01 -3.9695e-02 6.0168e-03 1.3192e-02 -6.0000e+00 1.2931e-01 1.2921e-02 3.1288e-03 3.9376e-03 -6.0000e+00 5.3935e-02 5.0329e-04 -7.9457e-04 1.4415e-04 4.9023e-05 -6.0000e+00 4.1356e-03 4.8842e-03 0.0000e+00 12 9 9 12 1 1 71.73 28.48 0.49 0.00488 -0.00109 8 15 1 5 0 374.950 37.00 20.00 28.48 32.15 3.0 1100.00 -32624 -48801 22290 -27102 -44880 -51870 -41403 -53075 -48486 -22540 -22249 -28273 5728 -14366 52172 -24714 -249 -9635 1196 1198 11350 -2604 -11376 -3060 14427 -1828 -3586 -9583 -51 8475 773 -7871 -3029 -6472 -1782 -2598 -3389 2580 1372 -2490 -1903 633 -1931 3311 -2170 -3947 2564 -1109 -534 5414 2140 493 -307 2343 3397 3490 1519 -680 1344 2273 -923 709 2830 3325 3820 -166 65 286 245 -13 2283 959 -342 1128 -706 -872 -851 -2399 -2778 -1513 -2535 -688 -2402 -2638 -1345 -823 -477 949 1103 543 1460 52 -182 112 -232 316 -247 464 766 -737 -926 -1207 -396 -701 -543 -1277 -685 -368 39 407 562 802 1053 109 -482 -63 9 165 444 377 379 95 441 -142 567 76 149 -426 1564 27 198 -102 -793 -188 432 -167 527 -365 413 -261 26 -172 -962 -663 -1344 322 -636 -1195 -1451 -1103 -1773 -1729 -671 -703 -1046 178 -668 1507 -1796 -16 -735 88 93 825 -222 -1099 -290 1231 -193 -392 -1094 -5 826 90 -1043 -429 -1009 -265 -392 -558 466 301 -614 -527 185 -608 1019 -718 -1348 830 -378 -185 1857 818 194 -133 1061 1610 1721 729 -335 643 1073 -463 377 1626 1936 2310 -103 39 173 159 -9 1680 756 -259 864 -515 -620 -560 -1568 -1937 -1108 -2027 -609 -2243 -2506 -1347 -832 -507 1031 1204 581 1540 52 -173 111 -232 336 -284 569 970 -965 -1219 -1476 -470 -829 -674 -1619 -913 -496 54 586 874 1254 1647 166 -728 -94 13 250 679 583 596 149 692 -216 858 111 210 -611 2355 43 331 -176 -1381 -342 800 -317 1029 -733 828 -516 49 -322 -1764 SS 20250705T204059.4Z 9317.861799 109 1 1.81 2 74.45 73.27 148.43 304.60 0.00 1 0.00 1 0 25 1.032e-01 1.255e-02 7.149e-02 8.030e-03 4.510167e-01 4.347405e-03 5.381244e-03 -6.000000e+00 6.412008e-02 233.04 -2.00 3.56 -2.00 318.81 0.00e+00 2.730527e-03 9.802090e-04 7.185488e-04 -6.000000e+00 2.833539e-03 287.06 -2.00 20.00 -2.00 318.01 0.00e+00 3.661 0.001 302.00 328.00 3 2.9836e+00 1.2022e-02 4.3897e-02 -6.0000e+00 1.6093e-01 1.6858e-02 1.3747e-02 2.4324e-02 -6.0000e+00 1.7329e-01 -4.2689e-02 9.4889e-03 1.2032e-02 -6.0000e+00 1.0311e-01 1.6741e-02 4.9096e-03 3.7999e-03 -6.0000e+00 4.3010e-02 4.1687e-04 -9.7920e-04 2.5202e-04 4.7061e-05 -6.0000e+00 3.2977e-03 4.5913e-03 0.0000e+00 12 9 9 12 1 1 999.00 28.49 0.22 0.00459 -0.00277 2 9 1 5 0 600.070 37.00 20.00 28.49 32.17 3.0 1100.00 -4641 -20621 -23487 -40545 -61471 -35621 -2399 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1995 2763 1931 1214 -356 318 203 -796 1529 371 2356 2014 -740 -314 107 192 -1787 -1009 -3039 -1936 -569 -2568 -2461 -1203 -568 -677 -668 1057 1118 75 -547 -242 267 265 634 225 1155 494 199 -1818 -1758 -1662 -1149 -486 -1326 -1871 -862 -532 1209 1070 174 1268 1651 -443 2214 -669 -271 788 -82 9 877 -316 722 728 1534 -297 1747 1800 519 929 -1459 -1620 -345 1925 -1084 -792 1381 234 -1061 645 -1090 -1797 SS 20250705T204608.4Z 9317.865375 113 1 36.97 2 73.54 74.07 149.18 306.29 0.00 1 0.00 1 0 17 8.995e-02 9.880e-03 1.815e-02 2.042e-03 4.345773e-01 1.105837e-03 5.129117e-03 -6.000000e+00 5.590189e-02 233.04 -2.00 3.56 -2.00 318.81 0.00e+00 1.035687e-03 2.516518e-04 4.710365e-04 -6.000000e+00 2.470346e-03 287.06 -2.00 20.00 -2.00 318.02 0.00e+00 3.472 0.001 302.00 328.00 3 3.7728e+00 3.0554e-03 4.1824e-02 -6.0000e+00 1.4030e-01 1.6121e-02 3.4968e-03 2.3394e-02 -6.0000e+00 1.5107e-01 -2.8183e-02 2.4166e-03 1.1345e-02 -6.0000e+00 8.9896e-02 1.1124e-02 1.2486e-03 3.1601e-03 -6.0000e+00 3.7498e-02 2.3066e-04 -6.8881e-04 6.4733e-05 3.8708e-05 -6.0000e+00 2.8750e-03 4.4854e-03 0.0000e+00 12 9 9 12 1 1 99.97 28.50 0.50 0.00449 -0.00069 37 6 1 5 0 972.790 37.00 20.00 28.50 32.26 3.0 1100.00 -31875 -16095 -16012 -5367 -34577 -17019 -18621 -25765 -46939 -727 -25693 -23742 -15285 -26071 27544 -13464 2119 -703 -6739 -6434 13641 -5224 -11766 -7533 20398 -3544 -4472 -2264 -7458 15488 7119 3759 1730 2942 -10042 534 1356 5626 -212 344 -1650 -690 -1482 3035 -596 -2353 2893 -47 726 8404 557 -328 18 2098 202 2512 612 -1253 1624 3925 -191 504 2662 3237 1034 -1191 -937 -971 -873 1181 2217 1202 250 319 471 -989 443 -1643 -2498 -871 -1867 -334 -1810 -3066 -1405 -579 -345 215 188 691 276 144 295 1299 -364 71 268 626 93 -448 -313 -726 -947 -1048 -227 -1179 -1089 -323 -326 440 610 612 189 43 -159 71 327 203 279 190 353 629 361 387 412 436 152 76 968 590 223 -310 -670 -187 50 173 453 -135 309 -188 -369 -348 -889 -1066 -522 -548 -162 -1322 -532 -623 -1031 -2589 -27 -1300 -1277 -874 -1983 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