File name: Pandora279s1_Sapporo_20251115_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260626T165533.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20251115_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20251115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251114T230219.9Z 9449.959953 249 1 55.41 2 76.34 132.35 42.66 189.71 0.00 1 0.00 1 0 17 3.255e-01 2.475e-02 8.248e-02 3.322e-03 5.659043e-01 1.697057e-03 7.027979e-03 -6.000000e+00 1.813448e-01 222.82 -2.00 3.56 -2.00 319.98 0.00e+00 2.493489e-03 5.463125e-04 2.250838e-03 -6.000000e+00 8.227460e-03 278.62 -2.00 20.00 -2.00 319.44 0.00e+00 4.136 0.001 302.00 328.00 3 3.9327e+00 4.8721e-03 5.1056e-02 -6.0000e+00 4.4752e-01 1.6121e-01 5.9443e-03 3.1339e-02 -6.0000e+00 4.8717e-01 -1.6888e-01 5.3120e-03 1.6562e-02 -6.0000e+00 2.8928e-01 5.8883e-02 2.7714e-03 5.2333e-03 -6.0000e+00 1.2777e-01 8.7463e-05 -2.6671e-04 8.8016e-05 6.5776e-05 -6.0000e+00 8.5644e-03 2.2216e-02 0.0000e+00 12 9 8 11 32 0 99.87 26.82 0.31 0.02222 0.02021 29 3 1 5 0 1910.290 35.00 19.98 26.82 12.67 0.3 911.71 -139015 900000 -14272 900000 -144081 -104366 -129686 900000 -54091 -31376 -87025 -69803 -46254 182678 65909 -38696 -19844 -23652 -9600 9578 14359 -1230 29114 -12005 3640 43180 -17433 -16439 14359 -18887 38048 -26787 10221 5044 3703 6688 59299 10805 5743 30843 -4834 -48 -15657 9053 2147 17125 5287 9104 3598 1793 12664 8435 4223 3679 7662 7988 40 1215 -2122 3062 -7492 -81 5103 3842 -3347 3191 -4555 -3436 3618 2563 2819 230 3740 645 932 139 -8499 -9951 -1623 -1544 677 331 -3906 -810 1101 1476 1453 837 -1194 137 -1465 -1003 1409 -3252 -2799 -1283 -292 -772 113 -41 -557 -853 -1223 -876 -2274 -672 -2683 34 -609 208 12708 117 130 -734 -559 -790 -1380 13 -724 258 -604 1342 -155 1190 1237 -440 1976 368 -861 -335 793 -427 -1402 235 459 -838 1270 -200 -603 190 248 -1146 900000 -4950 900000 -180 900000 -5504 -2770 -4912 900000 -1208 -579 -2902 -2327 -1542 769 1088 -2067 -957 -1286 -479 409 581 -58 1093 -735 202 1677 -1219 -1075 688 -1425 1921 -2983 890 459 316 580 3474 1238 848 4114 -997 -10 -3575 1785 459 3204 1126 1919 829 453 3210 2217 1254 1179 2446 2626 14 422 -738 1010 -2919 -33 2221 1854 -1717 1458 -2240 -1737 1940 1455 1707 145 2199 397 514 69 -4412 -5459 -948 -973 479 264 -3449 -732 970 1371 1404 828 -1186 126 -1368 -873 1161 -2972 -2677 -1389 -334 -1000 151 -53 -660 -975 -1326 -1008 -2658 -806 -3485 46 -851 321 18728 188 215 -1161 -825 -1133 -2045 21 -1199 435 -1000 2100 -239 1728 1847 -641 2734 523 -1400 -560 1411 -804 -2612 459 955 -1828 2753 -422 -1257 394 486 -2157 900000 SS 20251115T013504.1Z 9450.066020 338 1 55.03 2 62.41 168.19 58.21 234.96 0.00 1 0.00 1 0 17 1.448e-02 6.424e-03 1.980e-03 8.166e-04 2.971573e-01 4.046984e-04 3.677163e-03 -6.000000e+00 8.029466e-03 222.81 -2.00 3.56 -2.00 316.65 0.00e+00 3.298572e-04 4.976927e-05 6.980013e-05 -6.000000e+00 3.532478e-04 278.60 -2.00 20.00 -2.00 316.03 0.00e+00 2.148 0.000 302.00 328.00 3 3.7999e+00 1.0448e-03 2.6124e-02 -6.0000e+00 1.9777e-02 -1.2085e-03 1.1713e-03 1.5122e-02 -6.0000e+00 2.1508e-02 -7.1736e-03 6.9697e-04 7.5673e-03 -6.0000e+00 1.2818e-02 9.0276e-04 3.4518e-04 2.2123e-03 -6.0000e+00 5.6270e-03 9.8324e-04 3.7944e-04 2.1834e-05 2.3989e-05 -6.0000e+00 3.6929e-04 2.1438e-02 0.0000e+00 11 8 0 10 0 0 99.95 26.92 0.32 0.02144 0.02429 87 8 1 5 0 632.390 35.00 20.00 26.92 14.47 0.2 919.37 -4610 1113 -2827 -905 -8061 -5057 -5086 1839 -1467 -1960 -5091 -3158 1849 1205 1653 -352 432 -503 757 1506 967 879 1455 189 519 2150 -105 -1147 -153 -359 1283 148 1005 -1093 -2892 -2116 -619 -2060 -352 410 -508 -296 -680 -115 -74 117 -135 -338 -129 290 1071 965 1204 1111 1233 1068 633 331 85 537 446 1167 2004 1521 -383 -148 -1262 -626 207 717 364 209 714 392 -64 -569 -1857 -1796 -1038 -1135 -839 -1310 -1937 -1360 -637 -68 -100 465 519 233 123 -537 -229 -148 -215 186 776 676 252 -215 -234 -690 -677 -296 -794 -504 -533 -99 348 695 103 760 566 36 -51 -233 -221 195 84 -26 -117 298 253 359 659 105 572 656 393 251 246 49 -366 -117 -126 -333 249 111 -150 -241 -313 -625 900000 -722 175 -456 -127 -1099 -687 -765 293 -265 -361 -952 -637 379 288 450 -97 123 -151 234 478 307 278 485 68 181 761 -37 -402 -51 -124 478 56 415 -446 -1106 -840 -275 -1036 -197 244 -325 -185 -437 -73 -47 74 -84 -207 -83 181 721 657 867 843 955 806 486 250 66 419 350 945 1758 1346 -344 -122 -1051 -522 183 683 355 209 693 378 -56 -470 -1506 -1444 -876 -1046 -826 -1362 -2039 -1502 -726 -82 -121 572 631 277 140 -582 -240 -151 -232 214 959 891 329 -279 -291 -820 -780 -355 -995 -656 -704 -136 492 1019 154 1120 817 50 -68 -306 -297 268 120 -39 -170 435 359 500 903 138 743 861 543 358 357 73 -557 -181 -202 -539 409 187 -251 -399 -499 -991 900000 SS 20251115T015423.4Z 9450.079437 354 1 42.97 2 61.85 173.33 61.17 239.24 0.00 1 0.00 1 0 17 1.349e-02 6.468e-03 1.921e-03 8.443e-04 2.909434e-01 4.183730e-04 3.619383e-03 -6.000000e+00 7.477324e-03 222.81 -2.00 3.56 -2.00 316.52 0.00e+00 4.197302e-04 4.964091e-05 6.313863e-05 -6.000000e+00 3.289512e-04 278.60 -2.00 20.00 -2.00 315.91 0.00e+00 2.109 0.000 302.00 328.00 3 3.6642e+00 1.0789e-03 2.5640e-02 -6.0000e+00 1.8417e-02 -3.4168e-03 1.2091e-03 1.4838e-02 -6.0000e+00 2.0028e-02 -7.3105e-03 7.1366e-04 7.4235e-03 -6.0000e+00 1.1936e-02 7.0458e-04 3.5065e-04 2.1768e-03 -6.0000e+00 5.2402e-03 1.1822e-03 3.9554e-04 2.2549e-05 2.3745e-05 -6.0000e+00 3.4389e-04 2.1200e-02 0.0000e+00 12 9 1 12 1 1 99.70 26.94 0.29 0.02120 0.02417 75 9 1 5 0 565.280 35.00 20.00 26.94 15.02 0.2 921.39 -3328 2672 -2083 -1669 -7725 -4372 -4654 1134 -1225 -1886 -4901 -3102 546 605 1464 -255 334 60 782 2109 757 416 1010 -107 297 1413 397 -1217 -36 -450 1312 100 669 -1271 -2517 -2042 -392 -1876 -131 732 -418 -352 -942 60 -24 284 -505 -34 -228 428 1178 1027 1156 1143 1097 930 774 410 150 562 501 921 1893 1632 -238 -230 -1183 -454 292 544 638 185 527 409 -76 -419 -1693 -1771 -1112 -1113 -933 -1360 -1987 -1364 -725 -213 -29 569 495 236 -18 -461 -189 -299 -168 145 743 665 184 -150 -424 -773 -766 -279 -685 -557 -490 -62 351 587 807 695 443 126 -138 -114 -212 48 -28 49 -172 147 293 458 596 128 733 619 521 338 219 -5 -285 -109 -101 -291 238 64 -149 -376 -357 -615 900000 -578 464 -374 -264 -1176 -660 -779 203 -226 -354 -933 -636 126 149 408 -78 105 20 247 680 246 135 345 -39 114 553 152 -434 -12 -158 495 39 281 -529 -1044 -823 -177 -960 -75 446 -259 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