File name: Pandora279s1_Sapporo_20251215_L2Fit_fout2c2d20231207p1-8.txt File generation date: 20251215T143702.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v2d20231207.txt Level 1 file used: Pandora279s1_Sapporo_20251215_L1_smca1c2d20231207p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20251215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1196 305.2603 305.4009 305.5416 305.6822 305.8229 305.9635 306.1041 306.2447 306.3853 306.5259 306.6665 306.8070 306.9476 307.0881 307.2287 307.3692 307.5097 307.6502 307.7907 307.9311 308.0716 308.2120 308.3525 308.4929 308.6333 308.7737 308.9141 309.0545 309.1949 309.3353 309.4756 309.6160 309.7563 309.8966 310.0369 310.1772 310.3175 310.4578 310.5980 310.7383 310.8785 311.0188 311.1590 311.2992 311.4394 311.5796 311.7198 311.8599 312.0001 312.1402 312.2804 312.4205 312.5606 312.7007 312.8408 312.9809 313.1209 313.2610 313.4010 313.5411 313.6811 313.8211 313.9611 314.1011 314.2410 314.3810 314.5210 314.6609 314.8008 314.9408 315.0807 315.2206 315.3605 315.5003 315.6402 315.7801 315.9199 316.0597 316.1996 316.3394 316.4792 316.6189 316.7587 316.8985 317.0382 317.1780 317.3177 317.4574 317.5971 317.7368 317.8765 318.0162 318.1559 318.2955 318.4352 318.5748 318.7144 318.8540 318.9936 319.1332 319.2728 319.4123 319.5519 319.6914 319.8309 319.9705 320.1100 320.2495 320.3889 320.5284 320.6679 320.8073 320.9468 321.0862 321.2256 321.3650 321.5044 321.6438 321.7832 321.9225 322.0619 322.2012 322.3405 322.4798 322.6191 322.7584 322.8977 323.0370 323.1762 323.3155 323.4547 323.5939 323.7331 323.8723 324.0115 324.1507 324.2899 324.4290 324.5682 324.7073 324.8464 324.9855 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251215T003845.6Z 9480.026916 282 1 55.32 2 71.08 153.14 64.37 212.67 0.00 1 0.00 1 0 25 1.002e-01 8.361e-03 1.300e-02 1.359e-03 4.763680e-01 6.733084e-04 5.818129e-03 -6.000000e+00 5.546935e-02 222.38 -2.00 3.56 -2.00 318.70 0.00e+00 5.825914e-04 1.460035e-04 2.085240e-04 -6.000000e+00 2.410955e-03 275.24 -2.00 20.00 -2.00 318.16 0.00e+00 3.047 0.000 302.00 328.00 3 3.4571e+00 1.8141e-03 3.8886e-02 -6.0000e+00 1.3665e-01 2.0464e-02 2.0830e-03 2.4475e-02 -6.0000e+00 1.4874e-01 -1.9997e-02 1.5699e-03 1.2395e-02 -6.0000e+00 8.8495e-02 5.9462e-03 8.5226e-04 3.7036e-03 -6.0000e+00 3.8798e-02 4.5015e-04 -3.8262e-04 3.5662e-05 3.7271e-05 -6.0000e+00 2.5555e-03 1.9261e-02 3.2881e-06 11 8 0 10 0 0 99.50 26.90 0.33 0.01926 0.01639 49 5 1 5 0 1128.880 35.00 20.00 26.90 9.45 0.5 896.63 -43664 -18990 -3240 716 -58096 -38027 -54357 22676 -11834 -8748 -36963 -22015 14898 8300 13156 -10906 -5799 -3853 -668 -3652 -126 1235 2217 -926 -5119 6006 -2423 -3743 512 -1914 3812 -3400 1185 -4549 -961 -1794 802 -3663 -1970 4184 -1184 -420 -3080 3618 325 1360 878 1954 -127 -38 1585 2251 1258 851 1202 1609 924 581 460 -458 592 831 2454 2354 -82 646 -377 -876 92 1364 1104 -818 746 -302 593 296 -2410 -2344 -570 -915 -1437 -1062 -2697 -1397 -691 -174 154 138 471 572 181 -268 669 -72 -206 19 735 458 254 -145 -397 -1044 -665 -773 -890 -843 -817 -443 150 599 1010 551 501 292 -99 72 -104 105 -174 -311 -499 320 -91 625 641 471 1155 965 285 264 304 95 -255 -13 -53 -423 264 17 -311 -272 -182 -579 900000 -1649 -614 -91 17 -2341 -1310 -2478 550 -453 -337 -1940 -1155 665 482 872 -1029 -560 -394 -70 -410 -14 133 256 -109 -669 734 -316 -463 65 -251 544 -592 221 -890 -168 -333 166 -960 -571 1323 -427 -158 -1135 1355 127 531 345 770 -48 -15 700 1073 607 441 643 886 521 322 248 -249 338 524 1593 1655 -58 424 -246 -592 65 1093 895 -690 600 -244 429 205 -1620 -1610 -411 -772 -1305 -1013 -2766 -1414 -749 -189 174 159 532 637 186 -272 641 -73 -221 22 914 611 351 -193 -511 -1280 -771 -959 -1136 -1121 -1096 -602 220 922 1590 882 775 441 -146 102 -151 154 -273 -485 -798 492 -137 923 906 667 1568 1341 426 414 508 158 -442 -24 -97 -799 502 33 -598 -497 -327 -1034 900000 SS 20251215T004645.6Z 9480.032472 288 1 17.36 2 70.44 154.97 65.19 214.56 0.00 1 0.00 1 0 25 5.819e-02 7.080e-03 6.622e-03 1.124e-03 4.623033e-01 5.561924e-04 5.669363e-03 -6.000000e+00 3.219965e-02 222.38 -2.00 3.56 -2.00 318.18 0.00e+00 6.450484e-04 1.021026e-04 1.705358e-04 -6.000000e+00 1.399581e-03 275.24 -2.00 20.00 -2.00 317.63 0.00e+00 2.954 0.000 302.00 328.00 3 2.1202e+00 1.4752e-03 3.7647e-02 -6.0000e+00 7.9326e-02 1.6284e-02 1.6735e-03 2.3612e-02 -6.0000e+00 8.6341e-02 -3.2428e-02 1.1465e-03 1.1919e-02 -6.0000e+00 5.1371e-02 1.4036e-02 6.1555e-04 3.5493e-03 -6.0000e+00 2.2522e-02 1.9167e-03 -4.2950e-04 2.9321e-05 3.6000e-05 -6.0000e+00 1.4835e-03 1.9097e-02 -8.8093e-06 12 9 1 12 1 1 93.49 26.90 0.28 0.01910 0.01587 60 18 1 5 0 284.470 35.00 20.00 26.90 9.60 0.5 896.80 -21575 -524 -13362 -16623 -32685 -24357 -27391 -9174 -14282 -10517 -21619 -14647 -2308 -461 2547 -3428 -1502 -1087 1782 552 718 -116 1170 -648 -905 2373 -1138 -3939 -3381 -1501 1163 -489 1558 -1129 -3208 -2760 -591 -1808 347 1652 -213 570 147 1532 884 1000 204 368 370 459 1295 1704 1609 1249 1021 1017 808 404 476 353 841 1298 2326 1855 438 -73 -528 -578 308 552 433 -287 36 112 -93 -586 -1526 -1355 -1008 -962 -1207 -1392 -2181 -1509 -1070 -554 -298 329 407 439 137 159 414 161 122 -12 549 532 29 -202 -396 -754 -735 -644 -978 -692 -846 -264 115 501 658 511 445 447 33 113 -152 -15 -3 -60 -209 262 254 678 665 239 839 865 441 465 295 112 -128 -8 -100 -406 106 -47 -297 -271 -465 -537 900000 -1125 -24 -707 -818 -1737 -1241 -1612 -516 -942 -691 -1623 -1184 -202 -44 279 -445 -205 -159 267 87 113 -18 199 -111 -166 439 -213 -709 -593 -283 245 -118 382 -281 -818 -679 -163 -565 130 660 -94 244 65 673 394 449 92 168 173 227 663 942 906 754 606 623 504 248 283 222 529 855 1695 1397 327 -53 -384 -411 235 458 385 -252 32 93 -73 -433 -1126 -1018 -780 -829 -1136 -1350 -2256 -1575 -1156 -632 -341 381 464 488 146 163 419 164 134 -14 696 707 39 -269 -502 -924 -856 -775 -1235 -907 -1137 -363 165 746 1017 801 691 668 48 160 -215 -22 -5 -93 -323 400 377 982 949 327 1138 1213 651 726 478 184 -211 -13 -179 -733 193 -87 -548 -487 -814 -921 900000 SS 20251215T010410.1Z 9480.044561 294 1 15.59 2 69.20 159.01 67.09 218.56 0.00 1 0.00 1 0 17 4.261e-02 6.543e-03 3.875e-03 7.944e-04 4.346983e-01 3.931458e-04 5.344056e-03 -6.000000e+00 2.358433e-02 222.38 -2.00 3.56 -2.00 317.92 0.00e+00 6.492026e-04 6.695275e-05 1.348145e-04 -6.000000e+00 1.024867e-03 275.24 -2.00 20.00 -2.00 317.35 0.00e+00 2.789 0.000 302.00 328.00 3 1.5208e+00 1.0366e-03 3.5466e-02 -6.0000e+00 5.8102e-02 1.7233e-02 1.1725e-03 2.2175e-02 -6.0000e+00 6.3235e-02 -2.3204e-02 7.7561e-04 1.1203e-02 -6.0000e+00 3.7623e-02 9.0869e-03 4.1210e-04 3.3548e-03 -6.0000e+00 1.6498e-02 4.2188e-03 -1.4809e-04 2.0838e-05 3.3723e-05 -6.0000e+00 1.0863e-03 1.9037e-02 5.0885e-05 12 9 1 12 1 1 99.98 26.92 0.27 0.01904 0.01792 174 58 1 5 0 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