File name: Pandora279s1_Sapporo_20251226_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260626T170428.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20251226_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20251226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251226T040319.7Z 9491.168978 230 1 54.97 2 69.46 201.59 66.53 125.12 0.00 1 0.00 1 0 17 2.540e-01 2.360e-02 7.544e-02 2.409e-03 4.745695e-01 1.175210e-03 5.663511e-03 -6.000000e+00 1.384404e-01 222.75 -2.00 3.56 -2.00 319.22 0.00e+00 3.367746e-04 2.991363e-04 1.508271e-03 -6.000000e+00 6.128171e-03 274.50 -2.00 20.00 -2.00 318.67 0.00e+00 2.822 0.000 302.00 328.00 3 4.8135e+00 3.2273e-03 3.7428e-02 -6.0000e+00 3.4117e-01 9.0385e-03 3.7709e-03 2.5672e-02 -6.0000e+00 3.7358e-01 -3.7472e-02 3.0082e-03 1.2198e-02 -6.0000e+00 2.2239e-01 2.4766e-02 1.6086e-03 3.5983e-03 -6.0000e+00 9.5194e-02 1.4571e-04 3.5967e-04 6.4202e-05 3.4218e-05 -6.0000e+00 6.4614e-03 1.2364e-02 0.0000e+00 12 9 8 11 40 0 99.96 27.03 0.17 0.01236 0.01507 36 3 1 5 0 1526.780 35.00 20.00 27.03 8.55 0.6 892.31 -61238 900000 181060 83381 -93998 -16847 -67653 143665 26192 -30061 -45931 6618 -12285 40214 -762 -9477 7804 -20222 -11044 41 21125 14150 4207 6205 -13196 28492 -10145 -2206 12436 11440 13208 -4255 -3289 -6617 2536 1949 -5425 -6842 -4375 8806 -3629 -15 -6727 7918 1640 5000 -249 4394 217 -318 3851 1370 738 49 2473 4415 434 3216 -444 -2631 -1714 -602 1968 2505 -1369 -1206 -614 -2324 53 3274 1809 -454 701 1002 1730 636 -3785 -3512 491 -931 -856 77 -3292 -1380 -1100 699 1163 595 -902 1115 510 -34 1840 412 -137 739 1228 1046 498 621 -357 -1147 211 91 -222 44 -474 1020 629 1690 -13486 1022 691 996 424 180 -127 1060 645 431 608 328 303 844 718 693 2392 1461 1277 1025 1009 145 -223 939 203 -705 649 -274 -555 -407 -261 -1001 -1005 -2187 900000 638 705 -4284 -368 -2750 810 535 -1123 -2050 201 -551 1294 -44 -672 501 -1848 -970 3 1404 1011 358 563 -1547 2303 -1184 -222 1055 1070 1396 -607 -522 -1080 350 282 -966 -1488 -1036 2127 -1073 -4 -2230 2271 505 1501 -79 1344 71 -111 1423 564 330 22 1105 1999 208 1469 -204 -1234 -841 -324 1155 1585 -884 -729 -362 -1431 36 2273 1368 -359 532 711 1192 396 -2321 -2187 333 -691 -723 67 -3130 -1357 -1163 770 1241 651 -988 1207 510 -31 1732 379 -143 807 1516 1361 676 808 -461 -1345 232 107 -282 58 -622 1402 884 2586 -23019 1614 1118 1507 635 260 -189 1543 1007 698 966 506 454 1272 1036 956 3125 2053 1884 1652 1638 246 -393 1727 380 -1382 1273 -525 -1108 -769 -468 -1815 -1797 SS 20251226T041358.2Z 9491.176368 233 1 54.23 2 70.21 204.07 64.97 127.38 0.00 1 0.00 1 0 64 2.421e-01 1.511e-01 5.300e-02 2.515e-03 5.092089e-01 1.250800e-03 1.380860e-02 -6.000000e+00 1.327286e-01 222.75 -2.00 3.56 -2.00 319.32 0.00e+00 -8.018074e-03 3.247775e-04 1.421708e-02 -6.000000e+00 5.980853e-03 274.50 -2.00 20.00 -2.00 318.79 0.00e+00 2.922 0.000 302.00 328.00 3 4.8072e+00 3.4564e-03 6.7909e-02 -6.0000e+00 3.2771e-01 -8.2520e-02 4.0409e-03 8.0562e-02 -6.0000e+00 3.5910e-01 -1.3843e-01 3.2416e-03 3.0930e-02 -6.0000e+00 2.1283e-01 1.6426e-01 1.7221e-03 3.8075e-03 -6.0000e+00 9.1199e-02 1.3388e-04 3.1590e-03 6.7720e-05 1.2996e-04 -6.0000e+00 6.3647e-03 9.7751e-03 0.0000e+00 12 9 8 11 8 0 99.97 27.03 -0.08 0.00978 0.03351 23 2 1 5 0 2357.540 35.00 20.01 27.03 8.84 0.5 893.01 -67887 900000 152829 900000 -86437 -13394 -60898 900000 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791 1841 -905 -1393 -1477 -1173 -328 -308 -3642 -3382 -2565 -1628 483 2668 1440 -1094 262 -584 217 -144 -3045 -1605 1970 1027 1170 2116 -917 1003 2092 3941 4394 3760 1590 2167 1829 1981 5536 5488 6105 5905 8010 7516 6199 4844 3336 2142 6126 7110 6768 8129 6944 9976 11043 12755 -165064 11767 10387 10072 9476 9694 9562 11404 10667 9284 7218 8633 6453 6571 6420 4857 8331 8359 8093 7257 6802 4772 4586 6345 3846 717 2410 -942 -4586 -5988 -6775 -9286 -8320 SS 20251226T042522.5Z 9491.184288 236 1 55.14 2 71.11 206.67 63.34 129.87 0.00 1 0.00 1 0 17 2.704e-01 1.444e-02 8.647e-02 1.676e-03 5.087555e-01 8.167227e-04 5.958615e-03 -6.000000e+00 1.473963e-01 222.75 -2.00 3.56 -2.00 319.18 0.00e+00 1.084452e-03 2.053847e-04 6.286191e-04 -6.000000e+00 6.449798e-03 274.50 -2.00 20.00 -2.00 318.62 0.00e+00 3.052 0.000 302.00 328.00 3 3.9393e+00 2.2447e-03 3.9876e-02 -6.0000e+00 3.6325e-01 1.4581e-02 2.6207e-03 2.6197e-02 -6.0000e+00 3.9775e-01 -4.0380e-02 2.1100e-03 1.2934e-02 -6.0000e+00 2.3659e-01 2.0383e-02 1.1296e-03 4.0727e-03 -6.0000e+00 1.0067e-01 2.6960e-04 1.8031e-04 4.3812e-05 3.7540e-05 -6.0000e+00 6.8793e-03 1.2444e-02 0.0000e+00 12 8 8 10 0 0 99.99 27.03 0.04 0.01244 0.01380 78 7 1 5 0 706.770 35.00 20.00 27.03 8.59 0.6 892.44 -67817 228695 10222 127913 -90505 -43625 -79537 45314 -13844 -34450 -53365 -13128 37499 3432 2938 -10953 2205 -17073 -12624 -4451 6798 1491 -4406 -1056 -10432 18402 -10314 -10342 4681 2377 6318 -3716 -2166 -5531 899 -335 -2967 -6733 -1422 6637 -1599 -1279 -3475 4817 2391 2858 38 2652 752 298 3617 1951 492 376 2488 3023 1150 1773 -8 -468 -903 238 2395 2691 -460 324 8 -1177 301 2079 1017 -655 314 7 844 191 -2461 -2418 -657 -735 -734 -362 -2386 -1266 -1305 194 381 484 -105 625 824 38 637 121 -498 82 744 621 219 -38 -437 -982 -448 -72 -680 -242 -481 282 392 988 -7565 871 743 718 265 485 -106 629 232 182 -2 743 303 498 636 680 1476 1368 926 769 527 212 -73 330 64 -529 432 -64 -589 -324 -348 -664 -667 -2140 411 167 585 -3373 -1055 -3081 578 -358 -1143 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