File name: Pandora279s1_Sapporo_20260110_L2Fit_fwvt1c3d20250917p1-8.txt File generation date: 20260626T170847.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260110_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1619 1768 Nominal wavelengths inside fitting window [nm]: 492.1120 492.2329 492.3537 492.4746 492.5954 492.7162 492.8370 492.9578 493.0785 493.1992 493.3200 493.4407 493.5613 493.6820 493.8027 493.9233 494.0439 494.1645 494.2851 494.4057 494.5262 494.6467 494.7673 494.8878 495.0082 495.1287 495.2491 495.3696 495.4900 495.6104 495.7308 495.8511 495.9715 496.0918 496.2121 496.3324 496.4527 496.5729 496.6932 496.8134 496.9336 497.0538 497.1740 497.2941 497.4143 497.5344 497.6545 497.7746 497.8947 498.0147 498.1348 498.2548 498.3748 498.4948 498.6147 498.7347 498.8546 498.9746 499.0945 499.2143 499.3342 499.4541 499.5739 499.6937 499.8135 499.9333 500.0530 500.1728 500.2925 500.4122 500.5319 500.6516 500.7713 500.8909 501.0105 501.1301 501.2497 501.3693 501.4889 501.6084 501.7279 501.8474 501.9669 502.0864 502.2059 502.3253 502.4447 502.5641 502.6835 502.8029 502.9222 503.0416 503.1609 503.2802 503.3994 503.5187 503.6380 503.7572 503.8764 503.9956 504.1148 504.2339 504.3531 504.4722 504.5913 504.7104 504.8295 504.9485 505.0676 505.1866 505.3056 505.4246 505.5436 505.6625 505.7815 505.9004 506.0193 506.1382 506.2570 506.3759 506.4947 506.6135 506.7323 506.8511 506.9699 507.0886 507.2073 507.3260 507.4447 507.5634 507.6821 507.8007 507.9193 508.0379 508.1565 508.2751 508.3936 508.5122 508.6307 508.7492 508.8677 508.9861 509.1046 509.2230 509.3414 509.4598 509.5782 509.6966 509.8149 509.9332 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260110T000313.5Z 9506.002239 348 1 12.14 2 74.60 142.11 75.90 244.29 0.00 1 0.00 1 0 15 2.397e-03 2.391e-03 9.143e-04 9.134e-04 2.033149e+03 5.642050e+01 1.411343e+02 -6.000000e+00 1.390274e+02 273.59 -2.00 20.00 -2.00 505.28 0.00e+00 1.387009e-03 2.545206e-05 7.590089e-05 -6.000000e+00 6.802413e-05 273.59 -2.00 20.00 -2.00 500.55 0.00e+00 3.294305e-01 1.868774e-02 2.205548e-02 -6.000000e+00 4.944388e-02 223.31 -2.00 3.56 -2.00 502.13 0.00e+00 3.696 0.001 489.00 513.00 1 6.0134e+00 1.4360e-03 5.8471e-03 -6.0000e+00 3.8001e-03 -1.0834e-02 3.6063e-04 5.2877e-04 -6.0000e+00 9.6202e-04 2.7157e-03 9.4404e-04 1.1514e-04 3.9014e-05 -6.0000e+00 3.1077e-04 1.3705e-02 -4.8309e-05 12 1 1 12 1 1 99.80 26.92 1.93 0.01371 0.02025 10 5 1 4 0 1102.740 35.00 19.99 26.92 6.62 0.7 883.48 -99 -212 -237 -177 -85 277 434 288 276 146 200 -106 -90 181 -57 -244 -31 289 54 -136 37 280 282 572 444 54 118 -24 -341 -244 100 -45 -154 184 -47 -343 -105 212 0 -42 103 -100 98 27 122 5 39 91 -195 -182 -571 -418 -609 -288 -1 -92 -125 85 -149 208 232 261 178 160 87 64 -47 168 118 -139 -72 -41 -161 70 -14 -284 -408 -149 25 88 -318 -426 -488 -258 -68 -322 -332 -119 -137 92 23 335 287 187 -93 -103 -118 -125 -80 -247 -499 -238 -254 -93 -414 -456 -325 -405 26 332 260 34 179 363 350 346 336 342 388 305 176 85 485 440 183 240 313 71 99 112 122 -150 -64 -164 -49 330 14 -311 -5 -88 112 -2 54 159 40 11 -191 -328 -325 -60 -96 -210 -237 -180 -87 284 449 299 286 149 205 -107 -90 183 -57 -246 -31 296 56 -141 38 292 294 589 459 56 122 -25 -346 -243 100 -45 -156 189 -49 -356 -108 216 0 -43 105 -103 101 28 126 6 40 93 -199 -181 -565 -407 -595 -284 -1 -93 -127 87 -152 211 236 265 181 162 88 65 -47 167 116 -136 -70 -40 -159 70 -14 -281 -399 -144 24 86 -307 -415 -479 -251 -67 -318 -329 -118 -135 91 23 337 286 186 -92 -102 -115 -121 -77 -235 -478 -228 -246 -92 -410 -454 -321 -398 25 326 259 34 180 364 353 351 342 347 390 307 176 84 477 433 181 237 310 70 98 110 118 -147 -62 -158 -47 322 14 -307 -5 -87 111 -2 54 160 40 11 -190 -321 -320 -59 SQ 20260110T001330.2Z 9506.009377 352 1 54.62 2 73.47 144.29 77.59 246.16 0.00 1 0.00 1 0 15 2.082e-03 2.083e-03 3.360e-04 3.358e-04 1.919803e+03 2.061585e+01 1.335689e+02 -6.000000e+00 1.207983e+02 273.58 -2.00 20.00 -2.00 505.28 0.00e+00 1.420494e-03 9.353642e-06 7.823147e-05 -6.000000e+00 5.910420e-05 273.58 -2.00 20.00 -2.00 500.56 0.00e+00 3.065810e-01 6.861618e-03 2.143763e-02 -6.000000e+00 4.295908e-02 223.31 -2.00 3.56 -2.00 502.14 0.00e+00 3.460 0.001 489.00 513.00 1 5.6560e+00 5.2723e-04 5.5471e-03 -6.0000e+00 3.3017e-03 -1.2863e-02 1.3252e-04 5.0166e-04 -6.0000e+00 8.3580e-04 4.0206e-03 1.0610e-03 4.2404e-05 4.0079e-05 -6.0000e+00 2.7002e-04 1.2360e-02 -3.6974e-05 10 0 0 10 0 0 99.81 26.93 1.93 0.01236 0.01972 94 9 1 4 0 580.910 35.00 19.99 26.93 6.76 0.6 883.94 -107 -81 -106 -233 -77 235 418 302 280 191 183 94 8 59 -50 -214 13 185 115 -135 131 231 180 495 317 127 203 -40 -275 -195 7 -190 47 218 -127 -384 -160 28 8 -79 70 1 -6 -4 151 -51 -49 58 -135 -238 -430 -404 -433 -164 -20 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-271 -267 -110 SQ 20260110T001734.2Z 9506.012202 355 1 35.23 2 73.04 145.17 78.27 246.89 0.00 1 0.00 1 0 15 2.098e-03 2.098e-03 2.564e-04 2.562e-04 1.834020e+03 1.568778e+01 1.259558e+02 -6.000000e+00 1.217120e+02 273.58 -2.00 20.00 -2.00 505.28 0.00e+00 1.431342e-03 7.132687e-06 7.905394e-05 -6.000000e+00 5.954956e-05 273.58 -2.00 20.00 -2.00 500.56 0.00e+00 2.935209e-01 5.237005e-03 2.118852e-02 -6.000000e+00 4.327945e-02 223.31 -2.00 3.56 -2.00 502.14 0.00e+00 3.377 0.001 489.00 513.00 1 4.6903e+00 4.0228e-04 5.4420e-03 -6.0000e+00 3.3264e-03 -1.3480e-02 1.0119e-04 4.8779e-04 -6.0000e+00 8.4193e-04 1.0694e-02 8.1660e-04 3.2334e-05 4.0246e-05 -6.0000e+00 2.7203e-04 1.1885e-02 -2.6564e-05 12 1 1 12 1 1 98.88 26.92 1.93 0.01188 0.01755 111 16 1 4 0 314.480 35.00 20.00 26.92 6.86 0.7 884.70 -160 -59 -20 -201 -154 286 373 385 290 217 199 48 -36 65 -49 -182 -40 160 100 -137 63 243 222 431 339 182 262 -29 -303 -165 -15 -186 -28 246 -171 -404 -132 35 7 15 62 -18 21 68 105 3 -40 -39 -144 -308 -407 -359 -437 -239 -66 -102 -173 -161 -30 133 243 303 214 203 166 49 61 57 26 -161 -42 -101 -105 45 -18 -371 -328 -66 -105 -129 -235 -316 -415 -171 -133 -293 -276 -136 -12 -129 44 177 199 12 -145 -37 -56 -77 -73 -248 -381 -342 -147 -65 -380 -466 -336 -150 94 262 224 97 191 216 276 349 456 392 252 278 207 188 319 373 148 69 157 12 179 232 44 -80 6 -80 4 205 136 -146 -84 45 35 81 135 94 40 11 -220 -349 -258 -76 -155 -58 -20 -203 -157 293 383 397 300 222 204 49 -36 65 -49 -183 -40 162 104 -141 65 252 231 449 350 187 270 -30 -305 -164 -15 -186 -28 251 -177 -419 -136 35 7 15 64 -19 22 70 109 4 -42 -40 -145 -309 -404 -350 -427 -236 -66 -103 -176 -163 -30 135 248 309 219 206 167 49 61 57 25 -158 -41 -99 -103 45 -18 -366 -320 -64 -102 -124 -228 -306 -406 -167 -130 -289 -274 -134 -12 -128 43 177 200 12 -145 -37 -55 -75 -70 -238 -363 -328 -143 -64 -376 -462 -334 -148 92 260 222 97 193 218 280 352 460 398 254 277 206 186 315 368 147 68 156 12 177 227 43 -78 6 -77 4 200 133 -145 -83 45 36 81 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