File name: Pandora279s1_Sapporo_20260119_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260626T171101.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260119_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260119T001436.0Z 9515.010139 112 1 54.48 2 72.28 143.05 76.85 141.89 0.00 1 0.00 1 0 17 1.480e-01 1.069e-02 3.120e-02 2.227e-03 5.015268e-01 1.105765e-03 5.878068e-03 -6.000000e+00 8.136930e-02 223.66 -2.00 3.56 -2.00 319.40 0.00e+00 1.485611e-03 2.952832e-04 4.980959e-04 -6.000000e+00 3.731598e-03 273.21 -2.00 20.00 -2.00 318.87 0.00e+00 3.240 0.001 302.00 328.00 3 4.2812e+00 3.0619e-03 4.1186e-02 -6.0000e+00 2.0136e-01 2.7569e-02 3.5950e-03 2.6068e-02 -6.0000e+00 2.2061e-01 -3.1120e-02 3.0124e-03 1.2892e-02 -6.0000e+00 1.3071e-01 8.0477e-03 1.6092e-03 4.2424e-03 -6.0000e+00 5.6269e-02 1.6191e-04 2.5303e-04 5.9705e-05 3.9306e-05 -6.0000e+00 3.9249e-03 1.3602e-02 0.0000e+00 12 9 8 11 32 0 99.86 26.89 0.72 0.01360 0.01550 29 3 1 5 0 1878.340 35.00 20.00 26.89 -0.09 1.1 851.64 -92643 900000 900000 900000 -74154 7058 -40413 900000 -20140 23338 -55721 1359 38782 65969 8297 -29382 17563 -9351 -4911 -13070 11365 3398 1453 -10163 -9003 15883 1810 -5171 9910 4974 16514 -3061 1248 -10536 -7149 -7458 2272 -4603 1105 12105 -6766 -2750 -4886 4979 1969 5057 2592 630 2302 -1361 4043 -301 2191 1592 996 1801 -127 2163 -1096 -1065 -1670 76 3615 2865 -1436 -348 -809 -2290 1495 2438 1631 961 795 1540 2118 -953 -4847 -2974 -496 -536 -954 -343 -2819 -1980 -898 174 487 852 719 731 -1129 402 1587 -501 -1236 -274 256 66 454 263 -910 -468 403 165 -936 -323 -1246 154 315 952 -1093 829 301 336 115 80 -1201 4 -379 169 -472 307 -529 476 322 -60 1715 725 619 147 621 -165 -244 434 -136 -256 879 -44 -418 129 -209 -687 -553 -3277 900000 900000 900000 -2060 90 -930 900000 -485 380 -2056 33 808 1288 349 -2040 827 -625 -333 -1004 686 223 105 -893 -832 1200 155 -448 727 424 1462 -377 166 -1575 -959 -1049 332 -868 220 2512 -1838 -756 -1426 1324 546 1379 728 184 679 -444 1391 -118 905 651 425 787 -58 939 -478 -464 -775 39 1992 1732 -893 -201 -464 -1374 903 1670 1209 732 589 1059 1307 -588 -2941 -1815 -311 -394 -746 -299 -2668 -1961 -885 180 523 930 775 741 -1073 375 1401 -471 -1232 -308 307 84 597 333 -1141 -524 452 185 -1148 -410 -1591 207 458 1435 -1713 1295 482 505 170 114 -1786 6 -595 273 -752 470 -791 711 462 -82 2244 1025 926 242 1031 -288 -440 782 -263 -490 1693 -87 -820 250 -387 -1215 -965 SS 20260119T002328.5Z 9515.016302 115 1 13.94 2 71.32 144.99 75.88 143.67 0.00 1 0.00 1 0 17 1.637e-01 1.029e-02 4.822e-02 2.991e-03 4.787383e-01 1.458250e-03 5.613738e-03 -6.000000e+00 8.951062e-02 223.66 -2.00 3.56 -2.00 318.91 0.00e+00 3.602107e-04 3.326748e-04 1.901234e-04 -6.000000e+00 3.883739e-03 273.21 -2.00 20.00 -2.00 318.36 0.00e+00 3.085 0.001 302.00 328.00 3 3.7302e+00 3.9626e-03 3.9040e-02 -6.0000e+00 2.2112e-01 1.2256e-02 4.5742e-03 2.4278e-02 -6.0000e+00 2.4204e-01 -3.3626e-02 3.4791e-03 1.2159e-02 -6.0000e+00 1.4377e-01 1.2806e-02 1.8656e-03 3.5763e-03 -6.0000e+00 6.0975e-02 3.3879e-04 3.1756e-04 7.8767e-05 3.5123e-05 -6.0000e+00 4.1656e-03 1.4079e-02 0.0000e+00 12 9 9 12 1 1 99.16 26.89 0.32 0.01408 0.01646 12 5 1 5 0 1071.800 35.00 19.99 26.89 0.00 1.1 852.77 -73620 70749 61182 99485 -68664 -29912 -39694 39685 -15060 -5188 -37423 -17678 14952 5161 11836 -18743 14686 -3127 -3159 -4842 4699 2989 6631 4581 -4289 4821 4672 -8335 2518 -7369 10074 -2096 129 -3316 -5092 -1048 -4268 -2791 -618 6310 -3977 -1086 -3046 1520 1720 3871 -988 1220 2427 -1301 2250 64 1039 2111 352 2733 738 -22 -892 751 -306 1132 3234 2766 -301 -282 -600 -1444 99 1702 684 620 287 501 412 -87 -1652 -2353 -537 -1015 -290 -1340 -1951 -1848 -1046 18 139 594 422 519 -376 -278 581 -342 74 -148 264 658 417 293 -902 -782 -385 -49 -815 -436 -1078 401 542 927 -3483 863 795 404 62 119 -123 425 156 191 -112 369 445 520 427 72 919 992 307 275 101 94 -346 184 -8 -259 345 342 -458 -361 -120 -558 -344 -3479 867 839 842 -2864 -881 -1447 752 -554 -180 -1834 -820 615 285 732 -1766 1067 -293 -312 -508 450 292 675 519 -514 608 579 -1101 292 -1032 1367 -331 22 -594 -860 -178 -857 -666 -163 1802 -1362 -380 -1125 538 612 1363 -365 447 899 -532 910 29 499 1076 189 1485 387 -11 -487 403 -163 659 2065 1796 -198 -186 -391 -911 70 1262 550 510 230 375 298 -57 -1101 -1612 -384 -797 -257 -1265 -1855 -1852 -1122 20 154 670 470 574 -386 -280 555 -342 78 -169 324 862 569 384 -1158 -949 -441 -60 -1030 -573 -1433 559 781 1401 -5649 1359 1260 603 89 167 -177 643 242 306 -177 562 658 766 602 102 1247 1372 456 446 169 155 -595 321 -15 -483 650 659 -875 -681 -214 -993 -603 SS 20260119T002951.8Z 9515.020739 119 1 54.66 2 70.67 146.41 75.21 144.96 0.00 1 0.00 1 0 25 6.498e-02 7.959e-03 6.910e-03 9.009e-04 4.658140e-01 4.378636e-04 5.553415e-03 -6.000000e+00 3.552994e-02 223.66 -2.00 3.56 -2.00 318.56 0.00e+00 1.050219e-03 8.968273e-05 2.376041e-04 -6.000000e+00 1.541651e-03 273.21 -2.00 20.00 -2.00 318.00 0.00e+00 2.986 0.000 302.00 328.00 3 2.9581e+00 1.1777e-03 3.7919e-02 -6.0000e+00 8.7772e-02 1.5380e-02 1.3488e-03 2.3688e-02 -6.0000e+00 9.6077e-02 -3.3933e-02 9.6065e-04 1.1887e-02 -6.0000e+00 5.7071e-02 9.6004e-03 5.1247e-04 3.5825e-03 -6.0000e+00 2.4202e-02 8.1619e-04 3.3910e-05 2.3710e-05 3.5311e-05 -6.0000e+00 1.6536e-03 1.4687e-02 0.0000e+00 11 8 0 10 0 0 99.63 26.88 0.34 0.01469 0.01494 135 13 1 5 0 404.830 35.00 20.00 26.88 0.35 1.1 854.98 -30894 2923 -925 -2667 -32118 -28679 -31186 -11373 -18122 -15094 -27633 -12923 -3545 -3442 366 -7075 188 -4448 -2856 -2783 573 -41 -717 -4900 -4254 1060 -1393 -6519 -462 -1749 1602 1020 434 -1654 -4469 -1980 -1287 -2392 -583 2438 -875 -127 10 2062 1223 1567 662 704 984 479 2152 1260 1296 1699 1726 1669 1149 735 277 213 357 1108 2183 1975 324 233 -523 -727 333 784 720 250 268 379 288 -608 -1754 -1821 -1193 -1258 -1227 -1381 -2293 -1729 -1073 -465 -98 289 535 549 260 136 212 -115 -346 -183 329 252 -28 -387 -601 -822 -791 -419 -990 -787 -834 -227 94 387 2803 440 303 116 55 -43 -273 -37 -51 -210 -276 139 277 333 416 125 820 890 547 546 124 62 -293 49 26 -340 286 5 -188 -204 -236 -426 -484 -1327 98 -33 -87 -1292 -1154 -1436 -492 -936 -786 -1663 -772 -237 -279 34 -728 19 -517 -344 -350 70 -5 -95 -735 -674 166 -220 -1017 -66 -278 283 205 99 -351 -984 -444 -300 -678 -184 866 -347 -49 4 806 487 628 267 288 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