File name: Pandora279s1_Sapporo_20260214_L2Fit_fwvt1c3d20250917p1-8.txt File generation date: 20260626T171700.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260214_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1619 1768 Nominal wavelengths inside fitting window [nm]: 492.1120 492.2329 492.3537 492.4746 492.5954 492.7162 492.8370 492.9578 493.0785 493.1992 493.3200 493.4407 493.5613 493.6820 493.8027 493.9233 494.0439 494.1645 494.2851 494.4057 494.5262 494.6467 494.7673 494.8878 495.0082 495.1287 495.2491 495.3696 495.4900 495.6104 495.7308 495.8511 495.9715 496.0918 496.2121 496.3324 496.4527 496.5729 496.6932 496.8134 496.9336 497.0538 497.1740 497.2941 497.4143 497.5344 497.6545 497.7746 497.8947 498.0147 498.1348 498.2548 498.3748 498.4948 498.6147 498.7347 498.8546 498.9746 499.0945 499.2143 499.3342 499.4541 499.5739 499.6937 499.8135 499.9333 500.0530 500.1728 500.2925 500.4122 500.5319 500.6516 500.7713 500.8909 501.0105 501.1301 501.2497 501.3693 501.4889 501.6084 501.7279 501.8474 501.9669 502.0864 502.2059 502.3253 502.4447 502.5641 502.6835 502.8029 502.9222 503.0416 503.1609 503.2802 503.3994 503.5187 503.6380 503.7572 503.8764 503.9956 504.1148 504.2339 504.3531 504.4722 504.5913 504.7104 504.8295 504.9485 505.0676 505.1866 505.3056 505.4246 505.5436 505.6625 505.7815 505.9004 506.0193 506.1382 506.2570 506.3759 506.4947 506.6135 506.7323 506.8511 506.9699 507.0886 507.2073 507.3260 507.4447 507.5634 507.6821 507.8007 507.9193 508.0379 508.1565 508.2751 508.3936 508.5122 508.6307 508.7492 508.8677 508.9861 509.1046 509.2230 509.3414 509.4598 509.5782 509.6966 509.8149 509.9332 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260213T234219.5Z 9540.987725 152 1 0.53 2 70.49 131.32 71.06 175.29 0.00 1 0.00 1 0 15 2.981e-03 2.968e-03 2.592e-03 2.590e-03 1.243383e+03 1.550391e+02 1.006156e+02 -6.000000e+00 1.727182e+02 273.21 -2.00 20.00 -2.00 505.28 0.00e+00 1.049879e-03 7.196649e-05 5.791521e-05 -6.000000e+00 8.451002e-05 273.21 -2.00 20.00 -2.00 500.56 0.00e+00 2.934399e-01 5.297361e-02 1.261769e-02 -6.000000e+00 6.161732e-02 224.68 -2.00 3.56 -2.00 502.14 0.00e+00 2.961 0.000 489.00 513.00 1 4.4803e+00 4.0685e-03 4.5531e-03 -6.0000e+00 4.7342e-03 -1.4987e-02 1.0261e-03 3.4025e-04 -6.0000e+00 1.1989e-03 1.4086e-02 7.6437e-04 3.2741e-04 3.0921e-05 -6.0000e+00 3.8651e-04 9.9791e-03 -1.9157e-05 12 1 1 12 1 1 999.00 26.83 1.98 0.00998 0.01528 1 20 1 4 0 261.300 35.00 20.00 26.83 10.43 0.4 902.86 -589 142 98 -32 454 294 394 371 48 164 77 120 -186 -276 -122 -474 67 534 328 18 311 396 68 62 701 228 21 -470 -368 -86 -560 -644 264 366 -89 -492 11 30 289 175 -161 -273 146 196 -123 163 -221 85 -146 -204 -117 -397 -423 -404 -217 -201 -226 450 -46 131 26 84 -11 -28 5 -63 338 457 8 -81 -289 -88 270 207 108 -656 -177 123 -162 -769 210 -115 -490 -606 -100 268 -378 -86 -321 230 190 337 399 62 -35 24 -145 134 -300 247 -538 -339 -507 -207 -289 -20 -519 -71 263 206 59 18 237 -27 99 -65 127 339 155 125 393 -70 331 652 -84 31 214 159 23 293 355 -100 236 -157 -172 171 597 -558 -308 250 -24 -153 142 -64 61 292 136 4 -772 149 -572 140 97 -33 462 303 406 383 50 169 78 121 -186 -276 -121 -479 68 542 336 18 323 408 70 64 724 236 22 -481 -373 -86 -560 -645 267 375 -92 -508 11 31 296 179 -164 -281 149 202 -127 168 -228 87 -148 -204 -116 -388 -414 -400 -215 -202 -230 454 -47 133 27 86 -11 -29 5 -64 337 450 8 -79 -284 -86 265 204 106 -649 -172 120 -157 -749 203 -111 -480 -594 -98 264 -373 -85 -318 229 189 338 399 62 -35 24 -142 129 -289 238 -518 -328 -498 -205 -288 -20 -514 -70 259 203 59 18 238 -27 100 -67 129 343 155 126 392 -70 328 644 -83 31 213 156 23 289 345 -98 227 -152 -167 167 584 -550 -306 250 -24 -154 143 -64 61 289 135 4 -757 145 SQ 20260213T235127.7Z 9540.994071 155 1 25.79 2 69.25 133.29 70.94 177.37 0.00 1 0.00 1 0 15 1.957e-03 1.960e-03 5.490e-04 5.484e-04 1.396712e+03 3.313728e+01 9.632156e+01 -6.000000e+00 1.133781e+02 273.21 -2.00 20.00 -2.00 505.26 0.00e+00 6.853806e-04 1.523942e-05 3.878757e-05 -6.000000e+00 5.548373e-05 273.21 -2.00 20.00 -2.00 500.50 0.00e+00 2.524689e-01 1.125356e-02 1.465218e-02 -6.000000e+00 4.046876e-02 224.68 -2.00 3.56 -2.00 502.08 0.00e+00 2.795 0.000 489.00 513.00 1 5.9590e+00 8.6449e-04 4.2538e-03 -6.0000e+00 3.1091e-03 -1.3642e-03 2.1809e-04 3.7606e-04 -6.0000e+00 7.8791e-04 3.3117e-03 1.4650e-03 6.9119e-05 2.0580e-05 -6.0000e+00 2.5387e-04 1.3513e-02 -7.7883e-05 12 1 1 12 1 1 99.98 26.85 2.01 0.01351 0.02367 44 9 1 4 0 572.830 35.00 20.00 26.85 11.61 0.4 906.78 10 -128 -95 -217 -56 198 412 308 234 199 180 110 -85 164 -95 -113 -19 198 126 -95 -3 169 119 555 321 102 142 -13 -258 -26 31 -306 72 263 -68 -383 -180 69 -55 -14 -14 -19 40 36 124 -210 -138 20 -168 -240 -464 -210 -428 -190 38 -158 -222 -223 7 104 237 276 155 117 99 76 69 165 15 -94 -55 -72 -80 -77 -17 -313 -214 -74 -133 55 -210 -328 -294 -96 -62 -318 -348 -98 187 -71 -34 91 126 31 -195 16 -114 -139 -89 -158 -300 -232 -188 -29 -287 -501 -331 -135 30 256 101 110 146 94 123 362 378 344 281 204 232 181 205 488 221 45 67 50 104 289 114 5 6 -75 112 227 128 -171 -47 62 -118 32 92 48 59 -11 -147 -250 -218 -72 10 -127 -95 -220 -58 206 427 321 242 207 184 113 -86 165 -96 -115 -20 203 132 -99 -3 176 125 580 336 106 147 -13 -261 -26 31 -310 74 269 -70 -402 -187 71 -56 -15 -14 -20 42 37 129 -217 -142 20 -171 -238 -459 -207 -417 -187 38 -160 -225 -228 7 107 239 280 157 118 101 76 69 163 15 -91 -54 -70 -79 -76 -17 -308 -207 -72 -129 53 -204 -317 -287 -94 -61 -313 -344 -96 185 -71 -34 91 126 31 -194 16 -111 -134 -85 -150 -286 -225 -184 -29 -283 -495 -329 -133 29 253 99 110 145 94 125 367 383 348 282 202 231 179 202 479 218 44 66 49 102 281 111 5 6 -72 107 220 125 -167 -46 61 -117 32 91 48 58 -11 -145 -243 -212 -70 SQ 20260214T000212.3Z 9541.001531 159 1 6.42 2 67.85 135.66 70.88 179.83 0.00 1 0.00 1 0 15 2.033e-03 2.035e-03 2.807e-04 2.805e-04 1.325548e+03 1.683183e+01 9.051310e+01 -6.000000e+00 1.177939e+02 273.21 -2.00 20.00 -2.00 505.27 0.00e+00 8.328191e-04 7.797960e-06 4.653589e-05 -6.000000e+00 5.764108e-05 273.21 -2.00 20.00 -2.00 500.55 0.00e+00 2.045401e-01 5.739531e-03 1.484889e-02 -6.000000e+00 4.203622e-02 224.68 -2.00 3.56 -2.00 502.13 0.00e+00 2.630 0.000 489.00 513.00 1 3.2854e+00 4.4082e-04 4.0851e-03 -6.0000e+00 3.2296e-03 -1.5857e-02 1.1117e-04 3.6248e-04 -6.0000e+00 8.1822e-04 4.9222e-02 1.1536e-03 3.5429e-05 2.4069e-05 -6.0000e+00 2.6369e-04 1.2464e-02 -5.6049e-05 12 1 1 12 1 1 99.91 26.89 1.99 0.01246 0.02047 105 85 1 4 0 60.470 35.00 20.01 26.89 12.63 0.3 912.30 -106 -75 -47 -223 -110 248 376 332 283 154 170 110 -68 35 -58 -175 0 245 78 -104 36 191 245 431 289 123 269 -22 -285 -198 -48 -176 3 253 -121 -393 -132 50 -14 -41 80 -30 7 74 133 22 -17 10 -147 -262 -354 -347 -433 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