File name: Pandora279s1_Sapporo_20260308_L2Fit_fout2c2d20231207p1-8.txt File generation date: 20260308T145140.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v2d20231207.txt Level 1 file used: Pandora279s1_Sapporo_20260308_L1_smca1c2d20231207p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1196 305.2603 305.4009 305.5416 305.6822 305.8229 305.9635 306.1041 306.2447 306.3853 306.5259 306.6665 306.8070 306.9476 307.0881 307.2287 307.3692 307.5097 307.6502 307.7907 307.9311 308.0716 308.2120 308.3525 308.4929 308.6333 308.7737 308.9141 309.0545 309.1949 309.3353 309.4756 309.6160 309.7563 309.8966 310.0369 310.1772 310.3175 310.4578 310.5980 310.7383 310.8785 311.0188 311.1590 311.2992 311.4394 311.5796 311.7198 311.8599 312.0001 312.1402 312.2804 312.4205 312.5606 312.7007 312.8408 312.9809 313.1209 313.2610 313.4010 313.5411 313.6811 313.8211 313.9611 314.1011 314.2410 314.3810 314.5210 314.6609 314.8008 314.9408 315.0807 315.2206 315.3605 315.5003 315.6402 315.7801 315.9199 316.0597 316.1996 316.3394 316.4792 316.6189 316.7587 316.8985 317.0382 317.1780 317.3177 317.4574 317.5971 317.7368 317.8765 318.0162 318.1559 318.2955 318.4352 318.5748 318.7144 318.8540 318.9936 319.1332 319.2728 319.4123 319.5519 319.6914 319.8309 319.9705 320.1100 320.2495 320.3889 320.5284 320.6679 320.8073 320.9468 321.0862 321.2256 321.3650 321.5044 321.6438 321.7832 321.9225 322.0619 322.2012 322.3405 322.4798 322.6191 322.7584 322.8977 323.0370 323.1762 323.3155 323.4547 323.5939 323.7331 323.8723 324.0115 324.1507 324.2899 324.4290 324.5682 324.7073 324.8464 324.9855 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260308T004413.1Z 9563.030707 362 1 53.98 2 55.31 142.28 112.24 262.99 0.00 1 0.00 1 0 17 1.262e-01 1.603e-02 2.187e-02 3.391e-03 3.570186e-01 1.661943e-03 4.285017e-03 -6.000000e+00 6.959962e-02 225.59 -2.00 3.56 -2.00 318.21 0.00e+00 1.990022e-03 3.032093e-04 1.086225e-04 -6.000000e+00 3.014078e-03 274.72 -2.00 20.00 -2.00 317.63 0.00e+00 1.752 0.000 302.00 328.00 3 6.2084e+00 4.4476e-03 2.5491e-02 -6.0000e+00 1.7260e-01 4.7923e-02 5.0465e-03 1.8453e-02 -6.0000e+00 1.8852e-01 -1.7100e-02 3.3513e-03 9.1788e-03 -6.0000e+00 1.1191e-01 4.0255e-03 1.7594e-03 3.2012e-03 -6.0000e+00 4.7402e-02 1.1240e-04 6.3511e-04 9.2304e-05 2.9614e-05 -6.0000e+00 3.2110e-03 8.2398e-03 2.2997e-04 12 9 8 11 40 0 99.99 26.92 -0.04 0.00824 0.01301 28 3 1 5 0 1927.360 35.00 19.99 26.92 6.67 0.7 883.98 -43755 75853 30687 26704 -37072 -20317 -21127 43913 -6123 36916 -42271 -15936 42260 20801 23716 -7013 -10161 -10161 5305 2932 -7773 -1672 7993 12589 -3579 14567 3291 -10782 10676 14133 11277 -1824 -2705 -8260 619 -1251 9731 -7101 -2153 2723 -4085 -3548 -846 5026 806 2735 2484 3413 2231 -2989 2431 -106 1277 -316 3673 2498 -365 3486 -2379 76 -2698 118 3541 4083 -3339 663 -2861 -2456 1558 1910 1565 1337 475 -231 2609 -2080 -4416 -4736 1365 -1513 273 -319 -2960 -912 -1071 7 742 -633 -262 -1022 801 -356 2094 -975 -1571 -1543 1021 -291 780 685 -32 -515 300 -129 -1209 -432 -1412 246 210 2109 997 353 434 -5 185 -558 -1859 381 -1055 114 -729 1031 -39 1117 478 -253 2380 871 -682 58 1483 -1521 -1303 1035 -185 54 1612 -315 -407 302 -424 -682 -867 -3806 2157 1380 1122 -2648 -1243 -1425 1743 -441 1770 -4431 -1423 2516 1816 2353 -1039 -1633 -1731 809 475 -1401 -280 1279 2044 -715 2515 623 -2182 1670 2257 2066 -420 -696 -2221 139 -296 2330 -2169 -758 1050 -1804 -1623 -389 2182 366 1224 1098 1484 979 -1433 1201 -58 728 -194 2215 1558 -237 2139 -1509 47 -1809 84 2465 3019 -2579 452 -1935 -1661 1126 1569 1384 1213 425 -197 1959 -1458 -3193 -3402 1022 -1230 246 -318 -2952 -935 -1186 9 895 -791 -323 -1196 841 -376 2010 -976 -1607 -1769 1282 -383 1052 887 -42 -610 335 -154 -1585 -585 -1883 340 309 3292 1553 555 697 -8 254 -738 -2536 535 -1615 182 -1159 1570 -58 1565 642 -351 3068 1191 -963 87 2325 -2524 -2059 1679 -324 98 2930 -597 -764 540 -730 -1126 -1410 SS 20260308T012255.8Z 9563.057590 387 1 6.01 2 51.52 153.34 119.10 269.09 0.00 1 0.00 1 0 25 5.234e-02 4.513e-02 2.110e-02 6.572e-03 3.406051e-01 3.227408e-03 4.106205e-03 -6.000000e+00 2.883860e-02 225.59 -2.00 3.56 -2.00 317.23 0.00e+00 1.374269e-04 4.498909e-04 9.760085e-04 -6.000000e+00 1.249451e-03 274.72 -2.00 20.00 -2.00 316.64 0.00e+00 1.604 0.000 302.00 328.00 3 5.1841e+00 8.4776e-03 2.3565e-02 -6.0000e+00 7.1517e-02 2.1367e-02 9.5672e-03 1.7303e-02 -6.0000e+00 7.8140e-02 -3.8264e-02 5.7947e-03 8.3176e-03 -6.0000e+00 4.6387e-02 3.5532e-02 2.8875e-03 2.4772e-03 -6.0000e+00 1.9633e-02 3.7608e-04 5.1204e-04 1.7587e-04 2.3529e-05 -6.0000e+00 1.3325e-03 1.0391e-02 3.8714e-05 12 9 9 12 1 1 999.00 26.92 -0.42 0.01039 0.01424 1 2 1 5 0 3000.560 35.00 20.00 26.92 7.31 0.6 886.87 -15777 20651 1266 5664 -2624 -21089 -8407 22695 29 1663 -17599 -6308 19645 3979 6355 1705 -1650 -3303 -627 4804 -2265 1680 2937 4314 -170 7360 1091 292 -4516 2427 -399 -2218 -481 -6067 -3479 -793 1693 -1239 -1456 2591 -2958 -1156 567 -702 764 367 -131 214 -224 -2642 270 864 355 -69 249 1003 -1046 472 -222 -977 -2274 1073 1210 2921 -612 1325 -2975 -2353 1783 480 2637 795 -217 687 94 -1844 -3236 -1706 563 -478 -258 -994 -1486 -408 528 -455 1144 1061 191 206 675 1034 1003 1645 1611 806 1658 2451 1378 453 1154 547 1495 2431 99 933 756 1657 1710 2361 -27634 1960 1866 2027 1178 2175 1521 2404 816 1155 584 869 979 726 2082 434 2688 2102 2148 121 2066 153 63 506 -303 -241 661 395 -442 -622 -266 -1344 -1920 -1838 1959 144 548 -249 -2460 -954 2138 4 216 -2492 -966 2720 682 1226 373 -388 -831 -160 1198 -603 427 780 1206 -52 2166 331 82 -1268 667 -125 -707 -165 -2155 -1104 -255 601 -540 -711 1392 -1662 -662 327 -408 438 211 -74 119 -125 -1561 169 574 235 -48 179 731 -788 343 -158 -703 -1743 869 1006 2532 -529 1028 -2311 -1830 1487 434 2498 785 -211 626 83 -1479 -2594 -1336 448 -441 -251 -1015 -1602 -458 600 -555 1361 1290 231 247 736 1087 1041 1720 1751 936 2034 3152 1847 586 1439 657 1702 2942 126 1226 995 2273 2379 3525 -49630 2954 2802 2948 1586 2917 1992 3292 1164 1719 869 1256 1436 1012 2858 577 3331 2741 2908 178 3010 232 98 787 -484 -400 1102 674 -752 -1013 -431 -2106 -2979 SS 20260308T024939.9Z 9563.117823 446 1 54.86 2 48.00 181.40 134.33 284.61 0.00 1 0.00 1 0 25 1.135e-02 5.868e-03 8.167e-04 3.933e-04 3.143201e-01 1.936137e-04 3.830781e-03 -6.000000e+00 6.256174e-03 225.60 -2.00 3.56 -2.00 316.29 0.00e+00 4.286992e-04 2.143001e-05 5.216914e-05 -6.000000e+00 2.710304e-04 274.72 -2.00 20.00 -2.00 315.73 0.00e+00 1.492 0.000 302.00 328.00 3 2.7927e+00 5.0079e-04 2.2007e-02 -6.0000e+00 1.5515e-02 1.4592e-02 5.6308e-04 1.5961e-02 -6.0000e+00 1.6951e-02 -8.3974e-03 3.2730e-04 7.9314e-03 -6.0000e+00 1.0062e-02 1.1080e-03 1.5408e-04 2.2627e-03 -6.0000e+00 4.2595e-03 4.7984e-03 1.0603e-04 1.0417e-05 2.4952e-05 -6.0000e+00 2.8899e-04 1.0157e-02 7.9875e-05 10 0 0 10 0 0 99.95 26.98 0.30 0.01016 0.01095 300 28 1 5 0 182.840 35.00 20.01 26.98 8.28 0.6 891.61 -2398 -806 -1343 -4231 -5568 -4528 -2536 -565 -1138 -1782 -3817 -2308 -324 236 1257 -21 250 531 1210 1379 636 815 1134 812 601 1165 225 -819 -484 979 1096 1488 1267 -1379 -2203 -2101 -1247 -1032 -75 -12 -451 -482 -195 -76 76 -94 -202 -182 -259 345 942 589 927 942 830 860 582 394 306 399 947 1265 1603 1367 -90 -287 -832 -494 271 465 357 -41 155 126 -10 -352 -919 -899 -507 -908 -921 -1379 -2052 -1589 -1030 -534 -332 206 485 268 416 66 155 223 213 126 665 591 68 -231 -343 -522 -515 -123 -595 -689 -593 -398 120 321 390 440 330 143 38 112 54 148 71 -69 -120 142 331 362 636 304 723 849 454 390 128 113 -167 -9 30 -295 139 26 -153 -278 -264 -404 -654 -435 -154 -257 -741 -964 -790 -478 -109 -244 -392 -843 -549 -82 64 391 -7 83 184 434 512 237 301 414 317 247 465 93 -316 -177 367 449 626 586 -609 -947 -934 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