File name: Pandora279s1_Sapporo_20260402_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260626T173113.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260402_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260402 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260402T002403.6Z 9588.016709 370 1 27.50 2 48.38 132.51 135.21 313.03 0.00 1 0.00 1 0 25 3.166e-02 4.391e-02 5.487e-03 2.301e-03 2.758937e-01 1.139562e-03 3.312461e-03 -6.000000e+00 1.755996e-02 227.25 -2.00 3.56 -2.00 316.60 0.00e+00 -4.009973e-04 1.364448e-04 7.532554e-04 -6.000000e+00 7.637909e-04 277.16 -2.00 20.00 -2.00 315.98 0.00e+00 1.503 0.000 302.00 328.00 3 5.5540e+00 2.9759e-03 2.0386e-02 -6.0000e+00 4.3678e-02 -1.4496e-03 3.3436e-03 1.3654e-02 -6.0000e+00 4.7645e-02 -1.9207e-02 1.9577e-03 6.5977e-03 -6.0000e+00 2.8287e-02 2.4656e-02 9.3352e-04 1.9143e-03 -6.0000e+00 1.1949e-02 3.2242e-04 8.2459e-04 6.2173e-05 2.1119e-05 -6.0000e+00 8.0638e-04 1.0478e-02 0.0000e+00 12 9 9 12 9 1 94.72 26.69 0.05 0.01048 0.01667 8 2 1 5 0 3054.280 34.75 19.98 26.69 14.39 0.2 918.60 -6165 6735 6364 1846 -2557 1714 -10301 4830 -1596 2168 -4169 -757 6902 2271 4480 -247 -942 -3438 368 1304 -268 -987 743 394 -1203 3540 922 1031 359 4046 3398 -590 275 -3067 -1363 -2249 1492 -3274 -217 1621 -2180 -1353 -1389 359 -668 138 -1249 -1625 -113 -778 651 -507 232 -32 1080 337 -332 985 -741 301 67 371 1146 1061 -559 -671 -2047 -1512 312 1202 814 455 705 642 303 -827 -1758 -1366 494 -112 -314 -329 -1696 -378 -3 754 916 773 732 1081 946 616 1329 1161 816 1134 2102 2030 1776 1266 1185 556 917 1235 64 688 713 1712 1733 1957 -27878 2285 1703 1457 1460 914 1505 1563 1582 1415 675 1723 919 785 1698 517 1993 1806 1451 959 1228 463 561 1017 492 63 653 46 -544 -411 -726 -1435 -1902 -1015 1029 962 284 -368 241 -1635 822 -290 383 -765 -145 1402 552 1210 -75 -295 -1055 113 408 -85 -312 243 138 -448 1295 335 342 123 1373 1149 -224 113 -1265 -505 -873 632 -1595 -124 963 -1427 -908 -955 241 -451 92 -820 -1047 -71 -503 448 -350 168 -25 832 267 -269 773 -578 233 55 308 1025 998 -509 -556 -1740 -1278 270 1105 803 462 699 605 277 -681 -1429 -1084 422 -103 -304 -350 -1809 -418 -4 901 1142 986 924 1278 1080 644 1349 1186 862 1328 2576 2613 2354 1609 1473 672 1064 1460 83 876 952 2370 2413 2914 -49093 3353 2492 1969 1897 1203 1908 2092 2176 2053 986 2438 1273 1082 2203 678 2455 2318 1920 1356 1726 667 823 1558 771 98 1032 75 -882 -667 -1139 -2178 -2862 SS 20260402T002854.9Z 9588.020080 373 1 54.39 2 47.73 133.89 135.84 314.42 0.00 1 0.00 1 0 17 1.234e-02 6.303e-03 2.067e-03 1.011e-03 2.660085e-01 4.997879e-04 3.231021e-03 -6.000000e+00 6.845509e-03 227.25 -2.00 3.56 -2.00 316.21 0.00e+00 3.619283e-04 5.489682e-05 4.682269e-05 -6.000000e+00 2.977647e-04 277.16 -2.00 20.00 -2.00 315.61 0.00e+00 1.484 0.000 302.00 328.00 3 4.8409e+00 1.2987e-03 2.0276e-02 -6.0000e+00 1.7027e-02 7.3641e-03 1.4573e-03 1.3652e-02 -6.0000e+00 1.8575e-02 -1.5787e-03 8.4227e-04 6.7254e-03 -6.0000e+00 1.1028e-02 -3.1779e-03 3.9322e-04 1.8991e-03 -6.0000e+00 4.6579e-03 6.8022e-04 4.4029e-04 2.7080e-05 2.0722e-05 -6.0000e+00 3.1440e-04 1.1266e-02 0.0000e+00 10 0 0 10 0 0 99.08 26.70 0.38 0.01127 0.01457 41 4 1 5 0 1326.350 34.75 20.03 26.70 14.49 0.2 919.59 -6278 1217 -218 -810 -4099 -772 -5303 2559 -1389 -1110 -4916 -2991 1313 855 1758 -125 -1017 -1521 1116 977 365 741 838 354 -578 1497 215 -160 910 2034 2296 719 782 -702 -1633 -1580 460 -1841 -201 638 -1127 -732 -882 251 35 -268 -640 -292 149 214 762 290 702 793 921 990 461 988 224 259 651 1164 1519 1321 -349 -378 -928 -865 326 669 625 49 497 563 141 -558 -1254 -1278 -43 -1000 -1078 -1119 -2121 -1381 -1038 -315 -123 143 571 380 171 -183 424 67 -123 -122 723 466 180 8 -378 -536 -390 -24 -755 -807 -732 -12 124 468 597 456 287 -22 -136 -246 -239 175 167 -21 -211 311 86 320 731 64 880 834 483 419 318 -66 -320 104 75 -195 299 116 -135 -218 -214 -605 -732 -1311 250 -45 -149 -699 -129 -1020 515 -293 -237 -1060 -682 330 248 531 -41 -348 -547 405 367 138 276 327 137 -236 617 87 -64 340 774 942 300 355 -316 -677 -678 219 -992 -120 408 -777 -520 -608 181 25 -193 -449 -199 100 146 528 215 546 613 725 795 377 789 176 205 539 989 1398 1219 -328 -322 -793 -736 289 641 611 50 489 551 133 -495 -1026 -1022 -37 -946 -1084 -1179 -2261 -1536 -1192 -383 -150 177 698 456 196 -201 426 68 -136 -142 897 591 236 10 -458 -621 -453 -28 -947 -1054 -964 -17 172 669 889 675 402 -29 -181 -313 -310 230 228 -30 -306 440 118 432 971 82 1102 1042 629 581 445 -94 -467 153 114 -309 479 185 -214 -344 -326 -922 -1105 SS 20260402T003408.6Z 9588.023711 376 1 55.01 2 47.05 135.40 136.50 315.94 0.00 1 0.00 1 0 25 1.322e-02 6.776e-03 2.066e-03 1.026e-03 2.629611e-01 5.070044e-04 3.181820e-03 -6.000000e+00 7.328463e-03 227.26 -2.00 3.56 -2.00 316.17 0.00e+00 1.043704e-04 5.502980e-05 5.332819e-05 -6.000000e+00 3.187810e-04 277.16 -2.00 20.00 -2.00 315.57 0.00e+00 1.465 0.000 302.00 328.00 3 4.9020e+00 1.3157e-03 2.0003e-02 -6.0000e+00 1.8229e-02 5.8690e-03 1.4776e-03 1.3445e-02 -6.0000e+00 1.9886e-02 -3.1727e-03 8.5367e-04 6.6273e-03 -6.0000e+00 1.1806e-02 -9.8431e-04 3.9754e-04 1.8524e-03 -6.0000e+00 4.9863e-03 6.5628e-04 4.2762e-04 2.7338e-05 2.0217e-05 -6.0000e+00 3.3661e-04 1.1780e-02 0.0000e+00 11 9 0 11 32 0 99.51 26.71 0.22 0.01178 0.01499 38 4 1 5 0 1447.470 35.00 20.01 26.71 14.72 0.2 920.83 -5540 750 212 -473 -4265 -1787 -6519 2248 -1141 85 -5334 -4005 1977 1333 1684 -931 -443 -1806 629 1208 414 856 820 876 -304 1791 639 355 1314 2325 2240 601 1152 -1382 -1703 -1642 783 -2351 -184 -303 -1148 -968 -568 88 -9 -285 -488 -410 -134 -25 851 306 1001 1016 1126 989 255 679 533 458 629 820 1303 1607 -497 -155 -760 -807 394 693 432 33 225 646 215 -268 -1369 -1134 -443 -820 -947 -1175 -2079 -1336 -876 25 -229 210 466 299 221 -110 391 59 -68 -218 737 438 343 10 -278 -565 -277 -8 -732 -599 -651 -12 273 721 -1515 432 248 125 -61 -276 -241 341 202 183 -161 351 209 385 689 123 1077 896 555 442 396 11 -233 271 -37 -42 443 139 -262 -252 -389 -676 -902 -1087 146 45 -89 -750 -311 -1309 468 -248 18 -1191 -950 507 394 520 -316 -154 -663 233 461 159 324 326 343 -126 750 262 144 496 894 930 254 527 -631 -713 -712 375 -1285 -111 -198 -799 -696 -393 60 -6 -206 -343 -281 -90 -17 625 227 778 785 887 797 210 545 419 362 521 700 1203 1479 -467 -132 -647 -685 349 662 443 33 222 632 202 -237 -1120 -904 -384 -771 -948 -1233 -2207 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