File name: Pandora279s1_Sapporo_20260410_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260626T173422.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260410_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260410 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260410T002814.7Z 9596.019614 308 1 53.97 2 44.96 132.10 87.35 228.49 0.00 1 0.00 1 0 17 2.990e-02 4.444e-02 2.437e-03 1.379e-03 2.314342e-01 6.873702e-04 2.786930e-03 -6.000000e+00 1.662552e-02 227.88 -2.00 3.56 -2.00 315.76 0.00e+00 -1.144340e-04 6.782318e-05 5.237515e-04 -6.000000e+00 7.239895e-04 278.05 -2.00 20.00 -2.00 315.17 0.00e+00 1.411 0.000 302.00 328.00 3 5.4940e+00 1.7773e-03 1.8130e-02 -6.0000e+00 4.1402e-02 3.5994e-02 1.9897e-03 1.1239e-02 -6.0000e+00 4.5129e-02 -2.0760e-02 1.1409e-03 5.4747e-03 -6.0000e+00 2.6793e-02 2.4417e-02 5.1767e-04 1.6551e-03 -6.0000e+00 1.1316e-02 3.9957e-04 5.7387e-04 3.7077e-05 2.1120e-05 -6.0000e+00 7.6143e-04 7.8703e-03 0.0000e+00 12 8 8 10 0 0 99.90 27.12 0.08 0.00787 0.01218 24 2 1 5 0 2248.360 35.25 20.00 27.12 19.29 0.0 940.64 -3636 5866 3813 5105 -2258 381 -5855 4415 223 2578 -4220 -678 4443 2920 1593 -1346 -478 -2167 1242 753 35 -458 1128 572 -154 2364 587 -1061 631 2827 1628 -167 -6 -1108 -2277 -1944 607 -2934 -323 719 -1858 -1359 -1383 240 -1288 -627 -2117 -1638 -541 -1411 84 -526 581 207 843 699 -97 306 -263 190 -272 351 1251 1417 -615 -542 -851 -692 767 1101 936 207 739 453 567 -103 -1418 -1629 779 -430 -135 -327 -1374 -526 -16 692 1070 980 1313 898 821 440 1538 1108 935 1196 2471 1909 1707 1516 914 529 1097 1374 637 550 633 1482 1628 1993 -28913 2021 1601 1487 1247 1253 1315 1735 1607 1196 807 1564 1127 1075 1483 565 2062 1788 1303 1027 1110 763 517 1103 378 259 566 219 -448 -441 -813 -1427 -1743 -961 1479 964 1122 -475 78 -1404 1077 62 707 -1193 -196 1267 955 594 -547 -196 -864 493 310 14 -187 474 255 -72 1109 271 -453 267 1189 682 -76 -3 -535 -1012 -887 305 -1672 -202 505 -1327 -995 -1035 176 -952 -456 -1612 -1204 -383 -1026 65 -403 463 173 714 603 -81 264 -223 161 -228 317 1209 1351 -568 -477 -752 -604 687 1054 962 220 767 449 543 -88 -1190 -1328 674 -401 -132 -351 -1475 -588 -18 836 1348 1204 1672 1080 950 464 1551 1116 1022 1366 2938 2396 2207 1874 1109 622 1239 1667 803 687 828 2005 2204 2865 -49833 2986 2241 2004 1614 1545 1649 2286 2184 1649 1122 2116 1559 1407 1925 702 2522 2149 1690 1347 1515 1061 731 1547 569 389 860 343 -701 -663 -1185 -2104 -2540 SS 20260410T003329.8Z 9596.023262 311 1 54.88 2 44.26 133.66 88.05 229.39 0.00 1 0.00 1 0 17 7.949e-03 5.707e-03 8.120e-04 5.258e-04 2.180910e-01 2.624172e-04 2.666786e-03 -6.000000e+00 4.420634e-03 227.88 -2.00 3.56 -2.00 315.24 0.00e+00 3.259289e-04 2.335095e-05 2.749373e-05 -6.000000e+00 1.925043e-04 278.05 -2.00 20.00 -2.00 314.68 0.00e+00 1.394 0.000 302.00 328.00 3 3.7574e+00 6.7453e-04 1.7958e-02 -6.0000e+00 1.1008e-02 2.8994e-02 7.5379e-04 1.1236e-02 -6.0000e+00 1.2000e-02 -3.8446e-03 4.3109e-04 5.5201e-03 -6.0000e+00 7.1241e-03 -1.9604e-03 1.9201e-04 1.5510e-03 -6.0000e+00 3.0088e-03 2.3803e-03 3.1199e-04 1.3985e-05 1.8281e-05 -6.0000e+00 2.0246e-04 7.8300e-03 0.0000e+00 10 0 0 10 0 0 99.90 27.13 0.31 0.00783 0.01017 263 25 1 5 0 208.620 35.25 20.00 27.13 19.51 0.0 942.03 -1667 585 -725 -1916 -2736 -1947 -1719 873 -17 -148 -2179 -884 -27 84 734 -70 73 166 1109 1161 759 901 1065 574 425 867 269 -579 -22 1139 1124 1112 1232 -924 -2153 -1874 -1018 -1524 -332 -88 -784 -720 -602 -190 -231 -415 -814 -680 -426 -20 776 535 782 980 795 763 518 364 315 508 798 1066 1528 1287 4 -257 -728 -528 344 537 292 25 388 239 257 -91 -799 -995 -443 -818 -797 -1301 -1852 -1353 -903 -439 -189 283 560 188 307 -1 115 113 118 109 614 636 101 -196 -318 -551 -434 -33 -580 -661 -687 -269 6 348 554 324 161 48 -130 -5 -68 147 162 28 -176 107 223 439 617 136 629 762 398 378 226 164 -116 21 53 -216 177 80 -123 -240 -256 -478 -654 -496 179 -221 -564 -722 -512 -492 274 -5 -48 -698 -296 -10 33 305 -31 33 78 530 573 375 438 539 289 223 466 141 -280 -10 542 570 566 677 -505 -1083 -967 -554 -932 -229 -65 -595 -563 -481 -150 -183 -325 -619 -524 -319 -15 594 435 637 834 688 672 444 320 272 439 691 996 1473 1251 4 -235 -654 -468 320 522 305 26 408 240 246 -81 -678 -854 -392 -788 -788 -1361 -2037 -1498 -1039 -518 -233 355 696 228 353 -1 118 115 125 123 737 788 129 -249 -389 -642 -488 -39 -713 -847 -892 -351 8 489 785 455 220 64 -164 -6 -83 189 218 39 -239 147 298 571 785 170 747 930 506 493 307 219 -157 29 76 -322 261 121 -185 -360 -372 -691 -934 SS 20260410T025104.7Z 9596.118805 404 1 53.66 2 35.31 186.45 108.84 250.98 0.00 1 0.00 1 0 17 3.700e-02 5.741e-02 2.763e-03 1.686e-03 2.048370e-01 8.431374e-04 2.630289e-03 -6.000000e+00 2.058327e-02 227.89 -2.00 3.56 -2.00 315.47 0.00e+00 -1.232678e-04 7.824918e-05 6.385668e-04 -6.000000e+00 8.962072e-04 278.06 -2.00 20.00 -2.00 314.90 0.00e+00 1.225 0.000 302.00 328.00 3 6.0620e+00 2.1718e-03 1.5652e-02 -6.0000e+00 5.1258e-02 1.7111e-02 2.4273e-03 9.5796e-03 -6.0000e+00 5.5868e-02 -2.3359e-02 1.3888e-03 4.6918e-03 -6.0000e+00 3.3168e-02 3.1113e-02 6.2129e-04 1.5683e-03 -6.0000e+00 1.4012e-02 2.8759e-04 5.1202e-04 4.5350e-05 2.5396e-05 -6.0000e+00 9.4234e-04 5.9318e-03 0.0000e+00 12 8 8 10 0 0 95.04 27.27 -0.11 0.00593 0.00978 15 1 1 5 0 3576.920 35.25 20.00 27.27 21.47 0.0 950.54 -2786 8495 4421 2879 -82 313 -6141 6581 -1371 2789 -5758 1547 4695 2665 1963 -272 -1178 -2574 2760 561 -408 -542 497 490 359 2010 1299 -651 -252 1950 1379 -687 291 -2631 -2072 -2152 1007 -3776 -726 1024 -1978 -1571 -1443 486 -1745 -1209 -2779 -1698 -770 -1438 -200 -852 431 755 885 1002 -373 115 -26 145 -188 113 1278 1447 -549 -766 -1341 -871 521 1389 1421 185 1347 477 590 -489 -1763 -2121 1441 -322 96 -392 -1159 -248 101 1641 1825 1374 1627 1265 939 318 1684 1620 1218 1390 2390 2296 2427 2414 1352 988 1860 1607 1011 1007 1157 1704 2166 2598 -36391 2699 2079 2077 1758 1537 1352 1793 2175 1761 1492 2098 1484 1390 1708 1079 2611 2064 1366 1199 1916 732 932 1327 606 533 908 246 -391 -516 -1076 -1720 -2297 -834 2371 1258 732 -19 72 -1645 1745 -430 844 -1816 475 1570 935 774 -116 -511 -1167 1219 261 -191 -249 235 244 171 969 660 -307 -109 834 627 -338 153 -1382 -981 -1047 534 -2282 -474 748 -1467 -1193 -1118 366 -1337 -911 -2198 -1283 -559 -1063 -156 -659 346 630 749 861 -329 99 -22 123 -167 102 1222 1441 -530 -708 -1166 -743 483 1360 1490 190 1429 488 551 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