File name: Pandora279s1_Sapporo_20260517_L2Fit_fwvt1c2d20231207p1-8.txt File generation date: 20260517T143945.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v2d20231207.txt Level 1 file used: Pandora279s1_Sapporo_20260517_L1_smca1c2d20231207p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 1619 1768 Nominal wavelengths inside fitting window [nm]: 492.1003 492.2211 492.3420 492.4628 492.5836 492.7044 492.8252 492.9460 493.0667 493.1874 493.3081 493.4288 493.5495 493.6702 493.7908 493.9114 494.0320 494.1526 494.2732 494.3938 494.5143 494.6348 494.7553 494.8758 494.9963 495.1168 495.2372 495.3576 495.4780 495.5984 495.7188 495.8391 495.9595 496.0798 496.2001 496.3204 496.4407 496.5609 496.6811 496.8014 496.9216 497.0418 497.1619 497.2821 497.4022 497.5223 497.6424 497.7625 497.8826 498.0026 498.1226 498.2427 498.3627 498.4826 498.6026 498.7225 498.8425 498.9624 499.0823 499.2021 499.3220 499.4419 499.5617 499.6815 499.8013 499.9210 500.0408 500.1605 500.2803 500.4000 500.5197 500.6393 500.7590 500.8786 500.9982 501.1178 501.2374 501.3570 501.4765 501.5961 501.7156 501.8351 501.9546 502.0740 502.1935 502.3129 502.4323 502.5517 502.6711 502.7905 502.9098 503.0291 503.1484 503.2677 503.3870 503.5063 503.6255 503.7447 503.8639 503.9831 504.1023 504.2215 504.3406 504.4597 504.5788 504.6979 504.8170 504.9360 505.0550 505.1741 505.2931 505.4120 505.5310 505.6500 505.7689 505.8878 506.0067 506.1256 506.2444 506.3633 506.4821 506.6009 506.7197 506.8385 506.9572 507.0760 507.1947 507.3134 507.4321 507.5507 507.6694 507.7880 507.9066 508.0252 508.1438 508.2624 508.3809 508.4994 508.6180 508.7365 508.8549 508.9734 509.0918 509.2103 509.3287 509.4470 509.5654 509.6838 509.8021 509.9204 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260517T001946.8Z 9633.013736 238 1 14.46 2 36.39 120.43 34.05 112.05 0.00 1 0.00 1 0 15 3.687e-03 3.731e-03 2.087e-03 2.083e-03 1.388571e+03 1.305833e+02 9.537679e+01 -6.000000e+00 2.214285e+02 282.19 -2.00 20.00 -2.00 505.24 0.00e+00 2.230669e-04 5.902906e-05 1.132321e-05 -6.000000e+00 1.067950e-04 282.19 -2.00 20.00 -2.00 500.39 0.00e+00 1.215970e-03 4.304128e-02 1.120035e-02 -6.000000e+00 7.653402e-02 231.10 -2.00 3.56 -2.00 501.99 0.00e+00 1.241 0.000 489.00 513.00 1 7.7391e+00 3.3138e-03 2.0230e-03 -6.0000e+00 5.8935e-03 6.5939e-03 8.3810e-04 2.7386e-04 -6.0000e+00 1.4947e-03 7.1282e-04 3.4098e-03 2.6168e-04 7.7816e-06 -6.0000e+00 4.7886e-04 1.8276e-02 -1.4256e-04 12 1 1 12 1 1 99.60 28.01 2.07 0.01828 0.04193 3 1 1 4 0 3613.720 35.75 20.00 28.01 19.29 0.0 940.43 -108 -117 -207 -241 447 208 373 -1590 533 -35 -223 163 -150 -6 -294 -145 100 226 389 24 -124 346 -51 763 142 -168 -117 -466 -105 162 602 -251 239 590 -20 -526 68 449 -499 -424 -121 115 362 447 335 -105 -422 280 -284 561 -578 -237 -707 -201 439 -900 353 0 -362 535 161 738 -201 91 403 21 125 279 -290 -274 310 -146 -110 -284 324 -276 -248 281 -149 863 -261 -315 -846 -212 -29 10 -674 -243 923 -126 1 300 457 632 -253 -7 -430 -264 320 242 -139 50 -572 67 -362 -433 -245 -89 329 78 102 -101 106 4 -27 84 125 625 328 238 135 42 -307 241 -243 260 198 -627 425 238 453 346 -193 -438 -4 26 -47 -438 -280 -93 -234 -3 107 -73 86 -14 -414 146 -124 263 -106 -118 -213 -248 469 217 394 -1720 562 -37 -231 170 -154 -6 -301 -149 102 235 411 25 -130 363 -53 800 150 -176 -122 -491 -108 163 612 -254 245 617 -21 -554 71 461 -514 -434 -124 118 374 464 350 -110 -439 285 -292 557 -568 -234 -700 -200 434 -921 362 0 -369 542 164 748 -205 92 404 21 125 275 -284 -267 300 -143 -108 -281 319 -271 -240 269 -142 834 -250 -304 -828 -209 -29 10 -662 -239 898 -124 1 301 460 634 -254 -7 -416 -256 303 228 -132 49 -555 66 -354 -425 -243 -88 323 77 100 -100 106 4 -28 84 125 631 329 236 133 40 -299 234 -237 252 192 -611 409 227 438 331 -184 -416 -4 25 -45 -425 -275 -92 -228 -3 105 -72 84 -13 -405 139 -118 248 SQ 20260517T002852.7Z 9633.020054 241 1 22.97 2 34.97 123.20 32.55 114.49 0.00 1 0.00 1 0 15 3.626e-03 3.640e-03 1.512e-03 1.509e-03 1.303515e+03 9.421666e+01 8.933858e+01 -6.000000e+00 2.178398e+02 282.19 -2.00 20.00 -2.00 505.25 0.00e+00 2.533091e-04 4.276325e-05 1.261138e-05 -6.000000e+00 1.049859e-04 282.19 -2.00 20.00 -2.00 500.43 0.00e+00 -3.862698e-03 3.118852e-02 1.165689e-02 -6.000000e+00 7.502024e-02 231.10 -2.00 3.56 -2.00 502.02 0.00e+00 1.220 0.000 489.00 513.00 1 7.6747e+00 2.4027e-03 2.0141e-03 -6.0000e+00 5.7808e-03 7.1149e-03 6.0664e-04 2.7673e-04 -6.0000e+00 1.4589e-03 7.6286e-04 -2.2601e-03 1.9025e-04 7.0755e-06 -6.0000e+00 4.7028e-04 -5.6291e-03 2.8115e-04 12 1 1 12 1 1 99.74 28.02 2.15 -0.00563 -0.02131 5 1 1 4 0 3826.870 36.00 20.00 28.02 19.61 0.0 940.98 204 -78 38 -527 74 52 360 -1597 162 96 62 -254 17 86 -47 -271 394 121 100 -160 -350 422 211 663 206 110 209 -240 -299 66 45 10 40 418 -180 -360 398 305 -231 -55 -83 -114 292 650 368 -151 -118 264 -520 456 -490 -86 -751 -404 395 -790 -5 -183 -105 718 180 365 -98 74 348 119 -47 386 55 -175 259 45 -196 -611 143 -395 -439 521 21 743 -564 -143 -694 -283 112 -646 -47 -171 781 74 200 466 223 835 -338 -32 -597 193 -111 -26 -136 165 -372 -111 -440 -527 -650 -235 182 674 27 77 -292 307 -3 265 184 253 181 427 292 -50 -108 640 15 -252 370 -283 20 328 474 -163 -42 -677 223 50 47 -425 180 273 50 -367 -34 67 62 28 -169 -153 -478 -144 201 -79 38 -548 77 55 383 -1699 172 101 65 -261 17 89 -48 -276 404 127 104 -168 -371 444 223 700 218 116 218 -248 -309 67 45 10 41 430 -189 -380 415 316 -238 -56 -85 -118 303 677 386 -158 -123 270 -525 455 -483 -85 -730 -396 393 -794 -5 -187 -107 730 184 373 -101 76 351 119 -46 382 54 -171 251 44 -193 -610 141 -390 -429 499 20 706 -545 -139 -682 -274 109 -635 -46 -168 765 73 200 459 221 822 -333 -32 -582 188 -106 -24 -130 159 -362 -110 -434 -520 -638 -228 179 651 27 77 -295 304 -3 265 184 252 179 425 287 -49 -105 620 15 -247 359 -276 20 316 451 -154 -40 -648 212 47 45 -415 177 265 49 -363 -33 67 61 27 -162 -147 -457 -137 SQ 20260517T003742.5Z 9633.026187 245 1 11.25 2 33.65 126.05 31.12 117.00 0.00 1 0.00 1 0 15 3.330e-03 3.336e-03 1.890e-03 1.887e-03 1.267416e+03 1.178306e+02 7.881108e+01 -6.000000e+00 1.999957e+02 282.19 -2.00 20.00 -2.00 505.25 0.00e+00 1.769224e-04 5.345701e-05 1.096939e-05 -6.000000e+00 9.642104e-05 282.19 -2.00 20.00 -2.00 500.40 0.00e+00 3.807012e-02 3.899740e-02 1.258938e-02 -6.000000e+00 6.899974e-02 231.10 -2.00 3.56 -2.00 502.00 0.00e+00 1.200 0.000 489.00 513.00 1 7.3324e+00 3.0043e-03 2.0152e-03 -6.0000e+00 5.3152e-03 8.6442e-03 7.5894e-04 2.8172e-04 -6.0000e+00 1.3446e-03 1.0750e-03 3.5111e-04 2.3768e-04 4.8538e-06 -6.0000e+00 4.3229e-04 5.9950e-03 7.6999e-05 12 1 1 12 1 1 99.93 28.03 2.22 0.00599 0.00843 3 2 1 4 0 2812.400 36.00 20.00 28.03 19.79 0.0 942.96 -255 -492 -36 -333 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