File name: Pandora279s1_Sapporo_20260518_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260626T174952.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260518_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260518 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260517T203027.4Z 9633.854484 85 1 54.59 2 76.95 75.42 82.61 60.52 0.00 1 0.00 1 0 17 3.043e-01 1.175e-02 9.795e-02 1.709e-03 6.047637e-01 8.690899e-04 6.844252e-03 -6.000000e+00 1.711986e-01 231.15 -2.00 3.56 -2.00 320.09 0.00e+00 2.234475e-03 2.924783e-04 3.945284e-04 -6.000000e+00 7.497461e-03 282.27 -2.00 20.00 -2.00 319.43 0.00e+00 4.314 0.001 302.00 328.00 3 2.6152e+00 2.5618e-03 5.3750e-02 -6.0000e+00 4.2909e-01 6.9148e-02 3.1394e-03 3.2159e-02 -6.0000e+00 4.6630e-01 -1.4141e-01 2.7866e-03 1.6065e-02 -6.0000e+00 2.7677e-01 5.6825e-02 1.4257e-03 5.5335e-03 -6.0000e+00 1.1645e-01 2.7536e-04 3.5509e-05 4.4223e-05 5.1623e-05 -6.0000e+00 7.7572e-03 1.1326e-02 0.0000e+00 12 8 8 10 0 0 99.94 27.69 0.38 0.01133 0.01159 97 9 1 5 0 562.750 35.75 20.00 27.69 17.91 0.0 933.94 -139313 93148 75396 100157 -150922 -70413 -124091 77544 -68413 -42382 -116585 -68382 -20582 -945 -34178 -33540 -5623 -29741 10209 -12100 8985 -28737 -10465 -16813 -19325 3677 -14352 -35881 3196 -707 -2186 -14193 -3019 -4061 -1208 3575 10189 -9760 -1370 16063 4520 70 -881 9771 2174 4624 2937 4479 8156 -1533 5827 2964 -174 314 5694 3214 558 1067 -926 67 -1476 673 2672 3807 517 1801 -1251 -1499 1023 2239 1789 1092 1209 525 1744 -1239 -3257 -1990 -414 -577 -1053 -853 -2446 -1618 -750 231 534 349 666 282 282 -333 432 -753 -1180 -744 205 445 -32 -218 -792 -913 -474 30 -869 -656 -1029 -166 46 788 -3308 513 417 49 -63 -106 202 749 124 212 191 829 468 679 876 444 867 823 646 300 409 -44 -226 406 -133 -146 573 -28 -364 -393 -193 -699 -587 -3599 264 264 250 -4276 -927 -3123 297 -1266 -636 -3828 -1653 -394 -19 -1168 -1314 -184 -1358 333 -518 313 -1466 -481 -899 -1130 180 -832 -2452 148 -39 -145 -1237 -270 -370 -99 293 898 -1272 -203 2345 735 13 -167 1686 411 872 573 890 1630 -365 1454 839 -55 108 1934 1163 194 395 -339 24 -528 264 1171 1824 256 842 -603 -757 530 1319 1141 718 770 314 929 -661 -1695 -1065 -233 -386 -759 -694 -2017 -1400 -694 225 507 339 638 273 253 -282 377 -656 -1179 -801 237 552 -42 -276 -984 -1017 -523 35 -1042 -820 -1294 -222 63 1219 -5253 847 675 76 -97 -156 306 1133 201 354 311 1294 712 1037 1282 627 1251 1216 1031 507 713 -81 -436 791 -269 -305 1210 -60 -780 -797 -386 -1327 -1148 SS 20260517T204103.1Z 9633.861841 88 1 10.93 2 75.07 77.11 80.97 62.09 0.00 1 0.00 1 0 17 1.448e-01 8.650e-03 3.702e-02 2.547e-03 5.378534e-01 1.278756e-03 6.244961e-03 -6.000000e+00 8.145211e-02 231.15 -2.00 3.56 -2.00 319.39 0.00e+00 1.454346e-03 3.421935e-04 4.870541e-04 -6.000000e+00 3.567052e-03 282.27 -2.00 20.00 -2.00 318.69 0.00e+00 3.804 0.001 302.00 328.00 3 2.4200e+00 3.6043e-03 4.7572e-02 -6.0000e+00 2.0415e-01 3.9608e-02 4.2316e-03 2.8513e-02 -6.0000e+00 2.2185e-01 -9.7164e-02 3.3339e-03 1.4068e-02 -6.0000e+00 1.3168e-01 3.8947e-02 1.7506e-03 4.2147e-03 -6.0000e+00 5.5407e-02 5.8433e-04 -5.3027e-05 6.6328e-05 4.0870e-05 -6.0000e+00 3.6905e-03 1.0979e-02 0.0000e+00 12 9 1 12 1 1 99.82 27.70 0.47 0.01098 0.01058 28 14 1 5 0 376.830 35.75 20.00 27.70 18.30 0.0 934.99 -75379 -8872 18840 -13825 -73014 -49534 -69344 2889 -45904 -43603 -46030 -28399 -19953 -22022 -14608 -14523 -5993 -9604 6194 -10947 250 -4972 -6317 -15335 -7725 4877 -8857 -9907 -4163 -8132 -7593 -9505 -500 -2564 -5270 -2458 512 -4808 -77 5528 2827 1266 854 5859 1200 1580 -443 2458 3323 626 3606 1987 1473 126 2899 2877 336 316 202 458 31 1938 2883 3058 787 761 -1390 -932 684 1544 595 703 1108 674 464 -2150 -2630 -1768 -936 -1338 -879 -1042 -2378 -1451 -1366 43 19 194 587 477 -213 -380 122 -227 -725 -444 423 255 158 -244 -700 -754 -565 -162 -1274 -793 -831 -571 88 395 944 403 304 100 -210 -39 -39 244 -67 -40 43 317 429 435 1065 407 723 806 376 320 377 37 -37 -52 -309 -185 388 -56 -226 -114 -270 -364 -699 -2228 -150 248 -230 -2013 -1119 -2135 50 -1436 -1397 -1555 -938 -758 -1056 -791 -894 -369 -668 391 -859 18 -370 -515 -1489 -741 432 -891 -950 -371 -838 -915 -1219 -67 -350 -687 -325 75 -900 -17 1345 705 339 238 1569 341 454 -131 723 999 207 1295 734 593 55 1290 1328 163 150 93 211 15 962 1600 1856 485 444 -820 -566 433 1113 437 530 808 463 308 -1312 -1637 -1120 -629 -995 -703 -938 -2186 -1396 -1343 44 21 213 637 489 -214 -356 109 -213 -734 -488 502 328 212 -318 -887 -903 -636 -193 -1586 -1026 -1088 -762 127 604 1492 655 482 155 -306 -57 -56 371 -105 -65 69 487 665 644 1568 579 990 1181 573 516 653 64 -68 -97 -598 -358 762 -113 -449 -222 -500 -665 -1262 SS 20260517T214447.3Z 9633.906103 125 1 3.44 2 63.54 87.43 70.66 71.26 0.00 1 0.00 1 0 25 4.047e-02 2.801e-02 2.182e-02 6.938e-03 3.300760e-01 3.463129e-03 3.837896e-03 -6.000000e+00 2.278037e-02 231.15 -2.00 3.56 -2.00 317.23 0.00e+00 2.089914e-04 4.838490e-04 6.526316e-04 -6.000000e+00 9.974387e-04 282.28 -2.00 20.00 -2.00 316.49 0.00e+00 2.232 0.000 302.00 328.00 3 4.3524e+00 9.1978e-03 2.8109e-02 -6.0000e+00 5.7096e-02 4.0955e-02 1.0348e-02 1.7097e-02 -6.0000e+00 6.2037e-02 -3.3534e-02 6.1815e-03 8.1000e-03 -6.0000e+00 3.6822e-02 1.9783e-02 3.0323e-03 2.3834e-03 -6.0000e+00 1.5501e-02 4.8203e-04 7.5116e-04 1.8647e-04 2.2840e-05 -6.0000e+00 1.0315e-03 7.7804e-03 0.0000e+00 12 9 9 12 1 1 999.00 27.76 -0.07 0.00778 0.01342 1 3 1 5 0 1719.070 35.75 20.00 27.76 19.00 0.0 938.20 -7495 9117 5838 -9129 -11896 4714 -1783 28809 -1797 -7179 -14765 3089 1481 8015 -534 -363 4003 -6105 1676 600 5335 2734 3216 -4755 -3333 695 -4035 -2863 2893 931 -2079 3006 -2013 1885 -29 -233 493 -2438 329 -49 1632 -1026 527 1122 -444 218 -2597 870 1111 411 -799 -1256 1203 -2173 993 353 1798 747 -417 80 -701 339 2647 191 -965 -2538 -632 327 -717 880 2119 -93 180 202 489 1251 -1498 -119 1268 135 -167 -685 -1664 -1543 -1694 75 599 -162 1314 266 982 142 1209 1430 703 137 1674 1240 708 27 878 -370 485 470 511 730 -493 1160 424 915 -17794 1206 1324 605 515 1365 1178 1278 517 1205 664 876 26 954 1872 774 1342 1545 1229 539 148 -271 -73 350 811 70 1295 -57 -349 -871 -413 -1368 -1106 -834 1012 668 -1081 -1304 447 -199 2690 -229 -985 -2152 412 235 1385 -116 -85 938 -1528 404 152 1404 672 832 -1424 -1034 214 -1269 -820 742 255 -645 970 -750 663 -10 -80 190 -1063 157 -27 881 -590 307 648 -261 127 -1524 487 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