File name: Pandora279s1_Sapporo_20260607_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260626T175604.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260607_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260606T210244.3Z 9653.876902 235 1 34.42 2 69.53 77.56 59.95 205.10 0.00 1 0.00 1 0 73 3.667e-01 9.239e-02 9.579e-02 3.009e-03 4.678791e-01 1.523790e-03 8.340229e-03 -6.000000e+00 2.073713e-01 232.41 -2.00 3.56 -2.00 319.02 0.00e+00 9.345192e-04 3.626269e-04 7.161149e-03 -6.000000e+00 9.221598e-03 284.31 -2.00 20.00 -2.00 318.28 0.00e+00 2.830 0.000 302.00 328.00 3 4.6367e+00 4.2512e-03 4.8413e-02 -6.0000e+00 5.2101e-01 2.1219e-02 4.9119e-03 5.1698e-02 -6.0000e+00 5.6538e-01 -9.0898e-02 3.5864e-03 1.3865e-02 -6.0000e+00 3.3585e-01 8.9721e-02 1.8902e-03 7.6140e-03 -6.0000e+00 1.4198e-01 1.6648e-04 1.9147e-03 8.0421e-05 2.2262e-05 -6.0000e+00 9.3519e-03 8.9847e-03 0.0000e+00 12 9 9 12 9 1 99.76 27.95 0.05 0.00898 0.02337 11 2 1 5 0 2867.650 35.75 20.00 27.95 18.89 0.0 937.47 -57294 900000 73832 380367 -18846 17804 -18081 111931 22078 52358 -50405 11527 44685 47994 9903 -7635 -2061 -6677 1250 -344 8802 -8355 27 -4810 -2705 13353 -8005 2878 -263 18087 10775 -3126 -6234 -5994 -3536 2866 10826 -7152 -953 4449 1202 -508 -3952 5214 -568 3715 -3287 4558 3160 -3425 3523 -1957 -3195 31 47 -1099 -1533 383 -1977 1815 -3341 -289 2223 1680 -2981 -2501 -4237 -2966 1152 3281 1071 -14 -1513 -1861 626 -2799 -3880 -2915 2698 -704 1497 1286 -1456 608 662 2562 2680 2593 2176 1763 1297 642 2614 2962 2090 2352 4171 3304 2781 1650 2370 1210 3181 3334 2048 3397 3190 3868 4061 4541 -47956 4418 3400 3347 2704 3065 3356 3847 3718 3017 2561 3654 2191 2626 2359 1392 3768 3691 3443 2958 2232 1180 1436 1836 1246 339 887 -77 -1337 -1510 -2421 -2806 -3006 -2756 900000 1040 1116 -547 371 -599 1149 615 1106 -3017 426 1442 1802 645 -656 -179 -650 118 -34 798 -900 3 -577 -336 1465 -1059 318 -29 1836 1347 -506 -1161 -1094 -583 466 1861 -1612 -247 1258 377 -170 -1410 1699 -198 1249 -1181 1529 1095 -1346 1431 -835 -1484 15 23 -569 -810 194 -1000 886 -1823 -169 1308 1070 -1936 -1514 -2562 -1825 772 2457 815 -11 -1171 -1460 433 -1794 -2566 -1801 1795 -564 1239 1188 -1364 590 693 2796 3047 2818 2498 1909 1297 642 2442 2874 2144 2732 5067 4263 3727 2138 2989 1393 3661 3856 2588 4410 4125 5274 5972 6886 -102534 7204 5383 4955 3954 4321 4836 5505 5694 4810 4024 5500 3238 3881 3338 1894 5134 5055 5234 4625 3538 1950 2441 3286 2270 644 1695 -144 -2603 -2790 -4280 -4974 -5265 SS 20260607T004205.0Z 9654.029225 387 1 3.20 2 30.72 122.52 88.39 251.30 0.00 1 0.00 1 0 17 7.455e-03 5.791e-03 1.414e-03 1.050e-03 1.934435e-01 5.355679e-04 2.341035e-03 -6.000000e+00 4.217266e-03 232.42 -2.00 3.56 -2.00 314.60 0.00e+00 2.846737e-04 4.238885e-05 1.950556e-05 -6.000000e+00 1.853624e-04 284.33 -2.00 20.00 -2.00 314.00 0.00e+00 1.163 0.000 302.00 328.00 3 2.5591e+00 1.3812e-03 1.5554e-02 -6.0000e+00 1.0596e-02 1.6421e-02 1.5322e-03 1.0127e-02 -6.0000e+00 1.1497e-02 -3.2968e-03 8.7503e-04 4.9093e-03 -6.0000e+00 6.8249e-03 -2.4782e-03 3.7838e-04 1.3488e-03 -6.0000e+00 2.8712e-03 1.0378e-02 4.2731e-04 2.7855e-05 1.6553e-05 -6.0000e+00 1.9009e-04 6.5598e-03 0.0000e+00 12 1 1 12 1 1 19.66 28.15 0.35 0.00656 0.00977 22 37 1 5 0 139.060 36.00 20.00 28.15 25.09 0.0 964.74 -363 277 113 -2475 -2761 -965 196 941 1111 -889 -1792 -564 -170 150 321 -72 9 452 936 786 755 555 1299 653 86 622 111 -336 -563 1018 1094 1314 1180 -870 -1902 -1767 -1225 -1433 -360 -188 -578 -601 -376 -639 -177 -674 -476 -519 -630 -153 653 629 835 733 698 617 686 442 610 475 715 1275 1476 1341 107 -350 -718 -447 316 258 220 119 271 344 156 -171 -608 -700 -482 -896 -918 -1382 -1754 -1307 -896 -437 -272 236 606 323 447 130 -86 109 128 116 642 815 7 -174 -364 -493 -522 -65 -695 -728 -447 -322 152 159 318 368 153 23 38 -110 -29 126 328 121 -68 112 113 394 631 151 406 730 530 362 -30 138 -136 25 176 -162 258 144 -75 -295 -240 -555 -695 -146 110 44 -923 -964 -332 73 369 453 -372 -725 -236 -76 72 165 -38 5 245 520 434 416 301 728 373 51 379 65 -189 -306 548 623 760 708 -518 -1078 -1028 -768 -954 -267 -149 -470 -504 -312 -529 -145 -566 -384 -417 -491 -120 525 534 720 644 621 558 612 399 539 423 647 1206 1463 1352 106 -329 -649 -396 298 256 229 125 285 354 151 -156 -530 -603 -435 -846 -915 -1474 -1915 -1457 -1030 -522 -333 288 747 384 507 140 -89 110 137 130 757 1012 9 -214 -427 -557 -583 -76 -837 -914 -574 -421 202 216 439 511 204 30 47 -133 -35 156 420 163 -90 149 149 502 776 181 480 864 658 455 -38 179 -180 34 245 -230 373 210 -109 -426 -342 -767 -966 SS 20260607T004650.2Z 9654.032526 391 1 54.84 2 30.00 124.15 89.17 252.11 0.00 1 0.00 1 0 17 7.307e-03 5.770e-03 1.965e-04 1.462e-04 1.919736e-01 7.453937e-05 2.330829e-03 -6.000000e+00 4.133637e-03 232.42 -2.00 3.56 -2.00 314.59 0.00e+00 2.852785e-04 5.893732e-06 2.160922e-05 -6.000000e+00 1.816951e-04 284.33 -2.00 20.00 -2.00 313.99 0.00e+00 1.154 0.000 302.00 328.00 3 1.5161e+00 1.9223e-04 1.5449e-02 -6.0000e+00 1.0386e-02 1.1797e-02 2.1322e-04 1.0069e-02 -6.0000e+00 1.1269e-02 -4.1737e-03 1.2178e-04 4.8833e-03 -6.0000e+00 6.6897e-03 -2.0338e-03 5.2647e-05 1.3431e-03 -6.0000e+00 2.8141e-03 2.9849e-02 3.3619e-04 3.8787e-06 1.6521e-05 -6.0000e+00 1.8634e-04 7.0787e-03 0.0000e+00 10 0 0 10 0 0 99.21 28.16 0.37 0.00708 0.00961 1459 137 1 5 0 37.580 36.00 20.00 28.16 25.39 0.0 967.26 -478 -1 -543 -2194 -2426 -1336 -1 747 943 -313 -1395 -833 -376 101 625 9 236 448 954 1162 614 753 942 479 312 617 296 -312 -234 1007 1153 1338 1214 -865 -2106 -1755 -1344 -1035 -331 -407 -759 -717 -691 -604 -304 -519 -555 -556 -578 118 699 554 828 871 738 757 605 504 499 565 915 1113 1393 1249 -42 -354 -697 -432 326 391 340 81 302 358 125 -138 -646 -731 -448 -774 -848 -1329 -1883 -1466 -935 -524 -294 256 528 286 329 97 92 199 182 218 638 649 84 -211 -262 -463 -496 -41 -569 -620 -594 -399 14 268 367 313 204 49 -58 53 26 176 215 55 -139 79 248 314 625 215 597 782 468 371 103 148 -122 41 103 -242 122 78 -114 -248 -284 -459 -631 -194 0 -216 -821 -849 -464 0 295 387 -131 -565 -352 -170 48 321 5 125 243 531 641 340 409 531 274 186 376 175 -176 -127 543 656 774 728 -515 -1196 -1020 -843 -686 -245 -323 -618 -601 -576 -499 -250 -435 -448 -445 -449 92 561 470 713 762 655 683 539 454 440 501 826 1053 1379 1259 -41 -332 -628 -382 307 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