File name: Pandora279s1_Sapporo_20260702_L2Fit_fout2c3d20250917p1-8.txt File generation date: 20260722T152555.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v3d20250917.txt Level 1 file used: Pandora279s1_Sapporo_20260702_L1_smca1c3d20250917p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1124 305.2531 305.3939 305.5346 305.6753 305.8160 305.9567 306.0974 306.2380 306.3787 306.5193 306.6599 306.8006 306.9412 307.0818 307.2223 307.3629 307.5035 307.6440 307.7846 307.9251 308.0656 308.2061 308.3466 308.4871 308.6276 308.7680 308.9085 309.0489 309.1894 309.3298 309.4702 309.6106 309.7510 309.8913 310.0317 310.1720 310.3124 310.4527 310.5930 310.7333 310.8736 311.0139 311.1542 311.2944 311.4347 311.5749 311.7152 311.8554 311.9956 312.1358 312.2760 312.4161 312.5563 312.6964 312.8366 312.9767 313.1168 313.2569 313.3970 313.5371 313.6772 313.8172 313.9573 314.0973 314.2373 314.3773 314.5173 314.6573 314.7973 314.9373 315.0772 315.2172 315.3571 315.4970 315.6369 315.7768 315.9167 316.0566 316.1965 316.3363 316.4762 316.6160 316.7558 316.8956 317.0354 317.1752 317.3150 317.4548 317.5945 317.7342 317.8740 318.0137 318.1534 318.2931 318.4328 318.5724 318.7121 318.8518 318.9914 319.1310 319.2706 319.4102 319.5498 319.6894 319.8290 319.9685 320.1081 320.2476 320.3871 320.5266 320.6661 320.8056 320.9451 321.0846 321.2240 321.3635 321.5029 321.6423 321.7817 321.9211 322.0605 322.1999 322.3392 322.4786 322.6179 322.7573 322.8966 323.0359 323.1752 323.3145 323.4537 323.5930 323.7322 323.8715 324.0107 324.1499 324.2891 324.4283 324.5675 324.7066 324.8458 324.9849 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260701T231440.4Z 9678.968524 313 1 55.29 2 46.33 98.71 116.69 263.08 0.00 1 0.00 1 0 33 8.801e-02 1.202e-01 7.789e-03 3.157e-03 2.597722e-01 1.600300e-03 5.564613e-03 -6.000000e+00 4.993101e-02 233.02 -2.00 3.56 -2.00 316.71 0.00e+00 6.805590e-05 1.972014e-04 3.078262e-03 -6.000000e+00 2.210809e-03 286.70 -2.00 20.00 -2.00 315.92 0.00e+00 1.446 0.000 302.00 328.00 3 6.6267e+00 4.2301e-03 2.0001e-02 -6.0000e+00 1.2554e-01 3.1137e-02 4.7395e-03 1.7080e-02 -6.0000e+00 1.3607e-01 -5.8046e-02 2.7486e-03 5.1604e-03 -6.0000e+00 8.0846e-02 8.9599e-02 1.2898e-03 3.9667e-03 -6.0000e+00 3.4065e-02 1.1520e-04 1.4234e-03 8.6087e-05 6.2644e-05 -6.0000e+00 2.2443e-03 2.3443e-03 0.0000e+00 12 9 9 12 9 1 99.98 28.74 -0.54 0.00234 0.01304 15 2 1 5 0 3455.390 36.50 20.00 28.74 28.23 0.0 978.10 -1501 47170 20067 26194 -1018 6964 -13241 27763 -4119 9108 -13654 1244 22505 13050 11523 177 2234 -747 7851 -1628 568 -1056 2483 3246 85 9038 -3945 263 -2143 8066 1571 -6954 -3770 -8309 -3350 -3191 2407 -3405 -3054 2023 -2749 -3240 -5417 2167 -3083 -1644 -3391 179 -4176 -2818 -902 -2460 -1471 -1426 181 262 -3230 -1590 -2433 -366 -4345 -337 -218 2079 -3047 -2322 -2818 -2791 242 3504 3231 1468 2313 398 2640 140 -3946 -3200 3159 383 2922 2072 -447 2009 2066 4436 4380 3095 2801 2915 819 786 3790 3611 1537 3962 6359 4577 5650 4621 4257 4093 4257 4235 3143 4407 4098 6068 5234 7071 -59389 5849 4441 5476 3855 3861 3475 5912 5153 4898 3364 5185 1410 3652 2539 3007 5144 4299 2784 2862 4076 1063 1602 2408 1502 1067 2671 599 -941 -890 -1637 -4083 -4388 -279 5635 3077 3315 -150 950 -2405 3753 -834 1624 -2943 246 4081 2945 2973 54 684 -222 2420 -516 175 -324 846 1051 30 3239 -1411 90 -704 2441 544 -2556 -1453 -3256 -1249 -1224 895 -1585 -1705 1221 -1687 -2060 -3596 1444 -1976 -1030 -2284 113 -2700 -1835 -620 -1669 -1040 -1058 134 198 -2565 -1219 -1839 -271 -3519 -285 -200 1947 -2862 -1959 -2256 -2222 207 3304 3020 1433 2196 397 2349 114 -3046 -2388 2417 343 2841 2057 -477 2197 2442 5457 5235 3833 3446 3630 951 831 3872 3691 1610 4490 7832 5884 7389 5829 5390 4753 4754 5091 4141 5537 5409 8201 7502 10625 -133219 8567 6673 7485 4887 5027 4617 7506 7110 7144 4984 7375 2019 4825 3457 3862 6129 5333 3770 3803 5576 1519 2307 3590 2401 1656 4137 967 -1523 -1377 -2625 -6418 -6785 SS 20260702T002832.7Z 9679.019823 369 1 5.00 2 33.48 116.24 129.50 275.41 0.00 1 0.00 1 0 17 7.403e-03 5.831e-03 5.898e-04 4.424e-04 1.897001e-01 2.261709e-04 2.302379e-03 -6.000000e+00 4.200414e-03 233.03 -2.00 3.56 -2.00 314.55 0.00e+00 3.050691e-04 1.788139e-05 2.031601e-05 -6.000000e+00 1.859869e-04 286.71 -2.00 20.00 -2.00 313.92 0.00e+00 1.198 0.000 302.00 328.00 3 1.2852e+00 5.8359e-04 1.5722e-02 -6.0000e+00 1.0561e-02 1.4981e-02 6.4670e-04 9.9891e-03 -6.0000e+00 1.1446e-02 -2.7790e-03 3.6949e-04 4.8314e-03 -6.0000e+00 6.8012e-03 -2.6682e-03 1.5983e-04 1.3256e-03 -6.0000e+00 2.8657e-03 3.6120e-02 2.6166e-04 1.1724e-05 1.6329e-05 -6.0000e+00 1.8880e-04 2.3651e-03 0.0000e+00 12 1 1 12 1 1 99.76 28.83 0.37 0.00237 0.00433 138 144 1 5 0 35.920 36.50 20.00 28.83 30.07 0.0 986.24 -420 -101 -447 -2038 -2421 -1385 56 819 984 -209 -1595 -916 -301 -36 605 39 111 408 963 1220 801 813 1046 442 369 701 238 -323 -458 976 1041 1370 1276 -886 -2103 -1786 -1381 -1123 -350 -423 -702 -727 -553 -647 -311 -404 -477 -520 -729 27 754 611 891 903 740 703 717 469 475 536 839 1099 1387 1270 -15 -323 -790 -412 332 387 344 149 204 450 92 -158 -639 -942 -513 -807 -907 -1306 -1894 -1415 -862 -432 -281 277 484 260 371 159 115 222 240 103 577 694 143 -278 -283 -496 -548 -77 -607 -630 -582 -393 8 194 509 331 185 51 -59 75 11 162 232 82 -123 25 299 293 591 250 523 811 513 345 102 204 -122 -37 102 -228 86 100 -97 -261 -265 -476 -633 -166 -42 -182 -783 -866 -489 21 329 413 -90 -663 -395 -138 -18 306 21 60 219 530 692 456 455 584 261 218 425 140 -188 -247 540 585 783 759 -526 -1229 -1026 -857 -764 -259 -337 -576 -598 -465 -541 -258 -333 -389 -420 -571 22 607 507 772 797 663 624 645 416 424 480 764 1051 1357 1268 -14 -299 -720 -367 306 387 353 158 213 458 91 -145 -563 -817 -463 -764 -909 -1372 -2048 -1561 -982 -513 -342 337 597 310 419 171 119 226 251 114 674 857 179 -342 -338 -570 -608 -89 -742 -787 -746 -514 10 264 704 453 248 65 -73 90 13 198 296 110 -165 34 396 374 726 304 615 971 633 441 134 265 -161 -49 141 -325 123 144 -143 -372 -372 -660 -881 SS 20260702T004451.4Z 9679.031151 375 1 1.45 2 30.87 121.31 132.31 278.44 0.00 1 0.00 1 0 17 9.892e-03 7.325e-03 6.196e-03 4.629e-03 1.886889e-01 2.375512e-03 2.279032e-03 -6.000000e+00 5.613380e-03 233.03 -2.00 3.56 -2.00 314.54 0.00e+00 1.495298e-04 1.866872e-04 1.767703e-05 -6.000000e+00 2.485077e-04 286.71 -2.00 20.00 -2.00 313.92 0.00e+00 1.164 0.000 302.00 328.00 3 4.0452e+00 6.1293e-03 1.5420e-02 -6.0000e+00 1.4114e-02 4.4051e-02 6.7910e-03 9.8985e-03 -6.0000e+00 1.5296e-02 -7.3586e-03 3.8789e-03 4.7902e-03 -6.0000e+00 9.0884e-03 -4.0577e-04 1.6768e-03 1.3008e-03 -6.0000e+00 3.8303e-03 2.3437e-03 1.1404e-04 1.2290e-04 1.6137e-05 -6.0000e+00 2.5224e-04 8.7009e-04 0.0000e+00 12 9 1 12 1 1 999.00 28.86 0.29 0.00087 0.00173 1 7 1 5 0 721.450 36.50 20.00 28.86 32.10 0.0 993.98 -2423 1021 480 -1369 -2896 -69 -1082 1580 314 -654 -2825 -725 1298 -108 1973 -12 1153 1865 2659 252 -190 -79 2515 1048 1062 582 -558 -372 -2005 457 628 549 1821 -1477 -2351 -2325 -1649 -1383 -466 338 -803 13 -1527 -479 -973 -974 -1878 -832 -587 266 543 526 546 855 687 620 661 1357 10 376 1454 1207 1198 1173 688 -486 -892 -1237 872 -89 1030 69 566 905 650 400 -998 -1029 -893 -1054 -670 -1243 -1609 -1187 -1260 -439 -346 142 304 802 75 519 455 892 440 -419 842 559 486 -462 -108 -231 -282 -34 -289 -959 -604 -491 -102 922 394 291 245 -591 -154 -308 198 107 226 148 -162 1 -222 -155 308 706 730 -449 420 53 188 -49 -279 -29 11 -356 547 370 -510 79 143 -568 -96 -980 419 195 -533 -1008 -23 -399 600 132 -282 -1187 -310 576 -51 978 -6 616 1017 1480 141 -107 -43 1399 621 624 353 -332 -211 -1120 249 360 317 1116 -874 -1330 -1339 -1009 -948 -350 266 -675 11 -1311 -405 -820 -813 -1581 -668 -472 213 443 438 475 749 611 561 605 1214 8 333 1332 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