File name: Pandora279s1_Sapporo_20260709_L2Fit_fout2c2d20231207p1-8.txt File generation date: 20260709T144438.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Masatomo Fujiwara Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 279 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora279_OF_v3d20230911.txt Instrument calibration file used: Pandora279s1_CF_v2d20231207.txt Level 1 file used: Pandora279s1_Sapporo_20260709_L1_smca1c2d20231207p1-8.txt Full location name: Hokkaido University, Environmental Earth Science, Building A, Sapporo, Japan Short location name: Sapporo Country of location: Japan Location latitude [deg]: 43.0727 Location longitude [deg]: 141.3459 Location altitude [m]: 46 Local noon date: 20260709 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1196 305.2603 305.4009 305.5416 305.6822 305.8229 305.9635 306.1041 306.2447 306.3853 306.5259 306.6665 306.8070 306.9476 307.0881 307.2287 307.3692 307.5097 307.6502 307.7907 307.9311 308.0716 308.2120 308.3525 308.4929 308.6333 308.7737 308.9141 309.0545 309.1949 309.3353 309.4756 309.6160 309.7563 309.8966 310.0369 310.1772 310.3175 310.4578 310.5980 310.7383 310.8785 311.0188 311.1590 311.2992 311.4394 311.5796 311.7198 311.8599 312.0001 312.1402 312.2804 312.4205 312.5606 312.7007 312.8408 312.9809 313.1209 313.2610 313.4010 313.5411 313.6811 313.8211 313.9611 314.1011 314.2410 314.3810 314.5210 314.6609 314.8008 314.9408 315.0807 315.2206 315.3605 315.5003 315.6402 315.7801 315.9199 316.0597 316.1996 316.3394 316.4792 316.6189 316.7587 316.8985 317.0382 317.1780 317.3177 317.4574 317.5971 317.7368 317.8765 318.0162 318.1559 318.2955 318.4352 318.5748 318.7144 318.8540 318.9936 319.1332 319.2728 319.4123 319.5519 319.6914 319.8309 319.9705 320.1100 320.2495 320.3889 320.5284 320.6679 320.8073 320.9468 321.0862 321.2256 321.3650 321.5044 321.6438 321.7832 321.9225 322.0619 322.2012 322.3405 322.4798 322.6191 322.7584 322.8977 323.0370 323.1762 323.3155 323.4547 323.5939 323.7331 323.8723 324.0115 324.1507 324.2899 324.4290 324.5682 324.7073 324.8464 324.9855 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260708T220451.9Z 9685.920045 285 1 29.78 2 59.67 86.73 29.52 204.89 0.00 1 0.00 1 0 17 2.064e-02 7.070e-03 4.396e-03 1.820e-03 2.698491e-01 9.181341e-04 3.248874e-03 -6.000000e+00 1.170961e-02 233.05 -2.00 3.56 -2.00 316.59 0.00e+00 6.727979e-04 1.112758e-04 5.218468e-05 -6.000000e+00 5.198599e-04 287.34 -2.00 20.00 -2.00 315.78 0.00e+00 1.972 0.000 302.00 328.00 3 4.5925e+00 2.4246e-03 2.4454e-02 -6.0000e+00 2.9438e-02 3.8119e-02 2.7145e-03 1.4362e-02 -6.0000e+00 3.1902e-02 3.7299e-04 1.5786e-03 6.9083e-03 -6.0000e+00 1.8962e-02 -5.7703e-03 7.4865e-04 1.9285e-03 -6.0000e+00 7.9959e-03 5.3384e-04 -1.6069e-04 4.9155e-05 2.0395e-05 -6.0000e+00 5.2650e-04 3.3560e-03 4.4399e-05 12 9 1 12 33 1 99.84 29.05 0.45 0.00336 0.00215 15 3 1 5 0 1861.060 36.75 20.00 29.05 28.50 0.0 978.71 -4103 9387 4533 4696 -7020 -8321 -5880 8043 -1280 673 -8013 -3668 3875 3138 2988 -437 93 -1414 1174 72 -225 -921 -84 977 -447 2643 -479 -21 340 3402 1831 -1303 407 -3182 -2213 -932 465 -2338 -915 529 -898 -1299 -1883 689 -207 -203 -315 -469 -743 -431 1155 -116 328 712 1012 1153 67 444 471 846 333 637 1677 1865 -406 -289 -785 -849 519 1051 979 311 797 790 477 -278 -1221 -1611 400 -894 -666 -898 -1853 -1325 -911 155 442 260 192 575 247 -319 -70 71 -479 -123 842 158 445 -216 -193 -607 -737 -189 -978 -383 -961 -44 177 595 578 439 19 -34 50 -10 -606 -48 93 -178 -573 372 -103 268 328 188 956 827 242 135 349 280 -170 50 -2 -265 197 331 172 -45 -89 -414 -939 -650 1385 700 646 -971 -1178 -890 1198 -231 121 -1532 -721 815 765 764 -125 27 -439 370 24 -75 -304 -29 352 -171 1012 -185 -7 112 1120 664 -526 163 -1301 -885 -378 194 -1187 -514 314 -575 -866 -1299 462 -140 -137 -207 -303 -473 -279 793 -81 239 545 790 917 51 355 369 663 258 536 1520 1683 -360 -246 -634 -680 453 983 986 307 771 769 426 -236 -1014 -1304 325 -839 -658 -928 -2031 -1441 -1066 183 543 329 241 681 282 -351 -70 71 -523 -141 1017 203 592 -278 -242 -734 -853 -221 -1261 -488 -1292 -59 249 853 870 659 28 -47 66 -13 -778 -65 129 -263 -820 539 -145 375 436 250 1196 1067 325 185 500 411 -254 74 -3 -427 321 534 277 -73 -139 -649 -1457 SS 20260708T223635.5Z 9685.942078 308 1 11.44 2 53.88 92.12 32.40 218.34 0.00 1 0.00 1 0 17 8.375e-03 5.799e-03 1.083e-03 7.017e-04 2.313072e-01 3.579009e-04 2.802348e-03 -6.000000e+00 4.752599e-03 233.05 -2.00 3.56 -2.00 315.30 0.00e+00 2.995410e-04 3.261925e-05 2.595503e-05 -6.000000e+00 2.109633e-04 287.34 -2.00 20.00 -2.00 314.59 0.00e+00 1.692 0.000 302.00 328.00 3 2.2789e+00 9.2977e-04 2.0944e-02 -6.0000e+00 1.1948e-02 2.0933e-02 1.0339e-03 1.2231e-02 -6.0000e+00 1.2947e-02 -4.1672e-03 5.8972e-04 5.8964e-03 -6.0000e+00 7.6954e-03 -1.4046e-03 2.6115e-04 1.6062e-03 -6.0000e+00 3.2457e-03 7.6573e-03 1.8361e-05 1.8758e-05 1.9010e-05 -6.0000e+00 2.1360e-04 2.8915e-03 9.5393e-05 12 1 1 12 1 1 97.95 29.07 0.32 0.00289 0.00303 61 28 1 5 0 184.410 36.75 19.99 29.07 29.08 0.0 981.55 -454 -133 -116 -2632 -3728 -2121 -346 860 899 -393 -2244 -907 -72 405 1222 141 189 63 998 1186 455 550 889 506 354 1020 32 -605 -432 1112 1298 1521 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-69 -34 339 216 79 -107 10 297 461 880 486 642 863 555 629 160 259 -233 -80 28 -305 217 59 -200 -329 -334 -594 -963 SS 20260708T225525.0Z 9685.955150 323 1 4.90 2 50.45 95.51 34.58 225.33 0.00 1 0.00 1 0 17 7.985e-03 6.112e-03 2.778e-03 1.862e-03 2.147620e-01 9.492645e-04 2.599757e-03 -6.000000e+00 4.531187e-03 233.05 -2.00 3.56 -2.00 315.14 0.00e+00 2.355931e-04 8.382805e-05 2.362472e-05 -6.000000e+00 2.011386e-04 287.34 -2.00 20.00 -2.00 314.44 0.00e+00 1.567 0.000 302.00 328.00 3 3.4101e+00 2.4609e-03 1.9412e-02 -6.0000e+00 1.1391e-02 2.8963e-02 2.7348e-03 1.1343e-02 -6.0000e+00 1.2344e-02 -3.6151e-03 1.5608e-03 5.4716e-03 -6.0000e+00 7.3369e-03 -2.0357e-03 6.8775e-04 1.4890e-03 -6.0000e+00 3.0945e-03 2.8658e-03 2.4426e-05 4.9791e-05 1.7917e-05 -6.0000e+00 2.0366e-04 2.6172e-03 7.9692e-05 12 1 1 12 1 1 90.47 29.10 0.34 0.00262 0.00280 8 10 1 5 0 543.520 36.75 20.00 29.10 30.63 0.0 988.47 -472 481 -741 -1915 -2856 -2162 -479 323 662 -529 -1839 -825 463 -344 1599 -593 -120 276 1112 1483 134 649 1713 331 442 520 50 -584 57 1306 621 813 1587 -852 -1677 -1740 -1274 -977 -215 -11 -452 -670 -1001 -229 -589 -517 -947 -578 -518 58 570 337 941 847 877 911 596 542 320 113 899 1336 1046 1557 356 -667 -699 -449 721 656 582 207 106 260 241 -489 -655 -910 -452 -607 -853 -1543 -2052 -1481 -844 -445 -381 208 579 443 527 130 168 204 260 -40 549 754 216 -152 -333 -497 -528 30 -584 -992 -618 -381 77 421 205 349 -16 64 176 -103 -22 410 41 -83 -373 251 225 481 710 280 754 648 810 236 31 131 -235 124 -15 -298 231 48 -355 -68 -158 -321 -773 -151 160 -247 -574 -821 -619 -147 104 232 -190 -644 -301 177 -141 683 -275 -56 133 551 718 66 312 849 175 231 280 26 -297 28 646 312 434 863 -465 -882 -938 -731 -599 -150 -8 -353 -520 -798 -181 -464 -404 -748 -440 -384 43 452 273 765 722 760 803 516 479 277 99 785 1213 994 1542 341 -621 -609 -398 669 648 598 213 111 260 228 -445 -562 -781 -401 -568 -860 -1609 -2253 -1643 -977 -533 -464 259 713 532 594 142 173 206 273 -45 646 949 275 -191 -402 -570 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